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Теплофізичні властивості композиційних металонаповнених кополімерів полівінілпіролідону

Oleksandr Grytsenko1, Mykhaylo Bratychak Jr.1, Ludmila Dulebova2, Ivan Gajdoš2
Affiliation: 
1 Lviv Polytechnic National University, 12, St. Bandera Str., 79013 Lviv, Ukraine 2 Technical University of Kosice, 74 Mäsiarska, 04001 Kosice, Slovakia oleksandr.m.grytsenko@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht18.01.037
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Abstract: 
Досліджено вплив присутності дрібнодисперсних металевих наповнювачів різної природи (Zn, Co, Ni) на теплофізичні характеристики (теплостійкість за Віка, температура склування) блочних кополімерів полівінілпіролідону з 2-гідроксіетилметакрилатом. Встановлено, що теплостійкість одержаних композитів є значно вищою за теплостійкість ненаповнених кополімерів і лежить у межах 360-395К залежно від природи та вмісту металевого наповнювача. Зміна теплостійкості корелює зі зміною температури склування, яку оцінювали на основі результатів термомеханічного та динамічного механічного термічного аналізів. Результати роботи є додатковим джерелом характеристики структури металонаповнених кополімерів і підтверджують участь частинок металевого наповнювача у формуванні вузлів просторової сітки кополімеру, а також доводять факт утворення різної структури полімерної сітки в міжфазному шарі на поверхні металевої частинки і в об’ємі полімеру.
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