Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Порівняльна характеристика сорбційної активності гідрогелів поліметакрилової кислоти стосовно йонів лантану в деяких міжгелевих системах

Talkybek Jumadilov1, Zamira Malimbayeva2, Leila Yskak2, Oleg Suberlyak3, Ruslan Kondaurov1, Aldan Imangazy1, Laura Agibayeva4, Auez Akimov1, Khuangul Khimersen1, Akerke Zhyzbayeva1
Affiliation: 
1JSC «Institute of Chemical Sciences after A.B. Bekturov», 106, Sh. Valikhanov St., 050010 Almaty, the Republic of Kazakhstan 2Kazakh National Women’s Teacher Training University 99, Aiteke Bi St., 050000 Almaty, the Republic of Kazakhstan 3 Lviv Polytechnic National University, Lviv, Ukraine 12, Bandera St., 79013 Lviv, Ukraine 4Al-Farabi Kazakh National University, 71, Al-Farabi Ave, 050001Almaty, the Republic of Kazakhstan r-kondaurov@mai.ru
DOI: 
https://doi.org/10.23939/chcht16.03.418
AttachmentSize
PDF icon full_text.pdf433.63 KB

Keywords:

Abstract: 
Вивчено явища віддаленої взаємодії в міжгелевих системах гідрогель поліметакрилової кислоти – гідрогель полі-4-вінілпіридину (hPMAA-hP4VP) та гідрогель поліметакрилової кислоти – гідрогель полі-2-метил-5-вінілпіридину (hPMAA-hP2M5VP). Встановлено, що питома електропровідність, рН та ступінь набухання гідрогелів PMAA, P4VP та P2M5VP зменшуються під час сорбції йонів лантану за участю міжгелевих систем. Визначено, що сорбційні властивості міжгелевих систем значно збільшуються (до 30 %) у порівнянні з окремими гідрогелями РМАА, Р4VP та Р2М5VP, що вказує на факт високої йонізації під час взаємної активації полімерів. Максимальна сорбція йонів лантану відбувається за співвідношень 17% hPMAA:83% hP4VP та 50% hPMAA:50% hP2M5VP. За допомогою ІЧ спектроскопії встановлено сорбцію рідкісноземельного металу міжгелевими системами. Показана важливість можливого застосування міжгелевих систем на основі рідкоземельних зшитих полімерних гідрогелів кислотної та основної природи для створення нових інноваційних сорбційних технологій у гідрометалургії.
References: 

[1] Alexandratos, S.D. Ion-Exchange Resins: A Retrospective from Industrial and Engineering Chemistry Research. Ind. Eng. Chem. Res. 2009, 48, 388-389. https://doi.org/10.1021/ie801242v
[2] Selvi, P.; Ramasami, M.; Samuel, M.H.P.; Adaikkalam, P.; Srinivasan, G.N. Recovery of Gallium from Bayer Liquor Using Chelating Resins in Fixed-Bed Columns. Ind. Eng. Chem. Res. 2004, 43, 2216-2221. https://doi.org/10.1021/ie030695n
[3] François, D.; Thomas, V.A. Ion Exchangers. In Ullmann's Encyclopedia of Industrial Chemistry; Wiley-VCH: Weinheim, 2008.
[4] Birnhack, L.; Keller, O.; Tang, S.C.N.; Fridman-Bishop, N.; Lahav, O. A Membrane-Based Recycling Process for Minimizing Environmental Effects Inflicted by Ion-Exchange Softening Applications. Sep. Pur. Tech. 2019, 223, 24-30. https://doi.org/10.1016/j.seppur.2019.04.056
[5] Ergozhin, E.; Menligaziyev, E. Polifunktsionalnyie Ionoobmenniki; Nauka: Moskwa, 1986.
