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Перетворення фруктози до 5-гідроксиметилфурфуролу на природних цеолітах Закарпаття

Lyubov Patrylak1, Serhiy Konovalov1, Anzhela Yakovenko1, Oleksandra Pertko1, Volodymyr Povazhnyi1, Mykhailo Kurmach2, Yuliya Voloshyna1, Mykhailo Filonenko3, Stepan Zubenko1
Affiliation: 
1 V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine vul. Murmanska, 1, Kyiv 02094, Ukraine 2 L.V. Pysarzhevski Institute of Physical Chemistry of the National Academy of Sciences of Ukraine Prospect Nauky, 33, Kyiv 03028, Ukraine 3 National Pedagogical Dragomanov University vul. Pyrogova, 9, Kyiv 01601, Ukraine lkpg@ukr.net
DOI: 
https://doi.org/10.23939/chcht16.04.521
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Abstract: 
На основі природного цеоліту (Закарпатська обл.) синтезовано каталізатори в кальцій-лантан-амонійній формі, модифіковані парообробкою та деалюмінуванням етилендіамінтетраоцтовою кислотою. Зразки досліджено з використанням адсобрції/десорбції азоту, рентгенофазного, рентгенофлуоресцентного аналізу та ІЧ-спектроскопії з перетворенням Фур’є. Встановлено, що за температури 433 K вихід 5-гідроксиметилфурфуролу на модифікованих зразках становить 50 і 83 % за практично повної конверсії фруктози.
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