Synthesis, Sorption Properties, and Evaluation of Silica Gel with Adsorbed Poly[8-Oxyquinoline Methacrylate] as a Sorbent for Cu(II), Cd(II), Pb(II) and Fe(III) Ions
Affiliation:
1 Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine.
2 Maria Curie-Skłodowska University, Maria Curie-Sklodowska Sq., 20-031 Lublin, Poland.
3 Ivan Franko Zhytomyr State University, 42 Pushkina Str., 10008 Zhytomyr, Ukraine.
irassavchenko@gmail.com
DOI:
https://doi.org/10.23939/chcht17.01.045
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Keywords:
Abstract:
In the present study, a novel functionalized silica composite was prepared by adsorption of poly[8 oxyquinoline methacrylate] on the surface of silica gel. Immobilization of poly[8 oxyquinoline methacrylate] on the silica gel surface was confirmed using IR spectroscopy and thermogravimetric analysis combined with mass spectrometry. Scanning electron microscopy revealed that the polymer almost completely covers the surface of the silica gel in the form of agglomerates of different geometric shapes. The processes of sorption of Cu(II), Cd(II), Pb(II), and Fe(III) ions on the surface of the synthesized composite in the static mode have been studied.
References:
[1] Demirbas, A. Heavy Metal Adsorption onto Agro-Based Waste Materials: A Review. J. Hazard. Mater. 2008, 157, 220-229. https://doi.org/10.1016/j.jhazmat.2008.01.024
https://doi.org/10.1016/j.jhazmat.2008.01.024
[2] Özcan, A.S.; Gök , Ö.; Özcan, A. Adsorption of Lead(II) Ions onto 8-Hydroxy Quinoline-Immobilized Bentonite. J. Hazard. Mater. 2009, 161, 499-509. https://doi.org/10.1016/j.jhazmat.2008.04.002
https://doi.org/10.1016/j.jhazmat.2008.04.002
[3] Yanovska, E.; Savchenko, I.; Petrenko, O.; Davydov, V. Adsorption of Some Toxic Metal Ions on Pine Sawdust in situ Immobilized by Polyaniline. Appl. Nanosci. 2022, 12, 861-868. https://doi.org/10.1007/s13204-021-01862-z
https://doi.org/10.1007/s13204-021-01862-z
[4] Savchenko, I.; Yanovska, E.; Polonska, Y.; Sternik, D.; Kychkiruk, O.; Ol'khovik, L. In situ Immobilization on the Silica Gel Surface and Adsorption Capacity of Polymer-Based Azobenzene on Toxic Metal Ions. Appl. Nanosci. 2019, 9(5), 657-664. https://doi.org/10.1007/s13204-018-0734-8
https://doi.org/10.1007/s13204-018-0734-8
[5] Savchenko, I.; Yanovska, E.; Polonska, Y.; Ol'khovik, L.; Sternik, D.; Kychkiruk, O. In situ Immobilization on the Silica Gel Surface and Adsorption Capacity of Poly[4-methacroyloxy-(4'-carboxy-2'-nitro)-azobenzene] On Toxic Metals Ions. Mol. Cryst. Liq. Cryst. 2018, 671, 164-174. https://doi.org/10.1080/15421406.2018.1542099
https://doi.org/10.1080/15421406.2018.1542099
[6] Kochubei, V.; Yaholnyk, S.; Bets, M.; Malovanyy, M. Use of Activated Clinoptilolite for Direct Dye-Contained Wastewater Treatment. Chem. Chem. Technol. 2020, 14(3), 386-393. https://doi.org/10.23939/chcht14.03.386
https://doi.org/10.23939/chcht14.03.386
[7] Savchenko, I.; Yanovska, E.; Sternik, D.; Kychkiruk, O.; Ol'khovik, L.; Buriachenko, I. In situ Immobilization on the Silica Gel Surface and Adsorption Capacity of Poly[N-(4-carboxyphenyl) methacrylamide] on Toxic Metal Ions. Nanoscale Res. Lett. 2017, 12, 313. https://doi.org/10.1186/s11671-017-2066-0
https://doi.org/10.1186/s11671-017-2066-0
[8] Chen, L.; Ji, T.; Mu, L.; Shi, Y.; Brisbin, L.; Guo, Z.; Khan, M.A.; Young, D.P.; Zhu, J. Facile Synthesis of Mesoporous Carbon Nanocomposites from Natural Biomass for Efficient Dye Adsorption and Selective Heavy Metal Removal. RSC Adv. 2016, 6, 2259-2269. https://doi.org/10.1039/c5ra19616g
https://doi.org/10.1039/C5RA19616G
[9] Panneerselvam, P.; Morad, N.; Tan, K.A. Magnetic Nanoparticle (Fe3O4) Impregnated onto Tea Waste for the Removal of Nickel(II) from Aqueous Solution. J. Hazard Mater. 2011, 186, 160-168. https://doi.org/10.1016/j.jhazmat.2010.10.102
https://doi.org/10.1016/j.jhazmat.2010.10.102
[10] Ji, F.; Li, C.; Tang, B.; Xu, J., Lu, G.; Liu, P. Preparation of Cellulose Acetate/Zeolite Composite Fiber and its Adsorption Behavior for Heavy Metal Ions in Aqueous Solution. Chem. Eng. J. 2012, 209, 325-333. https://doi.org/10.1016/j.cej.2012.08.014
https://doi.org/10.1016/j.cej.2012.08.014
[11] Yanovska, E.; Savchenko, I.; Sternik, D.; Kychkiruk, O. Adsorption Properties of Natural Alumosilicate Ukrainian Minerals, in situ Modified by Poly[8-methacroyloxy-quinoline] to Pb(ІІ), Mn(ІІ), Cu(ІІ) and Fe(ІІІ) Ions. Mol. Cryst. Liq. Cryst. 2021, 717, 1-13. https://doi.org/10.1080/15421406.2020.1859704
https://doi.org/10.1080/15421406.2020.1859704
[12] Savchenko, I.; Yanovska, E.; Sternik, D.; Kychkiruk, O. Synthesis of Organo-Inorganic Composite Based on Clinoptilolite (Ukraine), in situ Modified Poly[8-oxyquinoline methacrylate] and its Sorption Properties with Respect to Toxic Metal Ions. Funct. Mater. 2021, 28(3), 597-604. https://doi.org/10.15407/fm28.03.597
https://doi.org/10.15407/fm28.03.597
[13] Chuiko, A.A. Silica surface chemistry. Part 1; Center UkrINTEI: Kyiv, 2001.
