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Дослідження координаційних сполук гадолінію (iii) з -дикетонами

ОleksandraBerezhnytska1,2, Artur Horbenko1, Irina Savchenko3, Oleksandr Rohovtsov1, Nataliya Rusakova4, ОlenaTrunova1
Affiliation: 
1V.I. Vernadsky Institute of General and Inorganic Chemistry of NAS of Ukraine Akad.Palladin Avenue, 32/34, Kyiv, Ukraine, 03142. 2National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», 37, Beresteisky Avenue, Kyiv, Ukraine, 03056. 3National Taras Shevchenko University of Kyiv, Kyiv, Ukraine 4A.V. BogatskyPhysico-Chemical Institute NASU, Odessa, Ukraine irassavchenko@gmail.com
DOI: 
https://doi.org/10.23939/chcht17.04.748
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Keywords:

Abstract: 
Синтезовано нові координаційні сполуки гадолінію з -дикетонами, що містять ненасичені та аліфатичні або ароматичні замісники в -положеннях хелатного циклу. Проведено квантово-хімічні розрахунки молекул лігандів свідчать про найкращі акцепторні властивості лігандів з ароматичними замісниками. Аналіз ІЧ-спектрів та квантово-хімічних розрахунків металокомплексів свідчить про бідентатно-хелатну координацію молекул ліганду та їх розташування в різних площинах незалежно від природи та геометричної структури замісника в молекулі β-дикетону. Розраховано енергії триплетних рівнів лігандів. Вивчено морфологію та дисперсність синтезованих комплексів металів.
References: 

