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Study on the Composition and Properties of Pyrolysis Pyrocondensate of Used Tires

Ksenia Hrynyshyn1, Volodymyr Skorokhoda1, Taras Chervinskyy1
Affiliation: 
1Lviv Polytechnic National University, 12 Bandery St., Lviv 79013, Ukraine chervinskijt@gmail.com
DOI: 
https://doi.org/10.23939/chcht16.01.159
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Abstract: 
A low-temperature pyrolysis, the target product of which is pyrocondensate, is one of the options for the recycling usedtires. The fractional composition and properties of pyrocondensate of rubber waste pyrolysis obtained at an industrial plant have been studied. The pyrocondensate was separated into gasoline, diesel fraction and residue. The composition and properties of obtained productswere determined using X-ray fluorescence analysis and IR spectroscopic studies.
References: 

[1] Hetmanchuk, Yu.P.; Bratychak,M.M.Khimiya ta TekhnolohiyaPolimeriv. BeskydBiT: Lviv 2006.

[2] Bratychak, M.M.;Grynyshyn, O.B.;Prysyazhnyy, YU.V.;Pushak, A.P. NaftopolimerniSmolyizFunktsiynymyGrupamy. Syntez,Vlastyvosti, Zastosuvannya. VydavnytsvoLvivskoyipolitekhniky:Lviv, 2016.

[3] Bratychak, M.;Gagin, M.; Shyshchak, O.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 1. Hydrocarbon Pyrolysis By-Products. Ecol.Chem.Eng.S2004, 11 (S1), 15-20.

[4] Michael Bratychak, MyroslavaGagin, Olena Shyshchak, Witold Waclawek. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 2. Method of Petroleum Resins Obtaining. Ecol. Chem. Eng.S2004,11(S1), 21-26.

[5] Bratychak, M.;Astakhova, O.;Shyshchak, O.; Namiesnik, J.; Ripak, O.; Pyshyev, S. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar.1. Coumarone-Indene Resins with Carboxygroups.Chem. Chem. Technol. 2017, 11, 509.
https://doi.org/10.23939/chcht11.04.509

https://doi.org/10.23939/chcht11.04.509
https://doi.org/10.23939/chcht11.04.509

[6] Bratychak, M.; Brostow, W.; Grynyshyn, O.; Shyshchak, O. Synthesis and Characterization of Petroleum Resins with Epoxy Groups. Mater.Res.Innov. 2003, 7, 167-171.https://doi.org/10.1007/s10019-003-0243-5
https://doi.org/10.1007/s10019-003-0243-5

[7] Skibitskiy, V.; Grynyshyn, O.; Bratychak, M.; Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 4. Resins with Carboxy Groups. Ecol. Chem. Eng.S2004, 11 (S1), 41-51.

[8] Bratychak, M.; Grynyshyn, O.; Shyshchak, O.; Romashko, I.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 12. Petroleum Resins with Hydroxyl Groups. Ecol. Chem. Eng.S 2007, 14 (2), 225-234.

[9] Bratychak, M.; Shust, O.;Chervinskyy, T.; Shyshchak, O.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 14. Petroleum Resins with Fluorine Atoms. Ecol. Chem. Eng.S2011, 18 (1), 49-54.

[10] Gagin, M.; Bratychak, M.; Shyshchak, O.Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 3. Petroleum Resins with Epoxy Groups. Ecol. Chem. Eng.S2004, 11 (S1), 27-40.

[11] Bratychak, M.; Gagin, M.;Shyshchak, O.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 5. Epoxy-Oligomeric Composites on the Basis of Petroleum Resins with Epoxy Groups. Ecol. Chem. Eng.S2004, 11 (S1), 53-58.

[12] Chervinskyy, T.; Bratychak, M.; Gagin, M.; Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 6. Petroleum Resins with Epoxy Groups as Active Components of Epoxy-Polymeric Composites. Ecol. Chem. Eng.S2004, 11 (11), 1225-1231.

[13] Bratychak, M.; Shyshchak, O.;Romashko, I.; Bratychak Mich.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 8. Petroleum Resins with Epoxy Groups Modified with Maleic Anhydride. Ecol. Chem. Eng.S2006, 13 (S1), 17-24.

[14] Bratychak, M.; Romashko, I.; Shyshchak, O.;Bratychak. Mich.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 9. Petroleum Resins with Epoxy Groups Modified Simultaneously with Maleic Anhydride and Styrene. Ecol. Chem. Eng.S2006,13 (S1), 25-33.

[15] Bratychak, M.;Romashko, I., Shyshchak, O.;Bratychak, Mich.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 10. Resins with Carboxyl Groups Based on C9Fraction from Gasoline Pyrolysis.Ecol. Chem. Eng. S2006, 13 (12), 1345-1352.

[16] Bratychak, M.;Romashko, I., Shyshchak, O.;Bratychak, Mich.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 11. Resins with Carboxyl Groups Synthesized in the Presence Peroxydiglutaric Acid. Ecol. Chem. Eng.S2007, 14 (S2), 245-252.

[17] Bratychak, M.;Romashko, I., Shyshchak, O.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 7. Resins with Carboxy Groups and Block-Cooligomers Based on Them and Polyethylene Glycol. Ecol. Chem. Eng.S2006, 13 (S1), 7-16.

