Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Перспективи очищення водних середовищ від полютантів активованими ультразвуком бентонітами

Viktoria Kochubei1, Yaroslava Yaremchuk2, Myroslav Malovanyy3, Svitlana Yaholnyk3, Andriy Slyuzar1
Affiliation: 
1 Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 12 S. Bandera St., Lviv 79013, Ukraine 2 Іnstitute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, 3a Naukova St., Lviv 79060, Ukraine 3 Viacheslav Chornovil Institute of Sustainable Development, Lviv Polytechnic National University, 12 S. Bandera St., Lviv 79013, Ukraine myroslav.mal@gmail.com
DOI: 
https://doi.org/10.23939/chcht17.04.870
AttachmentSize
PDF icon full_text.pdf574.02 KB
Abstract: 
У роботі проаналізовані перспективи застосування природних сорбентів у природоохоронних технологіях. Об’єктом дослідження була глиниста порода з лівого берега верхів’я річки Південний Буг (околиці м. Хмельницький). Збагачення породи монтморилонітом проводили центрифугуванням суспензії глини з отриманням фракції ≤ 5 мкм. Мінеральний склад збагаченої глини встановлювали за даними Х-променевого дифрактометричного та комплексного термічного аналізів. Хімічну активацію збагаченої глини проводили 5 % водним розчином NaCl, фізичну активацію – дією ультразвуку. За результатами фотоколориметричних досліджень знайдено катіонообмінну ємність збагачених природної та активованої ультразвуком глин відносно барвника метиленового блакитного. Здатність катіонів барвника сорбуватись міжшаровим простором монтморилоніту підтверджували даними Х-променевого фазового та комплексного термічного аналізів.
References: 

[1] Lazaruk, Y.; Karabyn, V. Shale gas in Western Ukraine: Perspectives, Resources, Environmental and Technogenic Risk of Production. Pet. Coal 2020, 62, 836–844. https://sci.ldubgd.edu.ua:8080/jspui/handle/123456789/7543
[2]Vaskina, I.; Plyatsuk, L.; Vaskin, R.; Ablieieva, I.; Sydorenko S. Patterns of Pollutants Distribution from Vehicles to the Roadside Ecosystems. In Advances in Design, Simulation and Manufacturing II. DSMIE 2019. Lecture Notes in Mechanical Engineering; Springer, Cham.; pp 893–902. http://dx.doi.org/10.1007/978-3-030-22365-6_89
[3] Starodub, Y.; Karabyn, V.; Havrys, A.; Shainoga, I.; Samberg, A. Flood Risk Assessment of Chervonograd Mining-Industrial District. In Remote Sensing for Agriculture, Ecosystems, and Hydrology XX (Vol. 10783), Neale, C.M.U.; Maltese, A., Eds.; SPIE: Bellingham, Washington, 2018. https://doi.org/10.1117/12.2501928
[4] Tymchuk, I.; Shkvirko, O.; Sakalova, H.; Malovanyy, M.; Dabizhuk, T.; Shevchuk, O.; Matviichuk, O.; Vasylinych, T. Wastewater a Source of Nutrients for Crops Growth and Development. J. Ecol. Eng. 2020, 21, 88–96.
http://dx.doi.org/10.12911/22998993/122188
[5] Rusyn, I.B.; Moroz, O.M.; Karabyn, V.V.; Kulachkovskyi, O.R.; Hudz, S.P. Biodegradation of oil Hydrocarbons by Candida yeast. J. Microbiol. 2003, 65, 36–42.
[6] Knysh, I.; Karabyn, V. Heavy Metals Distribution in the Waste Pile Rocks of Chervonogradska Mine of the Lviv-Volyn Coal Basin (Ukraine). Pollution Research 2014, 33, 663–670.
[7] Gumnitsky, J.; Sabadash, V.; Matsuska, O.; Lyuta, O.; Hyvlud, A.; Venger, L. Dynamics of Adsorption of Copper Ions in Fixed-Bed Column and Mathematical Interpretation of the First Stage of the Process. Chem. Chem. Technol. 2022, 16, 267–273.
