Adsorption Properties of Hydrophobic Porous Coordination Polymers of Zinc-Oxalic Acid with Triazole and Amino Triazole Mixture Ligands
Affiliation:
1 Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, North Sumatera, Indonesia
2 Chemistry Department, Faculty of Science, Shinshu University, Matsumoto, Nagano, Japan
3 Chemical Engineering Department, faculty of Engineering, Tohoku University, Sendai Miyagi, Japan
4 Mechanical Engineering Department, Politeknik Negeri Medan, Medan, North Sumatera, Indonesia
moondrazubir@unimed.ac.id
DOI:
https://doi.org/10.23939/chcht18.03.305
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Abstract:
The porous coordination polymers were prepared from Zn2+ and oxalic acid with 2 linker ligands, 1,2,4-triazole (Taz) and 3-amino-1,2,4-triazole (ATaz). The adsorption of N2 after adsorption of degassed CO2 in the pore frameworks increased by 3 times. The flexibility of this structure is due to the interaction of CO2 molecules with the amine groups contained in it, thereby increasing its porosity.
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