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Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 3. Coumarone-Indene Resins with Methacrylic Fragments

Michael Bratychak1, Olena Astakhova1, Yuriy Prysiazhnyi1, Mariia Shved1, Olena Shyshchak1, Jacek Namiesnik2, Marta Plonska-Brzezinska3
Affiliation: 
1 Lviv Polytechnic National University 12, S.Bandery St., 79013 Lviv, Ukraine 2 Gdansk University of Technology, 11/12 G. Narutowicza St., 80233 Gdansk, Poland 3 University of Bialystok, 1, Hurtowa St., 15-399 Bialystok, Poland mbratychak@gmail.com
DOI: 
https://doi.org/10.23939/chcht12.03.379
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Keywords:

Abstract: 
The method for obtaining coumarone-indene resins with methacrylic fragments (CIRM) was developed with the addition of methyl methacrylate, using a light fraction of coal tar and its fraction boiling within 423–463 К. CIRM was obtained via radical cooligomerization using 2,2'-azobis (2-methyl-propionitrile) as the initiator. The effect of the initiator amount, temperature and reaction time on the yield, softening temperature and molecular weight of CIRM has been established. The structure of the synthesized CIRM has been confirmed by IR and NMR spectroscopy. It is proposed to use CIRM as a polymer component of bitumen-polymeric mixtures (BPS). The effect of CIRM amount, temperature and time on the main characteristics of BPS has been studied.
References: 

[1] McNally T. (Ed.): Polymer Modified Bitumen. Properties and Characterization. Woodhead Publ., 2011.
[2] Airey G.: J. Mater. Sci., 2004, 39, 951. https://doi.org/10.1023/B:JMSC.0000012927.00747.83
[3] Fang C., Li T., Zhang Z., Jing D.: Polym. Composite., 2008, 29, 500. https://doi.org/10.1002/pc.20390
[4] Pyshyev S., Gunka V., Grytsenko Y., Bratychak M.: Chem. Chem. Technol., 2016, 10, 631. https://doi.org/10.23939/chcht10.04si.631
[5] Bahl J., Atheya N., Singh H. et al.: Erdoel Kohle, Erdgas, Petrochem., 1993, 46, 22.
[6] Bratychak M., Chervinskyy T., Astakhova O. et al.: Chem. Chem. Technol., 2010, 4, 325.
[7] Bratychak M., Grynyshyn O., Astakhova O. et al.: Ecolog. Chem. Eng. S, 2010, 17, 309.
[8] Grynyshyn O., Astakhova O., Chervinskyy T.: Chem. Chem. Technol., 2010, 4, 241.
[9] Strap G., Astakhova O., Lazorko O. et al.: Chem. Chem. Technol., 2013, 7, 279.
[10] Bratychak M., Iatsyshyn O., Shyshchak O. et al.: Chem. Chem. Technol., 2017, 11, 49. https://doi.org/10.23939/chcht11.01.049
[11] Bratychak M., Gagin M., Shyshchak O., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 15.
[12] Bratychak M., Gagin M., Shyshchak O., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 21.
[13] Gagin M., Bratychak M., Shyshchak O., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 27.
[14] Chervinskyy T., Bratychak M., Gagin M., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 1225.
[15] Skibitskiy V., Grynyshyn O., Bratychak M., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 41.
[16] Bratychak M., Grynyshyn O., Shyshchak O. et al.: Ecolog. Chem. Eng., 2007, 14, 225.
[17] Grynyshyn O., Bratychak M., Krynytskiy V., Donchak V.: Chem. Chem. Technol., 2008, 2, 47.
[18] Wu Y., Li J., Xu J. et al.: J. Shanghai Univ. Engl. Ed., 2010, 14, 313. https://doi.org/10.1007/s11741-010-0651-3
[19] Sokolov V.: Inden-Kumaronovye Smoly. Metalurgia, Moskva 1978.
[20] Pyshyev S., Grytsenko Y., Solodkyy S. et al.: Chem. Chem. Technol., 2015, 9, 359.
[21] Bratychak M., Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2017, 11, 509. https://doi.org/10.23939/chcht11.04.509
[22] Bratychak M., Ripak O., Namiesnik J. et al.: Chem. Chem. Technol., 2018, 12, 93. https://doi.org/10.23939/chcht12.01.093
[23] https://www.chemicalbook.com/ChemicalProductProperty_EN_CB3415111.htm.
[24] BS EN 13589:2008. European Standard. Bitumen and bituminous binders. Determination of the tensile properties of modified bitumen by the force ductility method
[25] BS EN 1426:2000. European Standard. Bitumen and bituminous binders. Methods of tests for petroleum and its products. Determination of needle penetration
[26] BS EN 1427:2007. European Standard. Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method
[27] BS EN 13614:2011. European Standard. Bitumen and bituminous binders. Determination of adhesivity of ituminous emulstions by water immersion test