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Синергічний ефект BaCl2 на інгібування олією Mentha Spicata корозії міді в 1м нітратній кислоті: гравіметричне та раман-спектроскопічне дослідження

Nadia Belarbi1,3, Fayçal Dergal1,2 Ilyas Chikhi2,4, Djahida Lerari1, Benamar Dahmani3, Noureddine Choukchou-Braham2, Khaldoun Bachari1
Affiliation: 
1 Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques. BP 384, zone industrielle 42004 Tipaza, Algérie. 2 Laboratoire de Catalyse et Synthèse en Chimie Organique, Faculté des Sciences, Université de Tlemcen, BP 119, 13000 Tlemcen, Algérie. 3 Laboratoire de Spectrochimie et pharmacologie Structurale, Département de chimie, Faculté des sciences, Université Abou-Bekr Belkaïd, BP 119 Imama, 13000 Tlemcen, Algérie. 4 Université Belhadj Bouchaib, BP 284, Ain Témouchent, 46000 Algérie. dergalf@yahoo.fr
DOI: 
https://doi.org/10.23939/chcht17.01.007
AttachmentSize
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Abstract: 
За допомогою методів втрати ваги та hа¬ман-спектроскопії досліджено вплив суміші олії Mentha Spicata та суміші BaCl2 й олії Mentha Spicata на корозію міді в 1М HNO3. Дослідження показало, що олія Mentha Spicata ефективніше інгібує мідь у присутності BaCl2 порівнянj з самою олією. Ефективність інгібування збіль¬шувалась із підвищенням концентрації добавок. З вико¬ристанням самої лише олії Mentha Spicata dslpyfxtyj най¬вищу ефективність інгібування 56,12 %. Підвищену ефектив¬ність інгібування 75,13 % спостерігали для суміші олії Mentha Spicata і BaCl2 за 298 K в 1М HNO3; цей ефект пояснюється синергізмом між олією Mentha Spicata і BaCl2. Ефективність інгібування знижувалася з підвищенням температури від 298 до 328 К. Адсорбція молекул інгібітора на поверхні металу відповідала ізотермі Фрумкіна та Ленгмюра. Термодинамічні параметри, такі як ентальпія ∆H, вільна енергія адсорбції ∆G та ентропія адсорбції, були отримані з експериментальних температур у діапазоні 298–328 К. Для дослідження поверх¬невих шарів використовували Раман-спектроскопію та мапінг.
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