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Асоціація аніонів 5,5′-дибромо-о-крезолсульфонфталеїну з катіонами барвників у водному розчині

Serghiy Shapovalov
Affiliation: 
V. N. Karazin Kharkiv National University, 4 Svobody sq., 61022 Kharkiv, Ukraine serghey.a.shapovalov@karazin.ua
DOI: 
https://doi.org/10.23939/chcht16.03.387
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PDF icon full_text.pdf694.61 KB
Abstract: 
Розглянуто утворення у водному розчині асоціатів між одно- або двозарядними аніонами 5,5′ дибромо-о-крезолсульфонфталеїну й однозарядними катіонами ціанінових барвників (квінальдиновий синій, квінальдиновий червоний). На підставі спектрофотометричних даних проаналізовані значення рівноважних констант асоціації. Напівемпіричним квантовохімічним методом АМ1 визначена енергетика катіон-аніонних взаємодій (стандартна ентальпія утворення іонів та асоціатів) і встановлена ймовірна будова асоціатів. Обговорена узгодженість між експериментальними спектрофотометричними та розрахунковими квантовохімічними даними.
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