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Цільовий синтез функціональних біосумісних нанокомпозитів будови «ядро-оболонка»

Alexander Zaichenko1, Nataliya Mitina1, Olesia Miagkota1, Orest Hevus1, Rortyslav Bilyi2, Rostyslav Stoika2, Olena Payuk1, Zoriana Nadashkevych1, Anatoliy Voloshinovskii3
Affiliation: 
1 Lviv Polytechnic National University, 12, S. Bandera St., 79013 Lviv, Ukraine 2 Institute of Cell Biology NAS of Ukraine, 14/16 Drahomanov St., 79005 Lviv, Ukraine 3 Ivan Franko National University of Lviv, 8, Kyryla i Mefodiya St., 79005 Lviv, Ukraine zaichenk@polynet.lviv.ua
DOI: 
https://doi.org/10.23939/chcht12.01.029
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Abstract: 
Металокомплексні макроініціатори були успішно застосовані для синтезу полімерних нанокомпозитів зі структурою «ядро-оболонка» методом двоступінчатої вододисперсійної полімеризації. На першому етапі формування монодисперсних полімерних частинок бажаного розміру і функціональності досягається внаслідок цілеспрямованої зміни концентрації макроініціатору, вмісту катіонів металів в його структурі, і рН середовища. Ініціювання прищеплювальної полімеризації з поверхні затравкових частинок забезпечується залишковими пероксидними фрагментами макроініціатору.
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