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Processing of Oily Waste. 1. Low-Temperature Pyrolysis of the Organic Part of Oil Sludge

Oleg Grynyshyn1, Yuriy Znak1, Taras Chervinskyy1
Affiliation: 
1 Lviv Polytechnic National University, 12 S. Bandery St., Lviv 79013, Ukraine oleh.b.hrynyshyn@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht19.03.557
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Keywords:

Abstract: 
The article presents the results of studies on the composition and properties of the organic part of oil sludge formed during oil production in the fields of western Ukraine. The thermal stability of the oil sludge organic part was studied. As a result of low-temperature pyrolysis of the organic (hydrocarbon) part of oil sludge, pyrolysis oil (pyrocondensate) was obtained. The fractional composition and properties of pyrolysis oil were studied. Pyrolysis oil was separated into gasoline fraction, diesel fraction, and the residue. The composition and properties of these fractions were determined. X-ray fluorescence analysis of pyrolysis oil and narrow fractions separated from it was performed. The composition and properties of the solid residue of the oil sludge hydrocarbon part after the pyrolysis process were investigated. It is proposed to use the narrow fractions separated from pyrolysis oil to produce motor fuels.
References: 

[1] Li, J.; Song, X.; Hu, G.; Thring, R.W. Ultrasonic Desorption of Petroleum Hydrocarbons from Crude Oil Contaminated Soils. J. Environ. Sci. Health. Part A Toxic/Hazard. Subst. Environ. Eng. 2013, 48, 1378-1389. https://doi.org/10.1080/10934529.2013.781885
https://doi.org/10.1080/10934529.2013.781885

[2] Kobilov, N.; Khamidov, B.; Shukurov, A.; Kodirov, S.; Sharifov, G.; Shukhratov, J. Study of Oil Sludge of Oil Refinery and Their Processing. The Austrian Journal of Technical and Natural Sciences 2023, 23, 67-70. https://doi.org/10.29013/AJT-23-9.10-67-70

[3] Aliyev, G.S.; Hajiyeva, R.J.; Ahmadova, E.N.; Imanova, T.R.; Rahimov, M.G. Analysis of Physico-Chemical Methods for Investigation of Oil Sludge. Journal of Survey in Fisheries Sciences 2023, 10, 826-830.

[4] Islam, B. Petroleum sludge, its treatment and disposal: A review. Int. J. Chem. Sc. 2015, 13, 1584-1602.

[5] Mohd Pauzi, N.N.; Ahmad Shah, M.S. A Review on the Treatment of Petroleum Sludge and Use as Construction Materials. Civil and Sustainable Urban Engineering 2022, 2, 12-20. https://doi.org/10.53623/csue.v2i1.74
https://doi.org/10.53623/csue.v2i1.74

[6] Yuxiao, S.; Yi, L.; Jianqi, C.; Yuan, H.; Hao, L.; Wei, Y.; Qiang, Y.; Jiandong, H.; Bichuan, Y.; Dun, W.; et al. Physical Pretreatment of Petroleum Refinery Wastewater Instead of Chemicals Addition for Collaborative Removal of Oil And Suspended Solids. J. Clean. Prod. 2021, 278, 12-38. https://doi.org/10.1016/j.jclepro.2020.123821
https://doi.org/10.1016/j.jclepro.2020.123821

[7] Echeverría, V.; Monsalve, G.; Vidales, H. Continuos Treatment of Oily Sludge at Colombian Refineries. CT&F - Ciencia, Tecnología y Futuro 2002, 2, 61-70.
https://doi.org/10.29047/01225383.538

[8] Shaporev, V.; Shestopalov, O.; Mamedova, O.; Bakhareva, G.; Kobylyanski, B.; Pushkova, O. Biolohichni metody zakhystu navkolyshnoho seredovyshcha vid zabrudnennya naftoproduktamy; NTU "KhPI": Kharkiv, 2015.

[9] Johnson, O.; Affam, A. Petroleum Sludge Treatment and Disposal: A review. Environ. Eng. Res. 2019, 24, 191-201. https://doi.org/10.4491/eer.2018.134
https://doi.org/10.4491/eer.2018.134

[10] Aitkaliyeva, G.; Yelubay, M.; Ismailova, A.; Massakbayeva, S.; Baisariyeva, A. Oil Sludge and Methods of Its Disposal. Pol. J. Environ. Stud. 2022, 31, 5563-5569. https://doi.org/10.15244/pjoes/152226
https://doi.org/10.15244/pjoes/152226

[11] Humadi, J.I.; Jafar, S.A.; Ali, N.S.; Ahmed, M.A.; Mzeed, M.J.; Al-Salhi, R.J.; Cata Saady, N.M.; Majdi, H.Sh.; Zendehboudi, S.; Albayati, T.M. Recovery of Fuel From Real Waste Oily Sludge Via a New Eco-Friendly Surfactant Material Used In a Digital Baffle Batch Extraction Unit. Sci. Rep. [Online] 2023, 13, 9931. https://doi.org/10.1038/s41598-023-37188-9.
https://doi.org/10.1038/s41598-023-37188-9

[12] Chelyadyn, V.; Bogoslavets, M.; Chelyadyn, L.; Poznyak, O.; Novosad, P. Sludge of Oil Refining Units and Their Processing. Journal of Ecological Engineering 2020, 21, 169-177. https://doi.org/10.12911/22998993/125556
https://doi.org/10.12911/22998993/125556

[13] Kaffe, D.; Spiliotis, X. Effect of Refinery Oily Sludge Addition on the Physico-Mechanical Properties of Red Ceramics. Global scientific journal [Online] 2024, 12, 1373-1386.

[14] Chu, Z.; Li, Y.; Zhang, C.; Fang, Y.; Zhao, J. A Review on Resource Utilization of Oil Sludge Based on Pyrolysis and Gasification. J. Environ. Chem. Eng. 2023, 11, 109692. https://doi.org/10.1016/j.jece.2023.109692
https://doi.org/10.1016/j.jece.2023.109692

[15] Vdovenko, S.; Boichenko, S.; Kochubey, V. Composition and Properties of The Refinery Oily Sludge. Chem. Chem. Technol. 2015, 9, 257-260. https://doi.org/10.23939/chcht09.02.257
https://doi.org/10.23939/chcht09.02.257

[16] Jia, H.; Zhao, S.; Zhou, X.; Qu, C.; Fan, D.; Wang, C. Low-Temperature Pyrolysis of Oily Sludge: Roles of Fe/Al-Pillared Bentonites. Arch. Environ. Prot. 2017, 43, 82-90. https://doi.org/10.1515/aep-2017-0027
https://doi.org/10.1515/aep-2017-0027