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The transition nanoreactor-nanoparticle in epoxy polymers curing process

Georgiy Kozlov, Musa Bashorov, Abdulakh Mikitaev and Gennady Zaikov
DOI: 
https://doi.org/10.23939/chcht02.04.281
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Keywords:

Abstract: 
It has been shown that for curing reaction in fractal space the reaction rate constant reduction is typical. Another typical feature of this reaction is the formation of a large number of microgels with smaller molecular weight in comparison with reaction in Euclidean space at the same conversion degree. The dimensional border between nanoreactor and nanoparticle for the curing reaction under consideration has been obtained.
References: 

[1] Kozlov G., Bejev A. and Zaikov G.: J. Appl. Polymer Sci., 2003, 90, 1202.
https://doi.org/10.1002/app.12602

[2] Kozlov G., Bejev A. and Lipatov Yu.: J. Appl. Polymer Sci., 2004, 92, 2558.
https://doi.org/10.1002/app.20222

[3] Kozlov G., Bejev A. and Dolbin I.: J. Balkan Tribolog. Assoc., 2004, 10, 31.

[4] Kozlov G., Shustov G. and Zaikov G.: J. Appl. Polymer Sci., 2004, 93, 2343.
https://doi.org/10.1002/app.20715

[5] Kozlov G., Shustov G. and Zaikov G.: J. Balkan Tribolog. Assoc., 2003, 9, 467.

[6] Smirnov B.: Uspekhi Fizicheskikh Nauk, 1986, 149, 177.
https://doi.org/10.3367/UFNr.0149.198606a.0177

[7] Buchachenko A.: Uspekhi Khimii, 2003, 72, 419.
https://doi.org/10.1070/RC2003v072n05ABEH000795

[8] Sahimi M., McKarnin M., Nordahl T. and Tirrell M.: Phys. Rev. A, 1985, 32, 590.
https://doi.org/10.1103/PhysRevA.32.590