https://doi.org/10.23939/chcht16.02.267
[8] Hyvlud, A.; Sabadash,V.; Gumnitsky, J.; Ripak, N. Statics and Kinetics of Albumin Adsorption by Natural Zeolite. Chem. Chem. Technol. 2019, 13, 95–100. https://doi.org/10.23939/chcht13.01.095
[9] Sabadash, V.; Gumnitsky, J.; Hyvlyud, A. Mechanism of Phosphates Sorption by Zeolites Depending on Degree of their Substitution for Potassium Ions. Chem. Chem. Technol. 2016, 10, 235–240. https://doi.org/10.23939/chcht10.02.235
[10] Danchenko, Y., Andronov, V.; Kariev, A.; Lebedev, V.; Rybka, E.; Meleshchenko, R.; Yavorska, D. Research into Surface Properties of Disperse Fillers Based on Plant Raw Materials. EasternEuropean J. Enterp. Technol. 2017, 5, 20–26. https://doi.org/10.15587/1729-4061.2017.111350
[11] Soloviy, Ch.; Malovanyy, M.; Bordun, I.; Ivashchyshyn, F.; Borysiuk, A.; Kulyk, Y. Structural, Magnetic and Adsorption Characteristics of Magnetically Susceptible Carbon Sorbents Based on Natural Raw Materials. J. Water Land Dev. 2020, 47, 160–168. https://doi.org/10.24425/jwld.2020.135043
[12] Kochubei, V.; Yaholnyk, S.; Bets, M.; Malovanyy, M. Use of Activated Clinoptilolite for Direct Dye-Contained Wastewater Treatment. Chem. Chem. Technol. 2020, 14, 386–393. https://doi.org/10.23939/chcht14.03.386
[13] Kochubei, V.V.; Yaholnyk, S.G.; Kniaz, S.V.; Parashchuk, L.Y.; Malovanyy, M.S. Research into the Influence of Activation Conditions of Transcarpathian Clinoptilolite on its Adsorption Capacity. Voprosy khimii i khimicheskoi tekhnologii 2020, 4, 80–87. https://doi.org/10.32434/0321-4095-2020-131-4-80-87
[14] Malovanyy, M.; Petrushka, K.; Petrushka, I. Improvement of Adsorption-Ion-Exchange Processes for Waste and Mine Water Purification. Chem. Chem. Technol. 2019, 13, 372–376. https://doi.org/10.23939/chcht13.03.372
[15] Lagaly, G.; Ogawa, M.; Dekany, I. Clay Mineral Organic Interactions. In: Handbook of Clay Science; Bergaya, F.; Theng, B.K.G.; Lagaly, G., Eds; Amsterdam: Elsevier, 2006; pp 309–377. https://doi.org/10.1016/S1572-4352(05)01010-X
[16] Rajkiran, R. T.; Kartic, C. K.; Upendra, N. Synthesis and Characterization of Novel Organo-Montmorillonites. Applied Clay Sci. 2008, 38, 203–208. https://doi.org/10.1016/j.clay.2007.05.008
[17] Mockovсiakova, A.; Orolinova, Z.; Skvarla, J. Enhancement of the Bentonite Sorption Properties. J. Hazard. Mater. 2010, 180, 274–281. https://doi.org/10.1016/j.jhazmat.2010.04.027
[18] Borgnino, L.; Avena, M.J.; De Pauli, C.P. Synthesis and Characterization of Fe(III) Montmorillonites for Phosphate Absorption. Colloids Surf. A: Physicochem. Eng. Asp. 2009, 341, 46–52. http://doi.org/10.1016/j.colsurfa.2009.03.037
[19] Menezes, R.R.; Marques, L.N.; Campos, L.A.; Ferreira, H.S.; Santana, L.N.L.; Neves, G.A. Use of Statistical Design to Study the Influence of CMC on the Rheological Properties of Bentonite Dispersions for Water-Based Drilling Fluids. Appl Clay Sci. 2010, 49, 13–20. https://doi.org/10.1016/j.clay.2010.03.013
[20] Vincenzi, S.; Panighel, A.; Gazzola, D.; Flamini, R.; Curioni A. Study of Combined Effect of Proteins and Bentonite Fining on the Wine Aroma Loss. J. Agric. Food Chem. 2015, 63, 2314–2320. https://doi.org/10.1021/jf505657h
[21] Ifa, L.; Wiyani, L.; Nurdjannah, N.; Muhammad, A.; Ghalib, T.; Ramadhaniar, S.; Kusuma, H.S. Analysis of Bentonite Performance on the Quality of Refined Crude Palm Oil's Color, Free Fatty Acid and Carotene: The Effect of Bentonite Concentration and Contact Time. Heliyon 2021, 7, e07230. https://doi.org/10.1016/j.heliyon.2021.e07230
[22] Krasinskyi, V.; Suberlyak, O.; Kochubei, V.; Jachowicz, T.; Dulebova, L.; Zemke, V. Nanocomposites Based on Polyamide and Montmorillonite Obtained from a Solution. Adv. Sci. Technol. Res. J. 2020, 14, 192–198. https://doi.org/10.12913/22998624/122297
[23] Mykhailova, V.A. Non-Metallic Minerals of Ukraine; Kyiv University Publishing House: Kyiv, 2007.
