Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Low Temperature Acrolein to Acrylic Acid Oxidation with Hydrogen Peroxide on Se-Organic Catalysts

Roman Nebesnyi1, Volodymyr Ivasiv1, Zoryan Pikh1, Tetiana Kharandiuk1, Iryna Shpyrka1, Taras Voronchak2, Anastasia-Bohdana Shatan3
Affiliation: 
1 Lviv Polytechnic National University, 12, Bandery St., 79013 Lviv, Ukraine 2 Market Central Laboratory, Nestle Ukraine LLC, Lviv, Ukraine 3 Institute of Macromolecular Chemistry, Czech Academy of Sciences, Prague, Czech Republic roman.v.nebesnyi@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht13.01.038
AttachmentSize
PDF icon full_text.pdf554.97 KB

Keywords:

Abstract: 
Catalytic performance of Se-containing organic substances, namely methylseleninic acid, benzeneseleninic acid, phenylselenol and diphenyldiselenide, has been tested as potential catalysts for unsaturated aldehydes oxidation by hydrogen peroxide. All tested substances proved to be active in the acrolein oxidation reaction but showed different efficiency regarding used solvents and the products of reaction – acrylic acid or methyl acrylate. Optimal catalyst, reaction conditions and solvent for acrylic acid synthesis have been determined.
References: 

[1] Esmaeili A., Kakavand S.: Comptes Rendus Chimie, 2006, 19, 936. https://doi.org/10.1016/j.crci.2016.02.009
[2] Zhou L., Donga B., Tang S. et al.: J. Energy Chem., 2013, 22, 659. https://doi.org/10.1016/S2095-4956(13)60087-X
[3] Sato K., Hyodo M., Takagi J. et al.: Tetrahedron Lett., 2000, 41, 1439. https://doi.org/10.1016/S0040-4039(99)02310-2
[4] Balinge K., Khiratkar A., Bhagat P.: J. Mol. Liq., 2017, 242, 1085. https://doi.org/10.1016/j.molliq.2017.07.105
[5] Singh S., Patel A., Prakashan P.: Appl. Catal. A., 2015, 505, 131. https://doi.org/10.1016/j.apcata.2015.07.032
[6] Hajimohammadi M., Safari N., Mofakham H. et al.: Tetrahedron Lett., 2010, 51, 4061. https://doi.org/10.1016/j.tetlet.2010.05.124
[7] Guo H., Kemell M., Al-Hunaiti A. et al.: Catal. Commun., 2011, 12, 1260. https://doi.org/10.1016/j.catcom.2011.04.025
[8] Nwaukwa S., Keehn P.: Tetrahedron Lett., 1982, 23, 3131. https://doi.org/10.1016/S0040-4039(00)88577-9
[9] Marsden C., Taarning E., Hansen D. et al.: Green Chem., 2008, 10, 168. https://doi.org/10.1039/B712171G
[10] Pikh Z., Nebesnyi R., Ivasiv V. et al.: Chem. Chem. Technol., 2016, 10, 401. https://doi.org/10.23939/chcht10.04.401
[11] Alberto E., Braga A.: Activation of Peroxides by Organoselenium Catalysts: A Synthetic and Biological Perspective. [in:] Woollins J., Laitinen R. (Eds.), Selenium and Tellurium Chemistry. Springer, Berlin, Heidelberg 2011, 251-283. https://doi.org/10.1007/978-3-642-20699-3_11
[12] Pikh Z., Ivasiv V.: Chem. Chem. Technol., 2012, 6, 9.
[13] Goti A., Cardona F.: Green Chem. React., 2008, 191.
[14] Hori T., Sharpless K.: J. Org. Chem., 1978, 43, 1689. https://doi.org/10.1021/jo00403a015
[15] Rangraz Y., Nemati F., Elhampour A.: J. Colloid Interf. Sci., 2018, 509, 485. https://doi.org/10.1016/j.jcis.2017.09.034
[16] Guo L., Huang K., Liu H.: J. Nanopart. Res., 2016, 18, 74. https://doi.org/10.1007/s11051-016-3357-6
[17] Narender N., Suresh Kumar Reddy K., Krishna Mohan K. et al.: J. Porous Mater., 2011, 18, 337. https://doi.org/10.1007/s10934-010-9383-3
[18] Brink G.-J., Vis J., Arends I. et al.: Tetrahedron, 2002, 58, 3977. https://doi.org/10.1016/S0040-4020(02)00248-X
[19] Landi G., Lisi L., Russo G.: J. Mol. Catal., 2005, 239, 172. https://doi.org/10.1016/j.molcata.2005.06.018
[20] Tanimoto M., Nakamura D., Kawajiri T.: Pat. US 6545178, Publ. Apr. 8, 2003.
[21] Mamoru A.: J. Catal., 1986, 101, 473. https://doi.org/10.1016/0021-9517(86)90274-5
[22] Talebian-Kiakalaieh A., Amin N.A., Hezaveh H.: Renew. Sust. Energ. Rev., 2014, 40, 28. https://doi.org/10.1016/j.rser.2014.07.168
[23] Liu R., Lyu S., Wang T.: J. Ind. Eng. Chem., 2016, 37, 354. https://doi.org/10.1016/j.jiec.2016.03.050