[18] Grynyshyn, O.; Bratychak, M.; Krynytskiy, V.;Donchak, V. Petroleum Resins for Bitumens Modification. Chem. Chem. Technol.2008, 2, 47-53.https://doi.org/10.23939/chcht02.01.047
https://doi.org/10.23939/chcht02.01.047

[19] Bratychak, M.;Grynyshyn, O.; Astakhova, O.; Shyshchak, O.;Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 13. Petroleum Resins with Hydroxyl Groups Modified with Styrene. Ecol. Chem. Eng.S 2008, 15 (3), 387-396.

[20] Bratychak, M.; Ripak, O.; Namiesnik, J.;Shyshchak, O.; Astakhova, O. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 2. Coumarone-Indene Resins with Epoxy Groups. Chem. Chem. Technol. 2018, 12, 93-100.https://doi.org/10.23939/chcht12.01.093
https://doi.org/10.23939/chcht12.01.093

[21] Sidun, I.; Solodkyy, S.; Shved, M.; Astakhova, O.; Shyshchak, O.; Bratychak, M. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 5. Emulsions on the Basis of Bitumen Modified by Coumarone-Indene Resins with Epoxy Groups. Chem. Chem. Technol. 2019, 13, 489-494.https://doi.org/10.23939/chcht13.04.489
https://doi.org/10.23939/chcht13.04.489

[22] Bratychak, M.; Astakhova, O.; Prysiazhnyi, Y.; Shved, M.;Shyshchak, O.; Namiesnik, J.; Plonska-Brzezinska, M. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 3. Coumarone-Indene Resins with Methacrylic Fragments. Chem. Chem. Technol. 2018, 12, 379-385.https://doi.org/10.23939/chcht12.03.379
https://doi.org/10.23939/chcht12.03.379

[23] Kutova, J. ProblemyUtylizaciiVidhodiv. https://sites.google.com/site/smittausvititaukraieni/home/(accessed May 12, 2021)

[24] Bradford, A. Pollution Facts & Types of Pollution. https://www.livescience.com/22728-pollution-facts.html(accessed May 12, 2021)

[25] Horner, J.M. Environmental Health Implications of Heavy Metals Pollution from Car Tyres. Environ. Health Rev.1999,11(4), 175-178.https://doi.org/10.1515/REVEH.1996.11.4.175
https://doi.org/10.1515/REVEH.1996.11.4.175

[26] Coleman, L.W. Tire Recycling and the Environment: Benefits and Challenges. EHS Daily Advisor, Mar 22, 2021. https://ehsdailyadvisor.blr.com/2021/03/tire-recycling-and-the-environme...

[27] Wulandari, P.S.; Tjandra, D.Use of Crumb Rubber as an Additive in Asphalt Concrete Mixture. Procedia Eng. 2017, 171, 1384-1389. https://doi.org/10.1016/j.proeng.2017.01.451
https://doi.org/10.1016/j.proeng.2017.01.451

[28] Lushinga, N.; Cao, L.; Dong, Z.; Yang, C.; Assogba, C.O. Performance Evaluation of Crumb Rubber Asphalt Modified with Silicone-Based Warm Mix Additives. Adv. Cicil Eng.2020, 2020, Article ID 4840825. https://doi.org/10.1155/2020/4840825
https://doi.org/10.1155/2020/4840825

[29] Nagurskyy, A.; Khlibyshyn, Y.; Grynyshyn, O.Bitumen Compositions for Cold Applied Roofing Products. Chem. Chem. Technol. 2017, 11, 226-229.https://doi.org/10.23939/chcht11.02.226
https://doi.org/10.23939/chcht11.02.226

[30] Grynyshyn, O.B.;Khlibyshyn, J.Y.;Nagyrskyy, A.O.;Nagurskyy, O.A. MetodyOderzannjaBitumivizZalyshkivPererobkyVazkyhNaft. TechnologicheskyyAudit iRezervyProizvodstva2015, 25(5/4), 45-48.

[31] Nkosi, N.; Muzenda, E.; Gorimbo, J.;Belaid, M.Developments in Waste TyreThermochemical Conversion Processes: Gasification, Pyrolysis and Liquefaction. RSC Adv.2021, 11, 11844-11871. https://doi.org/10.1039/D0RA08966D
https://doi.org/10.1039/D0RA08966D

[32] Czajczyńska, D.; Anguilano, L.; Ghazal, H.; Krzyżyńska, R.; Reynolds, A.J.; Spencer, N.; Jouhara, H.Potential of Pyrolysis Processes in the Waste Management Sector.Therm. Sci. Eng. Prog. 2017, 3, 171-197. https://doi.org/10.1016/j.tsep.2017.06.003
https://doi.org/10.1016/j.tsep.2017.06.003

[33] Ryzhkov, S.;Rudyuk, N.;Markina, L. Research of Thermal Conductivity of the Condensed Mass of the Whole Waste Tires and Determination of Their Optimum Arrangement in the Pyrolysis Reactor. East.-Eur. J.Enterp. Technol. 2016, 82 (4/5), 12-18.https://doi.org/10.15587/1729-4061.2016.73557
https://doi.org/10.15587/1729-4061.2016.73557

[34] Topilnytskyy, P.;Grynyshyn, O.;Machynskyy, O. TekhnologiaPervynnoiPererobkyNaftyiGazu. VydavnytsvoLvivskoyipolitekhniky:Lviv, 2014.

[35] Rybak, B.M. AnalizNeftiiNefteprodyktov. Gostoptehizdat: Moskwa 1962.

[36] Speight, J.G. Handbook of Petroleum Product Analysis, 2ndedn.; John Wiley & Sons, Inc.,2015.
https://doi.org/10.1002/9781118986370