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Nucleotide Interaction with Nanocrystalline Ceria Surface

Nataliia Vlasova1, Olga Markitan1
Affiliation: 
1 Chuiko Institute of Surface Chemistry of the National Academy of Sciences of Ukraine 17, Generala Naumova St., Kyiv 03164, Ukraine natalie.vlasova@gmail.com
DOI: 
https://doi.org/10.23939/chcht16.04.581
AttachmentSize
PDF icon full_text.pdf380.88 KB
Abstract: 
The adsorption of nucleotides on the surface of nanocrystalline cerium dioxide (pHpzc = 6.3) in NaCl solutions was investigated using multi-batch adsorption experiments over a wide range of pH. The obtained results were interpreted as a formation of outer and inner sphere surface complexes with the participation of phosphate moieties. The Basic Stern surface complexation model was applied to obtain quantitative equilibrium reaction constants.
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