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Isomerization of Glucose into Fructose over Basic Oxide Catalysts

Svitlana Levytska1, Volodymyr Brei1
Affiliation: 
1 Institute for Sorption and Endoecology Problems, Ukrainian National Academy of Sciences, 13 Oleg Mudrak St., Kyiv 03164, Ukraine s_levytska@ukr.net
DOI: 
https://doi.org/
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Keywords:

Abstract: 
The isomerization of 10-30% glucose aqueous solutions over several mixed basic oxides supported on γ-Al2O3 was studied at 90°C and atmospheric pressure using batch and flow reactors. The catalyst samples were obtained by conventional impregnation method which is important for the development of the readily commercially available catalyst. It was found that the MgO-ZrO2/Al2O3 catalyst with atomic ratio of Mg/Zr= 4 and the deposited oxide phase content of 20 wt.% provides glucose conversion up to 19% at 90°C, with maximum fructose selectivity up to 100% using the continuous flow fixed bed reactor. After 30h of operation the deactivated catalyst has been regenerated by air calcination for 2 hours at 600°C, restoring its activity and selectivity.
References: 

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