Synergistic Effect of BaCl2 on Corrosion Inhibition of Copper by Mentha Spicata Oil in 1M Nitric Acid: Gravimetric and Raman Spectroscopy Studies
Affiliation:
1 Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques. BP 384, zone industrielle 42004 Tipaza, Algérie.
2 Laboratoire de Catalyse et Synthèse en Chimie Organique, Faculté des Sciences, Université de Tlemcen, BP 119, 13000 Tlemcen, Algérie.
3 Laboratoire de Spectrochimie et pharmacologie Structurale, Département de chimie, Faculté des sciences, Université Abou-Bekr Belkaïd, BP 119 Imama, 13000 Tlemcen, Algérie.
4 Université Belhadj Bouchaib, BP 284, Ain Témouchent, 46000 Algérie.
dergalf@yahoo.fr
DOI:
https://doi.org/10.23939/chcht17.01.007
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Abstract:
The effect of Mentha Spicata oil and the mixture of BaCl2 and Mentha Spicata oil on corrosion of copper in 1M HNO3 have been investigated using weight loss methods and Raman spectroscopy. The study revealed that copper is more efficiently inhibited by Mentha Spicata oil in the presence of BaCl2 than pure oil. The inhibition efficiencies increased with increased concentration of the additives. The highest inhibition efficiency of 56.12 % was observed with single Mentha Spicata oil. An improved inhibition efficiency of 75.13 % was observed with the mixture of Mentha Spicata oil and BaCl2 at 298 K in 1M HNO3, an effect attributed to synergism between Mentha Spicata oil and BaCl2. Inhibition efficiency decreased with increase in temperature from 298-328 K. The adsorption of inhibitor molecules on metal surface followed Frumkin and Langmuir isotherm. Thermodynamic parameters such as enthalpy ∆H, free energy of adsorption ∆G and entropy of adsorption are obtained from experimental temperatures ranging from 298-328 K. Raman Spectroscopy and mapping were used to characterize the surface layers.
References:
[1] Chapter 24: Corrosion Control-Cooling Systems. In Handbook of Industrial Water Treatment; Suez, Ed.; Suez: Trevose, 2019.
[2] Cragnolino, G.A. 2 - Corrosion Fundamentals and Characterization Techniques. In Techniques for Corrosion Monitoring; Woodhead Publishing, 2021, pp 7-42.
https://doi.org/10.1016/B978-0-08-103003-5.00002-3
[3] Adebayo, E.O. Corrosion and Corrosion Control of Petroleum Pipelines. Thesis, Department of Mechanical Engineering, University of Ilorin, Nigeria, 2004.
[4] Hart, K.; James, A.O. Corrosion Inhibition of Copper in Hydrochloric and Tetraoxosulphate (VI) Acid Solutions Using Aloe Vera Barbadensis Gel. Curr. Appl. Sci. Technol. 2014, 4, 4052-4065. https://doi.org/10.9734/BJAST/2014/9658
https://doi.org/10.9734/BJAST/2014/9658
[5] Jmiai, A.; Tara, A.; El Issami, S.; Hilali, M.; Jbara, O.; Bazzi, L. A New Trend in Corrosion Protection of Copper in Acidic Medium by Using Jujube Shell Extract as an Effective Green and Environmentally Safe Corrosion Inhibitor: Experimental, Quantum Chemistry Approach and Monte Carlo Simulation Study. J. Mol. Liq. 2021, 322, 114509. https://doi.org/10.1016/j.molliq.2020.114509
https://doi.org/10.1016/j.molliq.2020.114509
[6] Corrosion Resistance of Copper and Copper Alloys; Schütze, M.; Feser, R.; Bender, R., Eds.; Wiley, 2011.
[7] Shinato, K.W.; Zewde, A.A.; Jin, Y. Corrosion Protection of Copper and Copper Alloys in Different Corrosive Medium Using Environmentally Friendly Corrosion Inhibitors. Corros. Rev. 2020, 38, 101-109. https://doi.org/10.1515/corrrev-2019-0105
https://doi.org/10.1515/corrrev-2019-0105
[8] Antonijevic, M.M.; Petrovic, B.M. Copper Corrosion Inhibitors. A Review. Int. J. Electrochem. Sci. 2008, 3, 1-28.
