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Synthesis of Epoxyperoxides and Peroxide Derivatives of -D-Galactopyranose Based Thereon

Roman Fleychuk1, Lidiya Vuytsyk1, Ananiy Kohut1, Orest Hevus1
Affiliation: 
1 Lviv Polytechnic National University 12, S. Bandery St., 79013 Lviv, Ukraine romanfleych@gmail.com
DOI: 
https://doi.org/10.23939/chcht14.04.439
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Keywords:

Abstract: 
New epoxide-containing peroxides have been synthesized via the interaction between epichlorohydrin and ditertiary -hydroxyalkyl peroxides. The effect of reaction conditions on both the yield and composition of the reaction products has been established. Through the reactions of either the synthesized epoxide-containing peroxides with 1,2;3,4-di-O-isopropylidene--D-galactopyranose or 6-O-glycidyl-1,2;3,4-di-O-isopropylidene--D-galactopyranose with the -hydroxyalkyl peroxides, new peroxide derivatives with ditertiary and primary-tertiary peroxide groups have been synthesized successfully. The decomposition of the developed substances has been studied by complex thermal analysis and the kinetic parameters of the thermolysis have been determined.
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