Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Тонкі плівки Аg з листя pelargonium zonale за допомогою зеленої хімії

Nora Elizondo-Villarreal1, Rubén O. Torres-Barrera1, Rodrigo Arriaga-Garza1, Luz-Hypatia Verástegui-Domínguez1, Rodolfo Cortés2, Víctor M. Castaño3
Affiliation: 
1 Research Center of Physical and Mathematical Sciences (CICFIM), Physical and Mathematical Sciences School, Universidad Autónoma de Nuevo León (UANL), San Nicolás de los Garza, N. L., México. Código Postal: 66455 2 CICESE, Monterrey, PIIT, Apodaca, N. L., México 3 Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, Querétaro 76230, México nelizond@yahoo.com; vmcastano@unam.mx
DOI: 
https://doi.org/10.23939/chcht17.01.133
AttachmentSize
PDF icon full_text.pdf571.31 KB
Abstract: 
Тонкі плівки Ag успішно одержано за допомогою методу зеленої хімії з наночастинок срібла, отриманих через реакцію екстракту листя Pelargonium Zonale з нітратом срібла. Іони нітрату срібла були відновлені до атомів срібла через відновлення речовинами-стабілізаторами, які містяться в екстракті листя Pelargonium Zonale. Отримані атоми нуклеюються в невеликі кластери, які виростають у наночастинки, і, нарешті, утворюють однорідну тонку плівку срібла на скляній підкладці. Отримані наноструктуровані тонкі плівки були охарактеризовані за допомогою профілометрії, дифракції рентгенівських променів, атомно-силової електронної мікроскопії, УФ-спектроскопії та трансмісійної електронної мікроскопії.
References: 

[1] Fu, Y.; Li, G.; Tian, M.; Wang, X.; Zhang, L. & Wang, W. Preparation of Silver Nanoparticles Immobilized Fibrillar Silicate by Poly (dopamine) Surface Functionalization. J. Appl. Polym. Sci. 2014, 131, 39859. https://doi.org/10.1002/app.39859
[2] de Faria, A.F.; Martinez, D.S.T.; Meira, S.M.M.; De Moraes, A.C.M.; Brandelli, A.; Souza Filho, A.G.; Alves, O.L. Anti-adhesion and Antibacterial Activity of Silver Nanoparticles Sup-ported on Graphene Oxide Sheets. Colloids Surf. B 2014, 113, 115-124. https://doi.org/10.1016/j.colsurfb.2013.08.006
[3] Nilius, N.; Risse, T.; Schauermann, S.; Shaikhutdinov, S. Ster-rer, M.; Freund, H.-J. Model Studies in Catalysis. Top. Catal. 2011, 54, 4-12. https://doi.org/10.1007/s11244-011-9626-9
[4] Hariprasad, E.; Radhakrishnan, T. P. Palladium Nanoparticles – Embedded Polymer thin Film “Dip Catalyst” for Suzuki – Miyaura Reaction. ACS Catal. 2012, 2, 1179-1186. https://doi.org/10.1021/cs300158g
[5] Guiet, A.; Reier, T.; Heidary, N.; Felkel, D.; Johnson, B.; Vai-nio, U.; Schlaad, H.; Aksu, Y.; Driess, M.; Strasser, P. et al. A One-Pot Approach to Mesoporous Metal Oxide Ultrathin Film Electrodes Bearing One Metal Nanoparticle per Pore with Enhanced Electrocatalytic Properties. Chem. Mater. 2013, 25, 4645-4652. https://doi.org/10.1021/cm401135z
[6] Gooding, J.J.; Alam, M.T.; Barfidokht, A.; Carter, L. Nanopar-ticle Mediated Electron Transfer Across Organic Layers: From Current Understanding to Applications. J Braz. Chem. Soc. 2014, 25, 418-426. http://dx.doi.org/10.5935/0103-5053.20130306
[7] Mubeen, S.; Hernandez-Sosa, G.; Moses, D.; Lee, J.; Moskovits, M. Plasmonic Photosensitization of a Wide Band Gap Semiconductor: Converting Plasmons to Charge Carriers. Nano Lett. 2011, 11, 5548-5552. https://doi.org/10.1021/nl203457v
[8] Wu, J.-L.; Chen, F.-C.; Hsiao, Y.-S.; Chien, F.-C.; Chen, P.; Kuo, C.-H.; Huang, M.H.; Hsu, C.-S. Surface Plasmonic Effects of Metallic Nanoparticles on the Performance of Polymer Bulk
Heterojunction Solar Cells. ACS Nano 2011, 5, 959-967. https://doi.org/10.1021/nn102295p
[9] Brandon, M.P.; Ledwith, D.M.; Kelly, J.M. Preparation of Saline-Stable, Silica-Coated Triangular Silver Nanoplates of Use for Optical Sensing. J. Colloid Interface Sci. 2014, 415, 77-84. http://dx.doi.org/10.1016/j.jcis.2013.10.017
[10] Akjouj, A.; Lévêque, G.; Szunerits, S.; Pennec, Y.;
Djafari-Rouhani, B.; Boukherroub, R.; Dobrzynski, L. Nanometal Plasmonpolaritons. Surf. Sci. Rep. 2013, 68, 1-67. https://doi.org/10.1016/j.surfrep.2012.10.001
[11] Dinda, E.; Rashid, M. H.; Biswas, M.; Mandal, T. K.
