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Low Temperature Acrolein to Acrylic Acid Oxidation with Hydrogen Peroxide on Se-Organic Catalysts

Roman Nebesnyi1, Volodymyr Ivasiv1, Zoryan Pikh1, Tetiana Kharandiuk1, Iryna Shpyrka1, Taras Voronchak2, Anastasia-Bohdana Shatan3
Affiliation: 
1 Lviv Polytechnic National University, 12, Bandery St., 79013 Lviv, Ukraine 2 Market Central Laboratory, Nestle Ukraine LLC, Lviv, Ukraine 3 Institute of Macromolecular Chemistry, Czech Academy of Sciences, Prague, Czech Republic roman.v.nebesnyi@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht13.01.038
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Keywords:

Abstract: 
Catalytic performance of Se-containing organic substances, namely methylseleninic acid, benzeneseleninic acid, phenylselenol and diphenyldiselenide, has been tested as potential catalysts for unsaturated aldehydes oxidation by hydrogen peroxide. All tested substances proved to be active in the acrolein oxidation reaction but showed different efficiency regarding used solvents and the products of reaction – acrylic acid or methyl acrylate. Optimal catalyst, reaction conditions and solvent for acrylic acid synthesis have been determined.
References: 

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