[24] Menier, A. Clays; Springer-Verlag: Berlin, Heidelberg, 2005.
[25] Malovanyi, M.S.; Petrushka, I.M. Ochyshchennia stichnykh vod pryrodnymy dyspersnymy sorbentamy; Department of Lviv Polytechnic, 2012.
[26] Salem, A.; Karimi, L. Physicochemical Variation in Bentonite by Sulfuric Acid Activation. Korean J. Chem. Eng. 2009, 26, 980–984. https://doi.org/10.1007/s11814-009-0162-2
[27] Boichuk, B.; Kuzyk, A.; Sysa, L.; Pastukhov, P.; Shuplat T. Wastewater Purification from Excess Phosphates Using Bentonite Activated by Microwave Radiation. J. Ecol. Eng. 2022, 23, 251–259. https://doi.org/10.12911/22998993/14713
[28] Dibrivnyi, V.M.; Serheiev, V.V.; Van-Chyn-Sian, Yu.Ia. Kurs koloidnoi khimii; Intelekt-Zakhid: Lviv, 2008.
[29] Tarasevich, Yu.I.; Ovcharenko, F.D. Adsorption on Clay Materials; Naukova dumka: Kyiv, 1975.
[30] Yaremchuk, Ya.V., Kochubei, V.V., Zinchuk, I.M., Malovanyi, M.S. Peculiarities of the Mineral Composition of Clays of Volino-Podillia (Surroundings of Khmelnytskyi). In The Newest Problems of Geology; Kharkiv, 2020; pp 117-119.
[31] Moore, D.M.; Reynolds, R.C. X-Ray Diffraction and the Identification and Analysis of Clay Minerals; New York, Oxford University Press, 1997.
[32] Powder diffraction file, Data cards, Inorganic section sets 1-34; JCPDS: Swarthmore, Pennsylvania, 1948–1984.
[33] Matkovskyi, O.; Kvasnytsia, V.; Naumko, I.; Bilonizhka, P; Hrechanovska, O.; Kvasnytsia, I.; Melnikov, V.; Popp, I.; Skakun, L.; Slyvko, Ye. et al. Mineraly Ukrainskykh Karpat. Sylikaty; Vydavnychyi tsentr LNU im. I. Franka: Lviv, 2011.
[34] Yaremchuk, Ya.; Kochubei, V. Features of Thermal Dehydration of Clay Minerals of Baden Gypsums from the Shchyrets and Sand Quarries. Mineralohichnyi zbirnyk 2010, 60, 106–115.
[35] Pansu, M; Gautheyrou, J. Handbook of Soil Analysis. Mineralogical, Organic and Inorganic Methods; Springer-Verlag Berlin Heidelberg, 2006.
[36] Saidov, B.Yu.; Alimov, U.K.; Ahmadzhonov, A.N.; Seytnazarov, A.R.; Namazov, Sh.S. The Question of the Prospects for the Use of Bentonite Clay as a Sorbent for the Purification of Various Types of Solutions. Short review. Int. j. appl. nat. sci. 2020, 1, 23–29. https://doi.org/10.24412/2181-144X-2020-1-23-30
[37] Wilson, J.; Cuadros, J.; Cressey, G. An In situ Time-Resolved XRD-PSD Investigation into Na-Montmorillonite Interlayer and Particle Rearrangement during Dehydration. Clays Clay Miner. 2004, 52, 180–191. https://doi.org/10.1346/CCMN.2004.0520204
[38] Churakov, S.V. Mobility of Na and Cs on Montmorillonite Surface under Partially Saturated Conditions. Environ. Sci. Technol. 2013, 47, 9816–9823. https://doi.org/10.1021/es401530n
[39] Novikova, L; Ayrault, P.; Fontaine, C.; Chatel, G.; Jérôme, F.; Belchinskaya, L. Effect of Low Frequency Ultrasound on the Surface Properties of Natural Aluminosilicates. Ultrason. Sonochem. 2016, 31, 598–609. https://doi.org/10.1016/j.ultsonch.2016.02.014
[40] Kontsur, A.; Sysa, L.; Petrova, M. Investigation of Copper Adsorption on Natural and Microwave-Treated Bentonite. EasternEuropean J. Enterp. Technol. 2017, 6, 26–32. https://doi.org/10.15587/1729-4061.2017.116090
[41] Brigatti, M.F.; Galan, E.; Theng, B.K.G. Structures and Mineralogy of Clay Minerals. Іn: Handbook of Clay Science; Bergaya, F.; Theng, B.K.G.; Lagaly, G., Eds; Elsevier: Amsterdam, 2006; pp 19–86.