Synthesis of Some Azo Dyes Based on 2,3,3-Trimethyl-3H-indolenine
Affiliation:
1 V. Chavchanidze Institute of Cybernetics, Georgian Technical University, S. Euli St., 5, Tbilisi 0186, Georgia
2 San Diego State University - Georgia, M. Kostava St., 5, Tbilisi 0179, Georgia
3 Ivane Javakhishvili Tbilisi State University, Department of Macromolecular Chemistry, I. Chavchavadze Ave., 1, Tbilisi 0179, Georgia
4 Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University, University St., 13, Tbilisi 0186, Georgia
tinatini.bukia@tsu.ge
DOI:
https://doi.org/10.23939/chcht17.03.549
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Abstract:
New azo compounds on the base of 2,3,3-trimethyl-3H-indolenine were synthesized and characterized by FT-IR, NMR, and Mas-spectral analysis. The synthesis was conducted in three different pathways: 1) by reducing the nitro compound with Zn/NaOH in alcohol; 2) by heating of 2,3,3-trimethyl-3H-indolenine-5-amine in the presence of MnO2 in toluene, and 3) by diazotization of 2,3,3-trimethyl-3H-indolenine-5-amine and treating the resulting diazonium salt with the appropriate coupler.
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