[9] Tansuǧ, G.; Tüken, T.; Giray, E.S.; Fındıkkıran, G.; Sığırcık, G.; Demirkol, O.; Erbil, M. A New Corrosion Inhibitor for Copper Protection. Corros. Sci. 2014, 84, 21-29. https://doi.org/10.1016/j.corsci.2014.03.004
https://doi.org/10.1016/j.corsci.2014.03.004
[10] Petrović Mihajlović, M.B.; Radovanović, M.B.; Tasić, Ž.Z.; Antonijević, M.M. Imidazole Based Compounds as Copper Corrosion Inhibitors in Seawater. J. Mol. Liq. 2017, 225, 127-136. https://doi.org/10.1016/j.molliq.2016.11.038
https://doi.org/10.1016/j.molliq.2016.11.038
[11] Metals Handbook Desk Edition; Davis, J.R., Ed.; ASM International, 1998.
[12] Nkuzinna, O.; Menkiti, M.; Onukwuli, O.; Mbah, G.; Okolo, B.; Egbujor, M.; Government, R. Application of Factorial Design of Experiment for Optimization of Inhibition Effect of Acid Extract of Gnetum africana on Copper Corrosion. Nat Resour. J. 2014, 5, 299-307. https://doi.org/10.4236/nr.2014.57028
https://doi.org/10.4236/nr.2014.57028
[13] Mas'ud, Z.A.; Darmawan; N.; Dawolo, J.; Apriliyanto, Y.B. Fatty Amidine as Copper Corrosion Inhibitor. J. Chem. 2020, 2020. https://doi.org/10.1155/2020/1092643
https://doi.org/10.1155/2020/1092643
[14] Fateh, A.; Aliofkhazraei, M.; Rezvanian, A.R. Review of Corrosive Environments for Copper and its Corrosion Inhibitors. Arab. J. Chem. 2020, 13, 481-544. https://doi.org/10.1016/j.arabjc.2017.05.021
https://doi.org/10.1016/j.arabjc.2017.05.021
[15] Tasić, Ž.Z., Petrović Mihajlović, M.B., Radovanović, M.B.; Antonijević, M.M. New Trends in Corrosion Protection of Copper. Chem. Pap. 2019, 73, 2103-2132. https://doi.org/10.1007/s11696-019-00774-1
https://doi.org/10.1007/s11696-019-00774-1
[16] Miralrio, A.; Espinoza Vázquez, A. Plant Extracts as Green Corrosion Inhibitors for Different Metal Surfaces and Corrosive Media: A Review. Processes 2020, 8, 942. https://doi.org/10.3390/pr8080942
https://doi.org/10.3390/pr8080942
[17] Khadraoui, A.; Khelifa, A.; Hadjmeliani, M.; Mehdaoui, R.; Hachama, K.; Tidu, A.; Azari, Z.; Obot, I.B.; Zarrouk, A. Extraction, Characterization and Anti-Corrosion Activity of Mentha Pulegium Oil: Weight Loss, Electrochemical, Thermodynamic and Surface Studies. J. Mol. Liq. 2016, 216, 724-731. https://doi.org/10.1016/j.molliq.2016.02.005
https://doi.org/10.1016/j.molliq.2016.02.005
[18] Khadraoui, A.; Khelifa, A.; Boutoumi, H.; Mettai, B.; Karzazi, Y.; Hammouti, B. Corrosion Inhibition of Carbon Steel in Hydrochloric Acid Solution by Mentha Pulegium Extract. Port. Electrochimica Acta 2014, 32, 271-280. https://doi.org/10.4152/pea.201404271
https://doi.org/10.4152/pea.201404271
[19] Znini, M.; Bouklah, M.; Majidi, L.; Kharchouf, S.; Aouniti, A.; Bouyanzer, A.; Hammouti, B.; Costa, J.; Al-Deyab S.S. Chemical Composition and Inhibitory Effect of Mentha Spicata Essential Oil on the Corrosion of Steel in Molar Hydrochloric Acid. Int. J. Electrochem. Sci. 2011, 6, 691-704.