[6] Mulder, M. Basic Principles of Membrane Technology, 2nd ed.; Springer Netherlands, 2006. https://doi.org/10.1007/978-94-009-1766-8
[7] Malika, C.; Kenza, A.; Yasmine, A.O.; Abdeltif, A.; Aicha, B. Removal of Nitrate from Drinking Water by Adsorption Using Ion Exchange Resin. Desal. Wat. Treat. 2010, 24, 109-116. https://doi.org/10.5004/dwt.2010.1251
[8] Rafati, L.; Mahvi, A.H.; Asgari, A.R.; Hosseini, S.S. Removal of Chromium (VI) from Aqueous Solutions Using Lewatit FO36 Nano Ion Exchange Resin. Int. J. Envir. Sci. Tech. 2010, 7, 147-156. https://doi.org/10.1007/BF03326126
[9] Tabushi, I.; Kobuke, Y.; Nakayama, N.; Aoki, T.; Yoshizawa, A. Chelating Resin Functionalized with Dithiocarbamate for the Recovery of Uranium from Seawater. Ind. Eng. Chem. Prod. Res. Dev. 1984, 23, 445-448. https://doi.org/10.1021/i300015a023
[10] Kawamura, Y.; Mitsuhashi, M.; Tanibe, H.; Yoshida, H. Adsorption of Metal Ions on Polyaminated Highly Porous Chitosan Chelating Resin. Ind. Eng. Chem. Res. 1993, 32, 386-391. https://doi.org/10.1021/ie00014a015
[11] Guibal, E.; Milot, C.; Tobin, J.M. Metal-Anion Sorption by Chitosan Beads:  Equilibrium and Kinetic Studies. Ind. Eng. Chem. Res. 1998, 37, 1454-1463. https://doi.org/10.1021/ie9703954
[12] Alexandratos, S.D.; Hussain, L.A. Bifunctionality as a Means of Enhancing Complexation Kinetics in Selective Ion Exchange Resins. Ind. Eng. Chem. Res. 1995, 34, 251-254. https://doi.org/10.1021/ie00040a026
[13] Kabay, N.; Demircioglu, M.; Yayli, S.; Günay, E.; Yüksel, M.; Saǧlam, M.; Streat, M. Recovery of Uranium from Phosphoric Acid Solutions Using Chelating Ion-Exchange Resins. Ind. Eng. Chem. Res. 1998, 37, 1983-1990. https://doi.org/10.1021/ie970518k
[14] Beatty, S.T.; Fischer, R.J.; Hagers, D.L.; Rosenberg, E. A Comparative Study of the Removal of Heavy Metal Ions from Water Using a Silica−Polyamine Composite and a Polystyrene Chelator Resin. Ind. Eng. Chem. Res. 1999, 38, 4402-4408. https://doi.org/10.1021/ie9903386
[15] Di Natale, F.; Lancia, A. Recovery of Tungstate from Aqueous Solutions by Ion Exchange. Ind. Eng. Chem. Res. 2007, 46, 6777-6782. https://doi.org/10.1021/ie061691w
[16] Kiefer, R., Holl, W.H. Sorption of Heavy Metals onto Selective Ion-Exchange Resins with Aminophosphonate Functional Groups. Ind. Eng. Chem. Res., 2001, 40, 4570-4576. https://doi.org/10.1021/ie010182l
[17] Xiong, Z.; Zhao, D.; Harper, W.F. Sorption and Desorption of Perchlorate with Various Classes of Ion Exchangers:  A Comparative Study. Ind. Eng. Chem. Res. 2007, 46, 9213-9222. https://doi.org/10.1021/ie0702025
[18] Maslov, O.D.; Tserenpil, Sh.; Norov, N.; Gustova, M.V.; Filippov, M.F.; Belov, A.G.; Altangerel, M.; Enhbat, N. Uranium Recovery from Coal ash Dumps of Mongolia. Sol. Fuel Chem. 2010, 44, 433-438. https://doi.org/10.3103/S0361521910060133
[19 Ladola, Y.S.; Kadam, S.V.; Hareendran, K.N.; Chowdhury, S.; Biswas, S.; Roy, S.B.; Pandit, A.B. Analysis of Uranium Leaching Process and Effect of Cake Washing on Uranium Recovery. J. Mat. Sci. Eng. Adv. Tech. 2014, 10, 63-75.
[20] Cheru, M.S., del Rosario, A.V.; Yimam, A.; Tadesse, B.; Berhe, G.G. Hydrometallurgical Removal of Uranium and Thorium from Ethiopian Tantalite Ore. Phys. Prob. Min. Proc., 2019, 55, 448-457. https://doi.org/10.5277/ppmp18153
[21] Horkay, F.; Basser, P.J.; Hecht, A.-M.; Geissler, E. Structural Investigations of a Neutralized Polyelectrolyte Gel and an Associating Neutral Hydrogel. Polymer 2005, 46, 4242-4247. https://doi.org/10.1016/j.polymer.2005.02.054
[22] Kondrashova, Yu.; Safronov, A. Proceedings of 16th Russian Youth Conference Devoted to 85 Years of Birth of Prof. Kochergin V.P. Russia, Ekaterinburg, 2006; p 232.
