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Синтез, характеристика й антибактеріальна активність комплексів іонів Sn(ii) та Sn(iv), що містять n-алкіл-n-фенілдитіокарбаматні ліганди

Wissam Abbas Ali1, HayderHamied Mihsen1, Sajid H.Guzar2
Affiliation: 
1Chemistry Department, College of Science, Kerbala University, Iraq 2Chemistry Department, College of Education for Pure Sciences, Kerbala University, Iraq hayder.kandoh@uokerbala.edu,hayderalhmedawy@gmail.com
DOI: 
https://doi.org/10.23939/chcht17.04.729
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PDF icon full_text.pdf1.48 MB
Abstract: 
У цій роботі ліганди з донорними атомами S2, N-метил-N-фенілдитіокарбамат натрію [L1] та N-етил-N-фенілдитіокарбамат натрію [L2] одержано з дисульфіду карбону за допомогою N-метиланіліну та N-етиланіліну, відповідно. Комплекси іонів Sn(II) та Sn(IV) з N-алкіл-N-фенілдитіокарбаматом одержано та охарактеризовано за допомогою CHNS елементного аналізу, інфрачервоної спектроскопії (FT-IR), 1Н ЯМР-спектроскопії, мас-спектроскопії, УФ-спектроскопії, вимірювання магнітної сприйнятливості та провідності. Аналітичні та спектральні дані показують, що стехіометрія для всіх комплексів становить 1 : 2 метал до ліганду. Спектральні дані підтверджують добру координацію дитіокарбаматного ліганду з металом через атоми сульфуру в дитіокарбаматному фрагменті. Вимірювання молярної провідності комплексів з використанням ДМФА як розчинника показало, що комплекси Sn(II) є неіонними, тоді як комплекси Sn(IV) є іонними. Ліганди L1 і L2 та їхні комплекси досліджено щодо бактерій Staphylococcusaureus і Escherichiacoli.
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