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Synthesis of Epoxyperoxides and Peroxide Derivatives of -D-Galactopyranose Based Thereon

Roman Fleychuk1, Lidiya Vuytsyk1, Ananiy Kohut1, Orest Hevus1
Affiliation: 
1 Lviv Polytechnic National University 12, S. Bandery St., 79013 Lviv, Ukraine romanfleych@gmail.com
DOI: 
https://doi.org/10.23939/chcht14.04.439
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Keywords:

Abstract: 
New epoxide-containing peroxides have been synthesized via the interaction between epichlorohydrin and ditertiary -hydroxyalkyl peroxides. The effect of reaction conditions on both the yield and composition of the reaction products has been established. Through the reactions of either the synthesized epoxide-containing peroxides with 1,2;3,4-di-O-isopropylidene--D-galactopyranose or 6-O-glycidyl-1,2;3,4-di-O-isopropylidene--D-galactopyranose with the -hydroxyalkyl peroxides, new peroxide derivatives with ditertiary and primary-tertiary peroxide groups have been synthesized successfully. The decomposition of the developed substances has been studied by complex thermal analysis and the kinetic parameters of the thermolysis have been determined.
References: 

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