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Ефективність інгібітування корозії, експериментальні та квантові хімічні дослідження нейтрального червоного для вуглецевої сталі у перхлорних кислих середовищах

Tarik Attar1, 2, Abbes Benchadli2, Boulanouar Messaoudi1, 3, Esma Choukchou-Braham2
Affiliation: 
1 Higher School of Applied Sciences, P.O. Box 165 RP, Tlemcen, 13000, Algeria 2 Laboratory of ToxicoMed, University of Abou Bekr Belkaid, B.P.119, Tlemcen, 13000, Algeria 3 Laboratory of Applied Thermodynamics and Molecular Modeling, University of Abou Bekr Belkaid, B.P. 119, Tlemcen, 13000, Algeria t.attar@essa-tlemcen.dz
DOI: 
https://doi.org/10.23939/chcht16.03.440
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Abstract: 
Як інгібітор корозії вуглецевої сталі (С-сталь) досліджено барвник нейтральний червоний (НЧ) в 1М хлорній кислоті за допомогою методу втрати маси та теоретичних розрахунків, заснованих на теорії функціоналу густини (DFT). Визначено, що нейтральний червоний є ефективним інгібітором, і його ефективність інгібування за температури 293 К зростає до 89,50 % із збільшенням концентрації до 5•10-3 М. Для процесів розчинення і адсорбції розраховано такі термодинамічні параметри, як ентальпія, ентропія та вільна енергія Гіббса. Встановлено, що пригнічення корозії відбувається внаслідок спонтанної фізико-хімічної адсорбції молекул інгібіторів на поверхні С-сталі. За допомогою розрахованих квантових хімічних параметрів показана можливість існування зв’язку між ефективністю інгібітора та його електронними властивостями.
References: 

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