[1] Wei, C.; Ma, L.; Wei, H.;Liu, Z.W.; Bian, Z.Q.; Huang, C.H. Advances in Luminescent Lanthanide Complexes and Applications.Sci. China Tech. Sci.2018, 61, 1265-1285. https://doi.org/10.1007/s11431-017-9212-7
[2] Stan, C.S.;Peptu, C.; Marcotte, N.;Horlescu, P.; Sutiman, D. Photoluminescent Properties of Novel Y(III), Sm(III), Eu(III), Gd(III) and Tb(III) Complexes with 2-(1H-1,2,4-Triazol-3-yl)pyridine.Inorg. Chim. Acta2015, 429, 160-167. http://dx.doi.org/10.1016/j.ica.2015.01.041
[3] Kanetomo,T.; Yoshitake,T.; Ishida, T. Strongest Ferromagnetic Coupling in Designed Gadolinium(III)–Nitroxide Coordination Compounds.Inorg. Chem.2016, 55, 8140-8146.https://doi.org/10.1021/acs.inorgchem.6b01072
[4] Orts-Arroyo, M.;Sanchis-Perucho, А.;Moliner, N.; Castro, I.; Lloret, F.; Martínez-Lillo, J. One-Dimensional Gadolinium (III) Complexes Based on Alpha- and Beta-Amino Acids Exhibiting Field-Induced Slow Relaxation of Magnetization.J. Inorganics2022, 10, 32. https://doi.org/10.3390/inorganics10030032
[5]Oliveira, R.S.; TrindadeCursino, A.C.; Gonçalves e Silva Hussein, F.R.Synthesis, Characterization and Photophysical Study of 4,4’-Diamino-2,2’-stilbenedisulfonate with Lanthanide Ions Complexes.Chem. Chem. Technol.2022, 177-184.https://doi.org/10.23939/chcht16.02.177
[6] Marin, R.; Brunet, G.;Murugesu, M.Shining New Light on Multifunctional Lanthanide Single-Molecule Magnets.Angew. Chem. Int. Ed. 2021, 60, 1728-1746. https://doi.org/10.1002/anie.201910299
[7] Woodruff, D.N.;Winpenny, R.E.P.;Layfield, R.A. Lanthanide Single-Molecule Magnets.Chem. Rev.2013, 113,5110–5148. https://doi.org/10.1021/cr400018q
[8] Coronado, E.; Yamashita, M. Molecular Spintronics: The Role of Coordination Chemistry.Dalton Trans. 2016, 45, 16553-16555. https://doi.org/10.1039/C6DT90183B
[9] Chen, J.-T.; Zhou, T.-D.; Sun, W.-B. Multifunctional Lanthanide-Based Single-Molecule Magnets Exhibiting Luminescence Thermometry and Photochromic and Ferroelectric Properties.Dalton Trans. 2023, 52, 4643-4657. http://doi.org/10.1039/D3DT00481C
[10]Oyarzabal, I.; Echenique-Errandonea, E.; San Sebastián, E.; Rodríguez-Diéguez, A.; Seco, J.M.; Colacio, E. Synthesis, Structural Features and Physical Properties of a Family of Triply Bridged Dinuclear 3d-4f Complexes.Magnetochemistry2021, 7, 22. https://doi.org/10.3390/magnetochemistry7020022
[11]Ortu, F.; Reta, D.; Ding, Y.-S.; Goodwin, C.A.P.;Gregson, M.P.; McInnes, E.J. L.; Winpenny, R.E. P.; Zheng, Y.-Z.; Liddle, S.T.; Mills, D.P.,et al.Studies of Hysteresis and Quantum Tunnellingof the Magnetisationin Dysprosium(Iii) Single Molecule Magnets.DaltonTrans.2019, 48, 8541-8545. https://doi.org/10.1039/C9DT01655D
[12]Pavlishchuk, A.V.;Pavlishchuk, V.V.Principles for Creating “Molecular Refrigerators” Derived from Gadolinium(III) Coordination Compounds: A Review.Theor. Exp. Chem. 2020, 56. https://doi.org/10.1007/s11237-020-09635-5
[13]Thalji, M.R.; Ibrahim, A.A.; Ali, G.A.M. Cutting-edge Development in Dendritic Polymeric Materials for Biomedical and Energy Applications.Eur. Polym. J.2021,160,110770.http://doi.org/10.1016/j.eurpolymj.2021.110770
[14] Zhao, M.; Tang, Z.; Zhang, J.; Fu, G.; Xu, W.; Wu, Q.; Pu, L. Preparation and MRI Performance of a Composite Contrast Agent Based on Palygorskite Pores and Channels Binding Effect to Prolong the Residence Time of Water Molecules on Gadolinium Ions. RSC Adv.2022, 12, 7328-7331.http://doi.org/10.1039/D1RA08967F
[15]Xu, K.; Xu, N.;Zhang, B.; Tang, W.; Dinga, Y.; Hu, A. Gadolinium Complexes of Macrocyclic Diethylenetriamine-N-oxide Pentaacetic Acid-Bisamide as Highly Stable MRI Contrast Agents with High Relaxivity.Dalton Trans. 2020, 49, 8927-8932. http://doi.org/10.1039/D0DT00248H
[16]Sakol, N.;Egawa, A.; Fujiwara, T. Gadolinium Complexes as Contrast Agent for Cellular NMR Spectroscopy.Int J. Mol. Sci.2020, 21, 4042. http://doi.org/10.3390/ijms21114042
[17]Clough, T.J.; Jiang, L.; Wong, K.-L.; Long, N.J. Ligand Design Strategies to Increase Stability of Gadolinium-Based Magnetic Resonance Imaging Contrast Agents.Nat.Commun. 2019, 10, 1420. https://doi.org/10.1038/s41467-019-09342-3
[18]Ramalho, J.;Semelka, R.C.;Ramalho, M.; Nunes, R.H.; AlObaidy, M.; Castillo, M. Gadolinium-Based Contrast Agent Accumulation and Toxicity: An Update.AJNR Am J Neuroradiol2016, 37, 1192-1198. http://doi.org/10.3174/ajnr.A4615
[19] Law,J.J.; Guven,A.; Wilson,L.Relaxivity Enhancement of AquatedTris(β-diketonate)gadolinium(III) Chelates by Confinement within Ultrashort Single-Walled Carbon Nanotubes. Contrast Media Mol. Imaging2014, 9, 409-412.https://doi.org/10.1002/cmmi.1603
[20]Savchenko, I.A., Berezhnytska, A.S., Ivakha, N.B.,Trunova E.K. Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications.InSpringer Proceedings in PhysicsV. 156; Springer International Publishing: Switzerland, 2015; pp 85-94.
[21]Galán, L.A.;Sobolev, A.N.;Zysman-Colman, E.; Ogden, M.I.; Massi, M. Lanthanoid Complexes Supported by retro-ClaisenCondensation Products of β-Triketonates.Dalton Trans.2018, 47, 17469-17478. http://doi.org/10.1039/C8DT03585G
[22]Berezhnytska, О.;Rohovtsov, O.;Horbenko, A.;Fedorov, Y.; Trunova, O.; Chyhyrynets, O.; Smola, S.The Coordination Compounds Gd (III) AND Dy(III) with some β-Diketones.Ukrainian ChemistryJournal2021, 87, 97-120. https://doi.org/10.33609/2708-129X.87.06.2021.97-120
[23] Fu, C.-Y.; Chen, L.; Wang, X.; Lin, L.R. Synthesis of Bis-β-Diketonate Lanthanide Complexes with an Azobenzene Bridge and Studies of their Reversible Photo/Thermal Isomerization Properties.ACS Omega2019,4, 15530-15538. https://doi.org/10.1021/acsomega.9b01817
[24]Berezhnytska, O.S.;Savchenko, I.O.;Ivakha, N.B.; Smola, S.S.; Rohovtsov, O.O.; Rusakova, N.V.; Trunova,O.K. Influence of the Nature of the Substitute on the Luminescent Properties of β-Diketonate Complexes of Neodyme (III).Mol. Cryst. Liq. Cryst.2020,716, 1-12. https://doi.org/10.1080/15421406.2020.1859691