[23] Kim, S.J.; Yoon, S.G.; Kim, S.I. Effect of the Water State on the Electrical Bending Behavior of Chitosan/Poly(diallyldimethylammonium Chloride) Hydrogels in NaCl Solutions. J. Polym. Sci. B 2004, 42, 914-921. https://doi.org/10.1002/polb.10778
[24] Chen, L.; Yu, X.; Li, Q. Reswelling Behavior of Polycation Hydrogels Carrying Charges on the Chain Backbone by Two-Step Surfactant Bindings. J. Appl. Polym. Sci. 2006, 102, 3791-3794. https://doi.org/10.1002/app.24747
[25] Sitnikova, N.; Malyshkina, I.; Gavrilova, N.; Philippova, O. Proceedings of 4th International Symposium on Molecular Order and Mobility in Polymer Systems, Russia, St. Petersburg, 2002; p 229.
[26] Alimbekova, B.T.; Korganbayeva, Zh.K.; Himersen, H.J.; Kondaurov, R.G.; Jumadilov, T.K. Features of Polymethacrylic Acid and Poly-2-Methyl-5-Vinylpyridine Hydrogels Remote Interaction in an Aqueous Medium. J. Chem. Chem. Eng. 2014, 3, 265-269
[27] Jumadilov, T. Mutual Activation and High Selectivity of Polymeric Structures in Intergel Systems. Abstracts of Papers of Third International Caucasian Symposium on Polymers & Advanced Materials, Tbilisi, Georgia, September 1-4, 2013; Iv. Javakhishvili Tbilisi State University: Tbilisi, 2013, p 43.
[28] Jumadilov, T. Electrochemical and Conformational Behaviour of Intergel Systems Based on the Rare Crosslinked Polyacid and Polyvynilpyrydines. Conference of Lithuanian Chemical Society “Chemistry and Chemical Technology”, Lithuania, Kaunas, 2014; pp 226-229.
[29] Alimbekova, B.T.; Jumadilov, T.K.; Korganbayeva, Zh.K. Some Features of Polymer Hydrogels Interaction with Low Molecular Salts. Bull. d'EUROTALENT-FIDJIP 2013, 5, 28-32.
[30] Erzhet, B.; Jumadilov, T.K.; Korganbayeva, ZhK. Electrochemical and Volume-Gravimetric Properties of Intergel System Based on Polyacrylic Acid and Poly-4-Vinylpyridine Hydrogels. Bull. d'EUROTALENT-FIDJIP 2013, 5, 41-45.
[31] Jumadilov, T.; Kaldayeva, S.; Kondaurov, R.; Erzhan, B.; Erzhet, B. Mutual Activation and High Selectivity of Polymeric Structures in Intergel Systems. In High Performance Polymers for Engineering Based Composites; CRC Press: Boca Raton, 2015; pp 111-119.
[32] Jumadilov, T. Effect of Remote Interraction of Polymeric Hydrogels in Innovative Technology. Ind. Kazakhstan, 2011, 2, 70-72.
[33] Bekturov, E.; Suleimenov, I. Polimernie Hydrogeli; Nauka: Moskwa, 1998.
[34] Jumadilov, T.; Kondaurov, R.; Abilov, Zh.; Grazulevicius, J.V.; Akimov, A.A. Influence of Polyacrylic Acid and poly-4-Vinylpyridine Hydrogels Mutual Activation in Intergel System on their Sorption Properties in Relation to Lanthanum (III) Ions. Pol. Bul. 2017, 74, 4701-4713. https://doi.org/10.1007/s00289-017-1985-3
[35] Jumadilov, T., Abilov, Zh., Kondaurov, R. Intergel Systems: Highly Effective Instruments for Rare Earth Elements Extraction from Industrial Solutions. In Chemical Engineering of Polymers. Production of Functional and Flexible Materials Composites; AAP Press: Sydney, 2017; pp 267-279. https://doi.org/10.1201/9781315365985-20
[36] Jumadilov, T.K.; Kondaurov, R.G.; Kozhabekov, S.S.; Tolegen, G.A.; Eskalieva, G.K.; Khakimzhanov, S.A. Influence of Poly-Acrylic Acid Hydrogel’s Swelling Degree on Sorption Ability of Intergel System Polyacrylic Acid Hydrogel–Poly-4-vinylpyridine Hydrogel in Relation to Neodymium Ions. Chem. Tech. Met. 2018, 53, 88-93.
[37] Tereshenkova, A.A; Statkus, M.A.; Tihomirova, T.I.; Tsizin, G.I. Sorption Concentrating of Lanthanum on Modified Low-Polar Sorbents. Moscow Univ. Bull. 2013, 54, 203-209.
[38] Praktikum po Phyziko-Khimicheskim Metodam Analiza; Petruhin, O., Ed.; Khimia: Moskwa, 1987.