Friedel-Crafts Reaction of Vinyltrimethoxysilane with Styrene and Composite Materials on Their Base
Affiliation:
1 Ivane Javakhishvili’ Tbilisi State University, Department of Macromolecular Chemistry, I. Chavchavadze Ave., 1, Tbilisi 0179, Georgia
2 Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University, I. Chavchavadze Ave., 13, Tbilisi 0186, Georgia
3 Vladimir Chavchanidze Institute of Cybernetics of the Georgian Technical University. Z. Andjzaparidze St. 5, 0186, Tbilisi
4 Sokhumi State University, Faculty of Natural Sciences, Mathematics, Technologies and Pharmacy, 61 Politkovskaya St., Tbilisi 0186, Georgia
tamar.tatrishvili@tsu.ge
DOI:
https://doi.org/10.23939/chcht17.02.325
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Abstract:
Friedel-Crafts alkylation reaction of vinyltri-methoxysilane with styrene was performed in the pres-ence of anhydrous AlCl3. Alkoxy(4-vinylphenethyl)silane has been obtained. The synthesized products were identified by 1H, 13C, COSY NMR, and FTIR spectroscopy. Calculations using the quantum-chemical non-empirical density functional theory (DFT) method for the reaction between vinyltrimethoxysilane and styrene performed for ortho-, meta- and para-positions were discussed. For the theoretical modeling an online prediction program "Priroda 04: A quantum-chemical program suite" was used. Composite materials based on wood sawdust with various dispersion qualities and synthesized trimethoxysilylated styrene as a binding and reinforcing agent with degrees of silylation (5 %), in the presence of various organic/inorganic additives, fire retardants, and antioxidants, have been developed at different temperatures and pressures via hot press method or extrusion. The physico-mechanical properties of composites have been investigated.
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