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Використання хімічно модифікованого хітозану для адсорбційного вилучення іонів токсичних металів у водних розчинах

Fadi Alakhras1, Huda Alghamdi1, Rabia Rehman2
Affiliation: 
1 Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, PO Box 1982, Dammam 31441, Saudi Arabia 2 Center for Inorganic Chemistry, Shcool of Chemistry, University of Punjab, Quaid-e-Campus, Lahore, Pakistan fadialakhras@gmail.com
DOI: 
https://doi.org/10.23939/chcht17.02.407
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Keywords:

Abstract: 
конденсації було успішно здійснено хімічну модифікацію хітозану з використанням трьох похідних, а саме: 3 гідроксибензальдегіду, 2,3-дигідроксибензальдегіду та 3,5-ди-трет-бутил-2-гідроксибенз¬альдегіду. Методи інфрачер-воної спектроскопії з перетворенням Фур’є (FTIR), сканувальної електронної мікроскопії (СЕМ), площі поверхні Брунауера–Еммета–Теллера (БЕТ), термогравіметричного аналізу (ТГА) та рентгенівської дифракції (XRD) були виконані для характеризації адсорбентів-основ Шиффа – похідних хітозану. Досліджено ефективність синтезованих адсорбентів у вилученні іонів кобальту і нікелю з водного розчину та проаналізовано експериментальні дані за допомогою ізотермічної і кінетичної моделей. Площа поверхні за БЕТ хімічно модифікованого хітозану була значно збільшена до 125,83 м2  г-1 з мезопористими характери-стиками. Максимальне поглинання було зафіксовано за pH 5-6, a максимальна здатність вилучення становила 243,90 мг  г-1 для іонів кобальту та 166,67 мг  г-1 для іонів нікелю. Кінетичні дані були краще описуються за допомогою псевдо-другого порядку.
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