Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Solid Solutions Formation Mechanism in Cordierite-Mullite Glass Materials During Ceramization

Оksana Savvova1, Hennadiy Voronov1, Оlena Babich2, Oleksii Fesenko1, Sviatoslav Riabinin3, Robert Bieliakov4
Affiliation: 
1 O.M.Beketov National University of Urban Economy in Kharkiv, 17, Bazhanova St., 61002, Kharkiv, Ukraine 2 Research Institution "Ukrainian Scientific Research Institute of Ecological Problems" 6, Bakulina St., 61166 Kharkiv, Ukraine 3 National Technical University “Kharkiv Polytechnic Institute” 2, Kyrpychova St., 61002 Kharkiv, Ukraine 4 Military Institute of Telecommunications and Information Technologies 45/1, Moskovskaya St., 01011 Kiev, Ukraine savvova_oksana@ukr.net
DOI: 
https://doi.org/10.23939/chcht14.04.583
AttachmentSize
PDF icon full_text.pdf1.3 MB
Abstract: 
Relevance of the development of high-strength glass-ceramic coatings obtained by resource-saving technology for protective elements has been established. Structure formation mechanism in magnesium aluminosilicate glasses during heat treatment has been analyzed. Selection of the system was substantiated, model glasses and glass-ceramic materials on its base have been developed. Patterns of structure regularity and formation of the phase composition of glass-ceramic materials during their ceramization have been investigated. It was established that the presence of crystalline phase of mullite after melting leads to formation of the primary crystals and allows the formation of the fine crystalline structure under conditions of the low-temperature heat treatment at the nucleation stage. Developed high-strength glass ceramic materials can be used as a base in creating protective elements for special-purpose vehicles by energy-saving technology.
References: 

[1] Carter B., Norton G.: Ceramic Materials Science and Engineering. Springer, New York, London 2007.

[2] Beall G.: Pat. US 7465687 B2, Publ. Oct. 01, 2015.

[3] Logvinkov S.: Tverdofaznye Reakcii Obmena v Tekhnologii Keramiki. HNJeU, Kharkіv 2013.

[4] Toropov N., Poraj-Koshic E.: Strukturnye Prevrashhenia v Steklakh pri Povyshennykh Temperaturakh. Nauka, Leningrad 1965.

[5] Kranold R., Lemcbe R.: 18th Іnt. Соngress Glass, San Francisco, California, ІСG 18 Мееt. Сuide, Westerville, Ohio 1998, 59.

[6] Hong S.-H., Messing G.: J. Am. Ceramic Soc., 1997, 80, 1551. https://doi.org/10.1111/j.1151-2916.1997.tb03015.x
https://doi.org/10.1111/j.1151-2916.1997.tb03015.x

[7] Mirwald P.: Am. Min., 1982, 67, 277.
https://doi.org/10.1007/BF02721167

[8] Miyashiro A.: Am. J. Sci., 1957, 255, 43. https://doi.org/10.2475/ajs.255.1.43
https://doi.org/10.2475/ajs.255.1.43

[9] Wong-Ng W., McMurdie H., Hubbard C., Mighell A.: J. Res. Natl. Inst. Stand. Technol., 2001, 106, 1013. https://doi.org/10.6028/jres.106.052
https://doi.org/10.6028/jres.106.052

[10] Vogel W.: Glass Chemistry. Springer-Verlag,  New York, Berlin 1994.

[11] Pimkov Ju., Filatova N., Kosenko N., Bezrukov R.: Ogneupory i Tekhn. Keramika, 2014, 4-5, 22.

[12] Al-Harbi O., Hamzawy E.: Ceram. Int., 2014, 40, 5283. https://doi.org/10.1016/j.ceramint.2013.10.101
https://doi.org/10.1016/j.ceramint.2013.10.101