Fructose Transformation into 5-Hydroxymethylfurfural over Natural Transcarpathian Zeolites
Affiliation:
1 V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine
vul. Murmanska, 1, Kyiv 02094, Ukraine
2 L.V. Pysarzhevski Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
Prospect Nauky, 33, Kyiv 03028, Ukraine
3 National Pedagogical Dragomanov University
vul. Pyrogova, 9, Kyiv 01601, Ukraine
lkpg@ukr.net
DOI:
https://doi.org/10.23939/chcht16.04.521
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Abstract:
Based on Transcarpathian zeolite the catalysts in calcium-lanthanum-ammonium form were synthesized and modified by steaming and dealumination with ethylenediaminetetraacetic acid. The samples were characterized by using nitrogen adsorption/desorption, XRD, XRF, and FTIR-spectroscopy. The yield of 5 hydroxymethylfurfural over modified samples at 433 K was found to be 50 and 83% at a practically full conversion of fructose.
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