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Порівняльна характеристика сорбційної активності гідрогелів поліметакрилової кислоти стосовно йонів лантану в деяких міжгелевих системах

Talkybek Jumadilov1, Zamira Malimbayeva2, Leila Yskak2, Oleg Suberlyak3, Ruslan Kondaurov1, Aldan Imangazy1, Laura Agibayeva4, Auez Akimov1, Khuangul Khimersen1, Akerke Zhyzbayeva1
Affiliation: 
1JSC «Institute of Chemical Sciences after A.B. Bekturov», 106, Sh. Valikhanov St., 050010 Almaty, the Republic of Kazakhstan 2Kazakh National Women’s Teacher Training University 99, Aiteke Bi St., 050000 Almaty, the Republic of Kazakhstan 3 Lviv Polytechnic National University, Lviv, Ukraine 12, Bandera St., 79013 Lviv, Ukraine 4Al-Farabi Kazakh National University, 71, Al-Farabi Ave, 050001Almaty, the Republic of Kazakhstan r-kondaurov@mai.ru
DOI: 
https://doi.org/10.23939/chcht16.03.418
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Keywords:

Abstract: 
Вивчено явища віддаленої взаємодії в міжгелевих системах гідрогель поліметакрилової кислоти – гідрогель полі-4-вінілпіридину (hPMAA-hP4VP) та гідрогель поліметакрилової кислоти – гідрогель полі-2-метил-5-вінілпіридину (hPMAA-hP2M5VP). Встановлено, що питома електропровідність, рН та ступінь набухання гідрогелів PMAA, P4VP та P2M5VP зменшуються під час сорбції йонів лантану за участю міжгелевих систем. Визначено, що сорбційні властивості міжгелевих систем значно збільшуються (до 30 %) у порівнянні з окремими гідрогелями РМАА, Р4VP та Р2М5VP, що вказує на факт високої йонізації під час взаємної активації полімерів. Максимальна сорбція йонів лантану відбувається за співвідношень 17% hPMAA:83% hP4VP та 50% hPMAA:50% hP2M5VP. За допомогою ІЧ спектроскопії встановлено сорбцію рідкісноземельного металу міжгелевими системами. Показана важливість можливого застосування міжгелевих систем на основі рідкоземельних зшитих полімерних гідрогелів кислотної та основної природи для створення нових інноваційних сорбційних технологій у гідрометалургії.
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