Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes

Tetiana Bilous1, Alena Tulskaya1, Igor Ryshchenko1, Issam Chahine1, Volodymyr Bairachnyi1
Affiliation: 
1 National Technical University “Kharkiv Polytechnic Institute”, 2, Kyrpychova St., 61002 Kharkiv, Ukraine beloustany@ukr.net
DOI: 
https://doi.org/10.23939/chcht14.02.135
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Abstract: 
The kinetics of anodic processes on Pt/PtO and PbO2 anodes has been studied in water solutions of acetic acid. The addition of sulfuric acid has a catalytic effect in the electrochemical synthesis of peroxyacetic acid. The choice of promoters of peroxide-particles formation has been proved. I–, Cl– (current efficiency is 1.2–1.5 %) particles have been defined as the most effective for platinum anode and I–, F– (current efficiency is 0.50–0.55 %) have been defined as the most effective for lead-dioxide anode.
References: 

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