Redox-Active Ionic-Liquid-Assisted One-Step General Method for Preparing Gold Nanoparticle Thin Films: Applications in Refractive Index Sensing and Catalysis. Langmuir 2010, 26, 17568-17580. https://doi.org/10.1021/la103084t
[12] Bernardo-Gavito, R.; Serrano, A.; García, M.A.; Miranda, R.; Granados, D. Local Characterization of the Optical Properties of Annealed Au Films on Glass Substrates. J. Appl. Phys. 2013, 114, 164312. https://doi.org/10.1063/1.4826902
[13] Ye, J.; Bonroy, K.; Nelis, D.; Frederix, F.; D'Haen, J.; Maes, G.; Borghs, G. Enhanced Localized Surface Plasmon Resonance Sensing on Three-Dimensional Gold Nanoparticles Assemblies. Colloids Surf. A: Physicochem. Eng. Asp. 2008, 321, 313-317. https://doi.org/10.1016/j.colsurfa.2008.01.028
[14] Brostow, W.; Hagg Lobland, H.E. Materials: Introduction and Applications; John Wiley & Sons, 2017.
[15] Skіba, M.; Vorobyova, V.; Kovalenko, I.; Shakun, A. Synthesis of Tween-Coated Silver Nanoparticles by a Plasma-Chemical Method: Catalytic and Antimicrobial Activities. Chem. Chem. Technol. 2020, 14, 297-303. https://doi.org/10.23939/chcht14.03.297
[16] Saldan, I.; Dobrovetska, O.; Makota O. Nanotechnologies for Preparation and Application of Metallic Nickel. Chem. Chem. Technol. 2022, 16, 74-94. https://doi.org/10.23939/chcht16.01.074
[17] Schneid, A.C.; Pereira, M.B.; Horowitz, F.; Mauler R.S.; Matte, C.R.; Klein, M.P.; Hertz, P.F.; Costa, T.M.H.; de Menezes, E.W.; Benvenutti, E.V. Silver Nanoparticle Thin Films Deposited on Glass Surface Using an Ionic Silsesquioxane as Stabilizer and as Crosslinking Agent. J. Braz. Chem Soc. 2015, 26, 1004-1012. http://dx.doi.org/10.5935/0103-5053.20150066
[18] Gaspera, E.D.; Karg, M.; Baldauf, J.; Jasieniak, J.; Maggioni, G.; Martucci, A. Au Nanoparticle Monolayers Covered with Sol–Gel Oxide Thin Films: Optical and Morphological Study. Langmuir 2011, 27, 13739-13747. https://doi.org/10.1021/la2032829
[19] Elizondo N.; Segovia P.; Coello V.; Arriaga J.; Belmares S.; Alcorta A.; Hernández F.; Obregrón R.; Torres E.; Paraguay E. Green Synthesis and Characterizations of Silver and Gold Nanopar-ticles. In Green Chemistry – Environmentally Benign Approaches; Mishra, N.K., Ed.; InTech, 2012; pp 139-156.