[20] Bouyanzer, A.; Hammouti, B.; Majidi., L. Pennyroyal Oil from Mentha pulegium as Corrosion Inhibitor for Steel in 1M HCl. Mater. Lett. 2006, 60, 2840-2843. https://doi.org/10.1016/j.matlet.2006.01.103
https://doi.org/10.1016/j.matlet.2006.01.103
[21] Khadraoui, A.; Khelifa, A.; Boutoumi, H.; Hammouti, B. Mentha Pulegium Extract as a Natural Product for the Inhibition of Corrosion. Part I: Electrochemical Studies. Nat. Prod. Res. 2014, 28, 1206-1209. https://doi.org/10.1080/14786419.2014.919288
https://doi.org/10.1080/14786419.2014.919288
[22] Khadraoui, A.; Khelifa, A.; Hamitouche, H.; Mehdaoui, R. Inhibitive Effect by Extract of Mentha Rotundifolia Leaves on the Corrosion of Steel in 1M HCl Solution. Res. Chem. Intermed. 2014, 40, 961-972. https://doi.org/10.1007/s11164-012-1014-y
https://doi.org/10.1007/s11164-012-1014-y
[23] Ansari, A.; Znini, M.; Laghchimi, A.; Costa, J.; Ponthiaux P.; Majidi, L. Chemical Composition, Adsorption Proprieties and Corrosion Inhibition on Mild Steel of Mentha Rotundifolia L. Essential Oil from Morocco. Der Pharm. Lett. 2015, 7, 125-140.
[24] Bensabah, F.; Houbairi, S.; Essahli, M.; Lamiri A.; Naja, J. Chemical Composition and Inhibitory Effect of the Essential
Oil from Mentha Spicata Irrigated by Wastewater on the Corrosion of Aluminum in 1 Molar Hydrochloric Acid. Port. Electrochimica Acta 2013, 31, 195-206. https://doi.org/10.4152/pea.2013041 95
https://doi.org/10.4152/pea.201304195
[25] Hamdani, I.; Chikri, M.; Fethi, F.; Salhi, A.; Bouyanzer, A.; Zarrouk, A.; Hammouti, B.; Costa, J.; Desjobert, J.M. Essential Oil Mentha Suaveolens L : Chemical Composition, Anticorrosive Properties on Mild Steel in 0.5M H2SO4 and Chemometric Approach. J. Mater. Environ. Sci. 2017, 8, 526-538.
[26] Merah, S.; Larabi, L.; Benali, O.; Harek, Y. Synergistic Effect of Methyl Red Dye and Potassium Iodide on Inhibition of Corrosion of Carbon Steel in 0.5 M H2SO4. Pigment. Resin Technol. 2008, 37, 291-298. https://doi.org/10.1108/03699420810901963
https://doi.org/10.1108/03699420810901963
[27] Brahmi, F.; Adjaoud, A.; Marongiu, B.; Falconieri, D.; Yalaoui-Guellal, D.; Madani, K.; Chibane, M. Chemical and Biological Profiles of Essential Oils from Mentha Spicata L. Leaf from Bejaia in Algeria. J. Essent. Oil Res. 2016, 28, 211-220. https://doi.org/10.1080/10412905.2015.1118411
https://doi.org/10.1080/10412905.2015.1118411
[28] Bouchard-Abouchacra, M. PhD Thesis, Mus'eum National d'Histoire Naturelle. Laboratoire de Min'eralogie, 2001.
[29] McCann, L.I.; Trentelman, K.; Possley, T.; Golding, B. Corrosion of Ancient Chinese Bronze Money Trees Studied by Raman Microscopy. J. Raman Spectrosc. 1999, 30, 121-132. https://doi.org/10.1002/(SICI)1097-4555(199902)30:2%3C121::AID-JRS355%3E3.0.CO;2-L
https://doi.org/10.1002/(SICI)1097-4555(199902)30:2<121::AID-JRS355>3.0.CO;2-L
[30] Di Lonardo, G.; Martini, C.; Ospitali, F.; Poli, G.; Prandsraller, D.; Tullini, F. In Proceedings of the 7th International Conference on Non-destructive Testing and Micro-analysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage, 2-6 June 2002, Congress Centre Elzenveld: Antwerp, Belgium Antwerp, 2002.
[31] Geethamani, P. Corrosion inhibitors; London: Intechopen, 2019.
