Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes

Tetiana Bilous1, Alena Tulskaya1, Igor Ryshchenko1, Issam Chahine1, Volodymyr Bairachnyi1
1 National Technical University “Kharkiv Polytechnic Institute”, 2, Kyrpychova St., 61002 Kharkiv, Ukraine beloustany@ukr.net
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The kinetics of anodic processes on Pt/PtO and PbO2 anodes has been studied in water solutions of acetic acid. The addition of sulfuric acid has a catalytic effect in the electrochemical synthesis of peroxyacetic acid. The choice of promoters of peroxide-particles formation has been proved. I–, Cl– (current efficiency is 1.2–1.5 %) particles have been defined as the most effective for platinum anode and I–, F– (current efficiency is 0.50–0.55 %) have been defined as the most effective for lead-dioxide anode.

[1] Dul’neva L., Moskvin A.: Russ. J. Gen. Chem., 2005, 75, 1125. https://doi.org/10.1007/s11176-005-0378-8
[2] Zhao X., Zhang T., Zhou Y., Liu D.: J. Mol. Catal. A, 2007, 271, 246. https://doi.org/10.1016/j.molcata.2007.03.012
[3] Zhao X., Cheng K., Hao J., Liu D.: J. Mol. Catal. A, 2008, 284, 58. https://doi.org/10.1016/j.molcata.2008.01.003
[4] Zhao X., Zhang T., Zhou Y., Liu D.: Chinese J. Process Eng., 2008, 8, 35.
[5] Sun X., Zhao X., Du W., Liu D.: Chinese J. Chem. Eng., 2011, 19, 964. https://doi.org/10.1016/S1004-9541(11)60078-5
[6] Zhang T., Luo J., Chuang K., Zhong L.: Chinese J. Chem. Eng., 2007, 15, 320. https://doi.org/10.1016/S1004-9541(07)60087-1
[7] Moraleda I., Llanos J., Sáez C. et al.: Electrochem. Commun., 2016, 73, 1. https://doi.org/10.1016/j.elecom.2016.10.010
[8] Saha M., Denggerile A., Nishiki Y. et al.: Electrochem. Commun., 2003, 5, 445. https://doi.org/10.1016/S1388-2481(03)00097-3
[9] Cotillas S., Sánchez-Carretero A., Cañizares P. et al.: Ind. Eng. Chem. Res., 2011, 50, 10889. https://doi.org/10.1021/ie2009422
[10] Ruiz-Ruiz E., Meas Y., Ortega-Borges R., Baizabal J.: Surf. Eng. Appl. Electrochem., 2014, 50, 478. https://doi.org/10.3103/S106837551406009X
[11] Cañizares P., Sáez C., Sánchez-Carretero A., Rodrigo M.: J. Appl. Electrochem., 2009, 39, 2143. https://doi.org/10.1007/s10800-009-9792-7
[12] Bilous T., Tulsky G.: Kinetics of Anodic Processes in Acetic Acid Solutions. [in:] Barsukov V. (Ed.), Promising Materials and Processes in Technical Electrochemistry. KNUTD, Kyiv 2016, 244-248.
[13] Bilous T., Tulskaya A., Matrunchyk O.: The Choice of Anode Material for the Electrochemical Synthesis of Peroxyacetic Acid. [in:] Barsukov V. (Ed.), Promising Materials and Processes in Applied Electrochemistry. KNUTD, Kyiv 2017, 230-234.
[14] Bilous T., Tulsky G., Korohodska A., Podustov M.: Visnyk NTU “KhPI”, 2017, 48, 24.
[15] Khidirov Sh.: Russ. J. Electrochem., 1992, 2, 158.
[16] Khidirov Sh., Khibiev Kh.: Russ. J. Electrochem., 2005, 11, 1176. https://doi.org/10.1007/s11175-005-0198-5