[20] Dwivedi A.D.; Gopal, K. Biosynthesis of Silver and Gold Nanoparticles Using Chenopodium album Leaf Extract. Colloids Surf. A: Physicochem. Eng. Asp. 2010, 369, 27-33. https://doi.org/10.1016/j.colsurfa.2010.07.020
[21] Castro L.; Blázquez M.L.; González F.; Muñoz J.A.; Ballester A. Extracellular Biosynthesis of Gold Nanoparticles Using Sugar Beet Pulp. Chem. Eng. J. 2010, 164, 92-97. https://doi.org/10.1016/j.cej.2010.08.034
[22] Ghodake, G.S.; Deshpande, N.G.; Lee, Y.P.; Jin, E.S. Pear Fruit Extract-Assisted Room-Temperature Biosynthesis of Gold Nanoplates. Colloids Surf. B 2010, 75, 584-589. https://doi.org/10.1016/j.colsurfb.2009.09.040
[23] Dubey, S.P.; Lahtinen, M.; Sillanpää, M. Tansy Fruit Mediated Greener Synthesis of Silver and Gold Nanoparticles. Process Biochem. 2010, 45, 1065-1071. https://doi.org/10.1016/j.procbio.2010.03.024
[24] Bar, H.; Bhui, D.K.; Sahoo, G.P.; Sarkar, P.; De, S.P.; Misra, A. Green Synthesis of Silver Nanoparticles Using Latex of Jatropha curcas. Colloids Surf. A: Physicochem. Eng. Asp. 2009, 339, 134-139. https://doi.org/10.1016/j.colsurfa.2009.02.008
[25] Dhulappanavar, G.; Hungund, B.; Ayachit, N.; Bhakat, A.; Singh P.P.; Priya S.; Pawar J.; Vinchurkar P.; Henry R. Characterization of Silver Nanoparticles Biosynthesized Using Lemon Juice. International Conference on Nanoscience, Engineering and Technology (ICONSET) 2011, 28-30 November 2011, Chennai, India, 258-262. https://doi.org/10.1109/ICONSET.2011.6167936
[26] Vala, A.K.; Chudasama, B.; Patel, R.J. Green Synthesis of Silver Nanoparticles Using Marine-Derived Fungus Aspergillus niger. Micro Nano Lett. 2012, 7, 859-862. https://doi.org/10.1049/mnl.2012.0403
[27] Sangappa, M.; Thiagarajan, P. Mycobiosynthesis and
Characterization of Silver Nanoparticles from Aspergillus Niger: a Soil Fungal Isolate. International Journal of Life Sciences Biotechnology and Pharma Research 2012, 1, 282-289.
[28] Bunghez, I.R.; Ghiurea, M.; Faraon,V.; Ion, R.M. Green Synthesis of Silver Nanoparticles Obtained from Plant Extracts and their Antimicrobial Activites. J. Optoelectron. Adv. Mater. 2011, 13, 870-873.
[29] Rangel, R.; Chávez Chávez, L.; Meléndrez, M.; Batolo-Pérez, P.; Pérez-Tijerina E.G.; García-Méndez, M. Ce(1-x)MXO2,{M=Ru, In} Solid Solutions as Novel Gas Sensors for CO Detection. J. Nano Res. 2011, 14, 135-143. https://doi.org/10.4028/www.scientific.net/JNanoR.14.135
[30] Korotcenkov, G. Thin Metal Films. In Handbook of Gas Sensor Materials. Properties, Advantages and Shortcomings for Applications; Potyrailo, R.A., Ed.; Springer: New York, 2013; pp.153-166. https://doi.org/10.1007/978-1-4614-7165-3
[31] Seshan, K. Thin Film deposition, equipment and processing. In Handbook of Thin Film Deposition, 3rd Ed.; Seshan, K., Ed.; Elsevier, 2012; pp. 55-256.
[32] Hanaor, D.A.H.; Triani, G.; Sorrell, C.C. Morphology and
Photocatalytic Activity of Highly Oriented Mixed Phase Titanium Dioxide Thin Films. Surf. Coat. Technol. 2011, 205, 12, 3658-3664. https://doi.org/10.1016/j.surfcoat.2011.01.007
[33] Jilani, A.; Abdel-wahab, M.S.; Hammad, A. H. Advance
Deposition Techniques for Thin Film and Coating. In Modern Technologies for creating the thin-film Systems and Coatings; Nikitenkov, N.N., Ed.; Intech, 2017; pp 137-150. http://dx.doi.or/10.5772/65702
[34] Bunghez, I.R.; Ion, R.M.; Pop, S.; Ghiurea, M.; Dumitriu, I.; Fierascu, R.C. Silver Nanoparticles Fabrication Using Marine Plant (Mayaca Fluviatilis) Resources. Analele Ştiinţifice ale Universităţii „Alexandru Ioan Cuza”, Secţiunea Genetică şi Biologie Moleculară, 2010, 11, 89-94.