[14] Al-Maliki, S.; Al-Khayat, Z.; Abdulrazzak, I.; AlAni, A. The Effectiveness of Zeolite for The Removal of Heavy Metals From an Oil Industry Wastewater. Chem. Chem. Technol. 2022, 16(2), 255-258. https://doi.org/10.23939/chcht16.02.255
https://doi.org/10.23939/chcht16.02.255
[15] Bernal, J.P.; De San Miguel, E.R.; Aguilar, J.C.; Salazar, G.; De Gyves, J. Adsorption of metallic cations on silica gel-immobilized 8-hydroxyquinoline. Sep. Sci. Technol. 2000, 35, 1661-1679. https://doi.org/10.1081/SS-100100247
https://doi.org/10.1081/SS-100100247
[16] Willie, S.N.; Tekgul, H.; Sturgeon, R.E. Immobilization of 8-Hydroxyquinoline onto Silicone Tubing for the Determination of Trace-Elements in Seawater Using Flow-Injection ICP-MS. Тalanta 1998, 47, 439-445. https://doi.org/10.1016/s0039-9140(98)00153-2
https://doi.org/10.1016/S0039-9140(98)00153-2
[17] Lührmann, M.; Stelter, N.; Kettrup, A. Synthesis and Properties of Metal Collecting Phases with Silica Immobilized 8-Hydroxyquinoline. Fresenius Z. Anal. Chem. 1985, 322, 45-52. https://doi.org/10.1007/bf00493041
https://doi.org/10.1007/BF00493041
[18] Sugawara, K.F.; Weetall, H.H.; Schucker, G.D. Preparation, Properties, and Applications of 8-Hydroxyquinoline Immobilized Chelate. Anal. Chem. 1974, 46(4), 489-492. https://doi.org/10.1021/ac60340a016
https://doi.org/10.1021/ac60340a016
[19] Lan, C.-R.; Yang, M.-H. Synthesis, Properties and Applications of Silica-Immobilized 8-Quinolinol. Part 2. On-Line Column Preconcentration of Copper, Nickel and Cadmium from Sea Water and Determination by Inductively-Coupled Plasma Atomic Emission Spectrometry. Anal. Chim. Acta 1994, 287, 111-117. https://doi.org/10.1016/0003-2670(94)85108-5
https://doi.org/10.1016/0003-2670(94)85108-5
[20] Shahata, M. Poly (8-Hydroxyquinoline) Properties, Different Methods for Characterization, and New Applications for Different Uses: Review Article. Eur. J. Appl. Sci. 2021, 9, 117-161. https://doi.org/10.14738/aivp.91.9409
https://doi.org/10.14738/aivp.91.9409
[21] Ryabchenko, K.; Yanovskaya, E.; Tertykh, V.; Kichkiruk, O. Complexation of Transition Metals with 8-Hydroxyquinoline Chemically Fixed on the Surface of the Silica Gel-Polyaniline Composite. Zhurn. Neorg. Khimii 2013, 58, 413-419. http://eprints.zu.edu.ua/id/eprint/17709
https://doi.org/10.1134/S0036023613030145
[22] Landing, W.M.; Haraldsson, C.; Paxeus, N. Vinyl Polymer Agglomerate-Based Transition-Metal Cation Chelating Ion-Exchange Resin Containing the 8-Hydroxyquinoline Functional Group. Anal. Chem. 1986, 58(14), 3031-3035. https://doi.org/10.1021/ac00127a029
https://doi.org/10.1021/ac00127a029
[23] Savchenko, I.; Yanovska, E.; Vretik, L.; Sternik, D.; Kychkyruk, O. Synthesis, Characterization and Adsorption Properties for Metal Ions of Silica-Gel Functionalized by Poly[8-methacroyloxy-quinoline]. Mol. Cryst. Liq. Cryst. 2021, 719, 103-115. https://doi.org/10.1080/15421406.2020.1862466
https://doi.org/10.1080/15421406.2020.1862466
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