[32] Xavier, G.T.; Thirumalairaj, B.; Jaganathan, M. Effect of Piperidin-4-ones on the Corrosion Inhibition of Mild Steel in 1 N H2SO4. Int. J. Corros. 2015, 2015, 15. https://doi.org/10.1155/2015/410120
https://doi.org/10.1155/2015/410120
[33] Aramaki, K.; Hackerman, N. Inhibition Mechanism of Medium‐Sized Polymethyleneimine. J. Electrochem. Soc. 1969, 116, 568. https://doi.org/10.1149/1.2411965
https://doi.org/10.1149/1.2411965
[34] Larabi, L.; Harek, Y. Effect of Iodide Ions on Corrosion Inhibition of Mild Steel in 0.5M H2SO4 by Poly(4-Vinylpyridine). Port. Electrochimica Acta 2004, 22, 227-247.
https://doi.org/10.4152/pea.200403227
[35] Bruneton, J. Pharmacognosie, Phytochimie des Plantes Médicinales. Revue et Augmentée ; Tec & Doc : Paris, 1999.
[36] Ivanov, E.S. Metallurgy, Moscow 1986.
[37] Singh, A.; Ahamad, I.; Yadav, D.K.; Singh, V.K.; Quraishi, M.A. The Effect of Environmentally Benign Fruit Extract of Shahjan (Moringa Oleifera) on the Corrosion of Mild Steel in Hydrochloric Acid Solution. Chem. Eng. Commun. 2012, 199, 63-77. https://doi.org/10.1080/00986445.2011.570390
https://doi.org/10.1080/00986445.2011.570390
[38] Attar, T.; Larabi, L.; Harek, Y. Inhibition Effect of Potassium Iodide on the Corrosion of Carbon Steel (XC 38) in Acidic Medium. Int. J. Adv. Chem. 2014, 2, 139-142. https://doi.org/10.14419/ijac.v2i2.3272
https://doi.org/10.14419/ijac.v2i2.3272
[39] Ansari, K.; Yadav, D.K.; Ebenso, E.E.; Quraishi, M. Novel and Effective Pyridyl Substituted 1,2,4-Triazole as Corrosion Inhibitor for Mild Steel in Acid Solution. Int. J. Electrochem. Sci. 2012, 7, 4780-4799.
[40] El Guerraf, A.; Titi, A.; Cherrak, K.; Mechbal, N.; Azzouzi, M.E.; Touzani, R.; Hammouti, B.; Lgaz, H. The Synergistic Effect of Chloride Ion and 1,5-Diaminonaphthalene on the Corrosion Inhibition of Mild Steel in 0.5 M Sulfuric Acid: Experimental and Theoretical Insights. Surf. Interfaces 2018, 13,168-177. https://doi.org/10.1016/j.surfin.2018.09.004
https://doi.org/10.1016/j.surfin.2018.09.004
[41] Popova, A.; Sokolova, E.; Raicheva, S.; Christov, M. AC and DC Study of the Temperature Effect on Mild Steel Corrosion in Acid Media in the Presence of Benzimidazole Derivatives. Corros. Sci. 2003, 45, 33-58. https://doi.org/10.1016/S0010-938X(02)00072-0
https://doi.org/10.1016/S0010-938X(02)00072-0
[42] Bentiss, F.; Lebrini, M.; Lagrenée, M. Thermodynamic Characterization of Metal Dissolution and Inhibitor Adsorption Processes in Mild Steel/2,5-bis(n-thienyl)-1,3,4-thiadiazoles/hydrochloric Acid System. Corros. Sci. 2005, 47, 2915-2931. https://doi.org/10.1016/j.corsci.2005.05.034
https://doi.org/10.1016/j.corsci.2005.05.034
[43] Abdul Rahiman, A.F.S.; Sethumanickam, S. Corrosion Inhibition, Adsorption and Thermodynamic Properties of Poly(Vinyl Alcohol-Cysteine) in Molar HCl. Arab. J. Chem. 2017, 10, S3358-S3366. https://doi.org/10.1016/j.arabjc.2014.01.016
https://doi.org/10.1016/j.arabjc.2014.01.016
[44] Larouj, M.; Ourrak; K.; El M'Rabet, M.; Zarrok, H.; Serrar, H.; Boudalia, M.; Boukhriss, S.; Warad, I.; Oudda, H.; Touir, R. Thermodynamic Study of Corrosion Inhibition of Carbon Steel in Acidic Solution by New Pyrimidothiazine Derivative J. Mater. Environ. Sci. 2017, 8, 3921-3931.