[35] Mulfinger, L.; Solomon, S.D.; Bahadory, M.; Jeyarajasingam, A.V.; Rutkowsky S.A.; Boritz, C. Synthesis and Study of Silver Nanoparticles. J. Chem. Educ. 2007, 84, 322-325. https://doi.org/10.1021/ed084p322
[36] Binnig, G.; Quate, C.F.; Gerber, Ch. Atomic Force Microscope. Phys. Rev. Lett. 1986, 56, 930-933. https://doi.org/10.1103/PhysRevLett.56.930
[37] Wickramasinghe, H.K. Scanned-Probe Microscopes. Sci. Am. 1989, 261, 98-105. https://www.jstor.org/stable/24987445
[38] Rawat, M.A Review on Green Synthesis and Characterization of Silver Nanoparticles and their Applications: A Green Nanoworld. World J Pharm Pharm Sci. 2016, 5, 730-762. DOI: 10.20959/wjpps20167-7227
[39] Balchin, M.L.; Houghton, P. J.; Woldemariam, T.Z. Elaeocarpidine Alkaloids from Pelargonium Species (Geraniaceae). Nat. Prod. Lett. 2006, 8, 105-112. https://doi.org/10.1080/10575639608043248

[40] Jin, X.; Wang, R-S.; Zhu, M.; Jeon, B.W.; Albert, R.; Chen, S.; Assmanna S.M. Abscisic Acid–Responsive Guard Cell Metabolomes of Arabidopsis Wild-Type and gpa1 G-Protein Mutants , Plant Cell 2013, 25, 4789-4811. https://doi.org/10.1105/tpc.113.119800
[41] Nadeem, M.; Abbasi, B.H.; Younas, M.; Ahmad, W.; Khan T. A Review of the Green Syntheses and Anti-Microbial Applications of Gold Nanoparticles. Green Chem. Lett. Rev. 2017, 10, 216-227. https://doi.org/10.1080/17518253.2017.1349192
[42] Rasheed, T.; Bilal, M.; Iqbal, H.M.N.; Li, C. Green Biosynthesis of Silver Nanoparticles Using Leaves Extract of Artemisia vulgaris and their Potential Biomedical Applications. Colloids Surf. B: Biointerfaces 2017, 158, 408-415. https://doi.org/10.1016/j.colsurfb.2017.07.020
[43] Bilal, M.; Rasheed, T.; Iqbal, H.M.N.; Li, C.; Hu, H.; Zhang, X. Development of Silver Nanoparticles Loaded Chitosan-Alginate Constructs with Biomedical Potentialities. Int. J. Biol. Macromol. 2017, 105, 393-400. https://doi.org/10.1016/j.ijbiomac.2017.07.047
[44] Latté, K.P.; Kolodziej, H. Antioxidant Properties of Phenolic Compounds from Pelargonium reniforme. J. Agric. Food Chem. 2004, 52, 4899-4902. https://doi.org/10.1021/jf0495688
[45] Carmona, E.R.; Benito, N.; Plaza, T.; Recio-Sánchez, G. Green Synthesis of Silver Nanoparticles by Using Leaf Extracts from the Endemic Buddleja globosa Hope. Green Chem. Lett. Rev. 2017, 10, 250-256. https://doi.org/10.1080/17518253.2017.1360400
[46] Lis-Balchin, M. History of nomenclature, usage and cultivation of Geranium and Pelargonium species. In Geranium and
Pelargonium; Lis-Balchin, M., Ed.; Taylor & Francis, 2002; pp 5-10.
[47] Wei, H.; Eilers, H. From Silver Nanoparticles to thin Films: Evolution of Microstructure and Electrical Conduction on Glass Substrates. J. Phys. Chem. Solids 2009, 70, 459-465. https://doi.org/10.1016/j.jpcs.2008.11.012
[48] Kiesow, A.; Morris, J.E.; Radehaus, C.; Heilmann A. Switching Behavior of Plasma Polymer Films Containing Silver Nanoparticles. J. Appl. Phys. 2003, 94, 6988-6990. https://doi.org/10.1063/1.1622990
[49] Ratke, L.; Voorhees, P.W. Growth and Coarsening: Ostwald Ripening in Material Processing; Springer, Berlin, Heidelberg, 2002.