Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Epoxy Composites Filled with Natural Calcium Carbonate. 3. Epoxy Composites Obtained in the Presence of Monocarboxylic Derivative of Epidian-6 Epoxy Resin

Michael Bratychak1, Olena Astakhova1, Olena Shyshchak1
Affiliation: 
1 Lviv Polytechnic National University 12, S.Bandery St., 79013 Lviv, Ukraine mbratychak@gmail.com
DOI: 
https://doi.org/10.23939/chcht14.04.504
AttachmentSize
PDF icon full_text.pdf2.56 MB

Keywords:

Abstract: 
A monocarboxylic derivative of Epidian-6 with free epoxy and carboxylic end groups (MCDER) has been synthesized using Epidian-6 epoxy resin and sebacic acid. The structure of MCDER was confirmed by a spectral analysis. The thermal stability of MCDER has been established and the formation of cross-linked films based on epoxy-oligomeric mixtures consisting of Epidian-5, TGM-3 oligoesteracrylate, and polyethylene polyamine has been studied in its presence. By means of IR spectroscopy, the chemistry of the mixtures formation has been established. Physico-mechanical characteristics and morphology of the epoxy-oligomeric mixture based samples which were filled with CaCO3 have been determined.
References: 

[1] Brostow W.: Mechanical and Thermophysical Properties of Polymer Liquid Crystals. Chapman and Hall, London 1996.

[2] Brostow W., Hagg Lobland H.E.: Materials: Introduction and Applications. John Wiley & Sons 2017.

[3] Bratychak M., Hetmanchuk Yu.: Khimichna Technologia Syntezu Vysokomoleculiarnykh Spoluk. Vyd-vo Lviv Polytechnic, Lviv 2009.

[4] Hetmanchuk Yu., Bratychak M.: Khimiya i Technologiya Polymeriv. Vyd-vo Beskid BiT, Lviv 2006.

[5] Chernin Ch., Smekhov F., Zherdeev Yu.: Epoksidnye Polymery i Kompozitsii. Khimia, Moskva 1982.

[6] Ellis B.: Chemistry and Technology of Epoxy Resins. Blackie Academic and Professional, London 1993.
https://doi.org/10.1007/978-94-011-2932-9

[7] Bratychak Mich., Bratychak Mih., Brostow W., Shyshchak O.: Mater. Res. Innovat., 2002, 6, 24.
https://doi.org/10.1007/s10019-002-0157-7

[8] Brzozowski Z., Szymanska E., Bratychak M.: React. Funct. Polym., 1997, 33, 217. https://doi.org/10.1016/S1381-5148(97)00045-X
https://doi.org/10.1016/S1381-5148(97)00045-X

[9] Iatsyshyn O., Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2013, 7, 73. https://doi.org/10.23939/chcht07.01.073
https://doi.org/10.23939/chcht07.01.073

[10] Bashta B., Bruzdziak P., Astakhova O. et al.: Chem. Chem. Technol., 2013, 7, 413. https://doi.org/10.23939/chcht07.04.413
https://doi.org/10.23939/chcht07.04.413

[11] Ivashkiv O., Namiesnik J., Astakhova O. et al.: Chem. Chem. Technol., 2015, 9, 313. https://doi.org/10.23939/chcht09.03.313
https://doi.org/10.23939/chcht09.03.313

[12] Ivashkiv O., Namiesnik J., Shyshchak O. et al.: Chem. Chem. Technol., 2016, 10, 587. https://doi.org/10.23939/chcht10.04si.587
https://doi.org/10.23939/chcht10.04si.587

[13] Hetmanchuk Yu., Bratychak M.: Khimiya i Technologiya Oligomeriv. Vyd-vo Kyiv Univ., Кyiv 2008.

[14] Yu H., Wang L., Shi Q. et al.: Prog. Org. Coat., 2006, 55, 296. https://doi.org/10.1016/j.porgcoat.2006.01.007
https://doi.org/10.1016/j.porgcoat.2006.01.007

[15] He H., Li K., Wang J. et al.: Mater. Design, 2011, 32, 4521. https://doi.org/10.1016/j.matdes.2011.03.026
https://doi.org/10.1016/j.matdes.2011.03.026

[16] Bratychak M., Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2019, 13, 360. https://doi.org/10.23939/chcht13.03.360
https://doi.org/10.23939/chcht13.03.360

[17] Odabiashian G., Shvets V.: Laboratornyi Praktikum po Khimii i Technologii Organicheskogo Sinteza. Khimia, Moskva 1982.

[18] Sorokin M., Lialiushko K.: Praktikum po Khimii i Technologii Plenkoobrazuyushikh Veshestv. Khimia, Moskva 1971.

[19] Bratychak M., Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2020, 14, 343. https://doi.org/10.23939/chcht14.03.343
https://doi.org/10.23939/chcht14.03.343

[20] Odabiashian G., Shvets V.: Laboratornyi Praktikum po Khimii i Technologii Organicheskogo Sinteza. Khimia, Moskva 1982.

[21] Toroptseva A. et al.: Laboratornyi Praktikum po Khimii s Technologii Vysokomoleculiarnykh Soedineniy. Khimia, Leningrad 1972.

[22] Bratychak M., Bashta B., Bruzdziak P. et al.: Chem. Chem. Technol., 2013, 7, 41. https://doi.org/10.23939/ chcht07.01.041