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Синтез деяких азобарвників на основі 2,3,3 триметил 3h індоленіну

Tinatin Bukia1, Mariam Utiashvili2, Manana Tsiskarishvili2, Sopo Jalalishvili2, Ana Gogolashvili2, Tamara Tatrishvili3,4, Gia Petriashvili1
Affiliation: 
1 V. Chavchanidze Institute of Cybernetics, Georgian Technical University, S. Euli St., 5, Tbilisi 0186, Georgia 2 San Diego State University - Georgia, M. Kostava St., 5, Tbilisi 0179, Georgia 3 Ivane Javakhishvili Tbilisi State University, Department of Macromolecular Chemistry, I. Chavchavadze Ave., 1, Tbilisi 0179, Georgia 4 Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University, University St., 13, Tbilisi 0186, Georgia tinatini.bukia@tsu.ge
DOI: 
https://doi.org/10.23939/chcht17.03.549
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Abstract: 
Нові азосполуки на основі 2,3,3-три¬метил-3Н-індоленіну синтезовано й охарактеризовано за допомогою ІЧ-, ЯМР- і мас-спектрального аналізу. Синтез проводили трьома різними маршрутами: 1) відновленням ніт¬ро¬сполуки за допомогою Zn/NaOH у спирті; 2) нагрі¬ванням 2,3,3-триметил-3Н-індоленін-5-аміну в присутності MnO2 в толуолі; 3) діазотуванням 2,3,3-триметил-3Н-індоленін-5-аміну й обробкою отриманої солі діазонію від¬повідною азоскладовою.
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