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Дослідження дисперсно-фазового розподілу хлорорганічних пестицидів, поліхлорованих біфенілів і поліциклічних ароматичних вуглеводнів у природних водних системах

Mikhaylo Milyukin1, Maksym Gorban1
Affiliation: 
1 A.V. Dumansky Institute of Colloid Chemistry and Water Chemistry of National Academy of Sciences of Ukraine, 42 Vernadsky St., Kyiv, 03680, Ukraine m_milyukin@ukr.net
DOI: 
https://doi.org/10.23939/chcht17.04.846
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Abstract: 
У статті проаналізовано закономірності дисперсно-фазового розподілу органічних екотоксикантів, а саме: хлорорганічних пестицидів (ХОП), поліхлорованих біфенілів (ПХБ) і поліциклічних ароматичних вуглеводнів (ПАВ) – у природних водних системах. Встановлено залежність між дисперсно-фазовим розподілом індивідуальних ХОП, ПХБ та ПАВ і логарифмом константи розподілу в системі октанол/вода log Ko/w (коефіцієнтом гідрофобності). Показано, що водорозчинна частка індивідуальних органічних екотоксикантів зменшується зі збільшенняи їхнього коефіцієнту гідрофобності. Із одинадцяти наведених кореляцій вісім є чіткими, значимими та достовірними. Також досліджено вплив характеристик водної системи на дисперсно-фазовий розподіл органічних екотоксикантів. Показано, що загальна водорозчинна частка ХОП, ПХБ та ПАВ зменшується зі збільшенням значення хімічного споживання кисню (ХСК), біологічного споживання кисню (БСК) та суми важких металів (Cr, Ni, Cu, Mn, Zn, Cd, Pb). Із дев’яти відповідних кореляцій чотири є чіткими, значимими та достовірними.
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