Voltammetric Determination of Pd(II) Using 5-Hydroxyimino-4-imino-1,3-thiazolidin-2-one after a Thermal Activation of the Interaction
Affiliation:
1 Department of Analytical Chemistry, Ivan Franko National University of Lviv,
6, Kyryla i Mephodia St., 79005 Lviv, Ukraine
2 Central Research Laboratory and Laboratory of Industrial Toxicology,
Danylo Halytsky Lviv National Medical University,
69, Pekarska St., 79010 Lviv, Ukraine
3 Department of General, Bioinorganic, Physical and Colloidal Chemistry,
Danylo Halytsky Lviv National Medical University,
52, Pekarska St., 79010 Lviv, Ukraine
peter_rydchuk@yahoo.com
DOI:
https://doi.org/10.23939/chcht15.03.324
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Abstract:
The interaction of Pd(II) with 5-hydroxyimino-4-imino-1,3-thiazolidin-2-one (HITO) was investigated over the pH range of 1.0–10.0. Optimal conditions for the voltammetric determination of Pd(II) were established. A new voltammetric method of Pd(II) determination by the peak of complex using NaCl as a supporting electrolyte at pH 2.0 was developed with the limit of detection 2.0∙10-7 M. The study of the method’s selectivity was presented in the work. The correctness of the method was confirmed by the analysis of model solutions and the real sample (resistor SP5-35B).
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