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Селективне видалення ртуті(ІІ) з використанням гідрогелів, приготовлених за допомогою гамма-випромінювання

Dursun Saraydın1, Ebru Şahin Yıldırım2, Erdener Karadağ3
Affiliation: 
1 Sivas Cumhuriyet University, Science Faculty, Chemistry Department, Sivas, Turkey 2 Sivas Cumhuriyet University, Imranlı Vocational School, Imranlı, Sivas, Turkey 3 Adnan Menders University, Science & Letter Faculty Chemistry Department, Aydın, Turkey saraydin@cumhuriyet.edu.tr; dsaraydin@gmail.com
DOI: 
https://doi.org/10.23939/chcht16.03.345
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Abstract: 
Для селективного видалення ртуті(II) із використанням випромінювання синтезували гідрогелі 2-гідроксиетилметакрилат (HM) та 2-гідроксиетилметакрилат/акриламід (HM/ACR). Проведено дослідження гідрогелів в процесах набухання, дифузії та зв'язування. Встановлено, що параметри набухання для системи HM/ACR-Hg2+ є вищими, ніж для систем HM-Hg2+. Визначено, що зв'язування ртуті відноситься до C-типу для HM та L-типу для гідрогелів HM/ACR. Параметри зв'язування розраховували за допомогою моделей Фрейндліха, Ленгмюра та Генрі. Досліджено вплив концентрації Hg2+, дози випромінювання, вмісту акриламіду, температури та протийонів. Встановлено, що зв'язування та набухання HM збільшуються із включенням акриламіду. Доведено, що гідрогелі HM/ACR поглинають лише Hg2+ і не поглинають йони важких металів.
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