[45] El Ouali, I.; Hammouti, B.; Aouniti, A.; Ramli, Y.; Azougagh, M.; Essassi, E.M.; Bouachrine, M. Thermodynamic Characterisation of Steel Corrosion in HCl in the Presence of 2-Phenylthieno(3, 2-b)quinoxaline. J. Mater. Environ. Sci. 2010, 1, 1-8.
[46] Keleş, H.; Keleş, M.; Dehri, I.; Serindağ, O. The Inhibitive Effect of 6-Amino-m-cresol and its Schiff Base on the Corrosion of Mild Steel in 0.5M HCI Medium. Mater. Chem. Phys. 2008, 112, 173-179. https://doi.org/10.1016/j.matchemphys.2008.05.027
https://doi.org/10.1016/j.matchemphys.2008.05.027
[47] Salghi, R.; Jodeh, S.; Ebenso, E.E.; Lgaz, H.; Ben Hmamou, D.; Belkhaouda, M.; Ali, I.H.; Messali, M.; Hammouti, B.; Fattouch, S. Inhibition of C-steel Corrosion by Green Tea Extract in Hydrochloric Solution. Int. Int. J. Electrochem. Sci. 2017, 12, 3283-3295. https://doi.org/10.20964/2017.04.46
https://doi.org/10.20964/2017.04.46
[48] Cano, E.; Polo, J.L.; Iglesia, A.L.A.; Bastidas, J.M. A Study on the Adsorption of Benzotriazole on Copper in Hydrochloric Acid Using the Inflection Point of the Isotherm. Adsorption 2004, 10, 219-225. https://doi.org/10.1023/B:ADSO.0000046358.35572.4c
https://doi.org/10.1023/B:ADSO.0000046358.35572.4c
[49] Shaju, K. S.; K. Joby Thomas; Vinod P. Raphael; Aby Paul. Synergistic Effect of KI on Corrosion Inhibition of Mild Steel by Polynuclear Schiff Base in Sulphuric Acid. Int. Sch. Res. Notices 2012, 2012, 425878. https://doi.org/10.5402/2012/425878
https://doi.org/10.5402/2012/425878
[50] Lgaz, H.; Bhat, K.S.; Salghi, R.; Shubhalaxmi; Jodeh, S.; Algarra, M.; Hammouti, B.; Ali, I.H.; Essamri, A. Insights into Corrosion Inhibition Behavior of Three Chalcone Derivatives for Mild Steel in Hydrochloric Acid Solution. J. Mol. Liq. 2017, 238, 71-83. https://doi.org/10.1016/j.molliq.2017.04.124
https://doi.org/10.1016/j.molliq.2017.04.124
[51] Belarbi, N.; Dergal, F.; Chikhi, I.; Merah, S.; Lerari, D.; Bachari, K. Study of anti-corrosion activity of Algerian L. stoechas oil on C38 carbon steel in 1 M HCl medium. Int. J. Ind. Chem. 2018, 9, 115-125. https://doi.org/10.1007/s40090-018-0143-6
https://doi.org/10.1007/s40090-018-0143-6
[52] El-Sabbah, M.M.B.; Bedair, M.A.; Abbas, M.A.; Fahmy, A.; Hassaballa, S.; Moustafa, A.A. Synergistic Effect between Natural Honey and 0.1M KI as Green Corrosion Inhibitor for Steel in Acid Medium. Z. Phys. Chem. 2018. https://doi.org/10.1515/zpch-2018-1208
https://doi.org/10.1515/zpch-2018-1208
[53] Momeni, M.M.; Ghayeb, Y.; Menati, M. Fabrication, Characterization and Photoelectrochemical Properties of Cuprous Oxide-Reduced Graphene Oxide Photocatalysts for Hydrogen Generation. J. Mater. Sci. Mater. Electron. 2018, 29, 4136-4146. https://doi.org/10.1007/s10854-017-8358-4
https://doi.org/10.1007/s10854-017-8358-4
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