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Активування каталізатора Мо2В в реакції епоксидування α-етилалілетилакрилату трет-бутилгідропероксидом

Zoryana Komarenska1, Lilianna Oliynyk1, Oksana Makota1
1 Lviv Polytechnic National University, 12, S.Bandery St., Lviv 79013, Ukraine.
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Вивчено закономірності активування каталізатора Мо2В у реакції епоксидування α етилалілетилакрилату трет-бутилгідропероксидом. Показано, що процес активування каталізатора описується топохімічним рівнянням Аврамі-Єрофеєва і містить дві послідовні стадії – зародкоутворення і формування нової фази, активної в реакції епоксидування. Утворення епоксиду відбувається тільки в присутності активованої форми каталізатора. Обчислено ефективні й топохімічні константи процесу.

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