Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Synthesis of Heterocyclic Thioamides and Copper(II) Coordination Compounds Based on Them

Anatoliy Ranskiy, Natalia Didenko and Olga Gordienko
DOI: 
https://doi.org/10.23939/chcht11.01.011
AttachmentSize
PDF icon full_text.pdf791.37 KB

Keywords:

Abstract: 
Arylamides of hetaryl-2-thiocarbonic acid were synthesized via Willgerodt–Kindler modified reaction. The final products were studied by means of chemical analysis, IR- and 1H NMR-spectroscopy. The coordination compounds of the general formula [Cu(HL4)Cl2]2] • хCH3OH (х = 0, 2) were obtained via traditional and direct synthesis based on benzimidazol-2-N-(4-ethoxyphenyl)carbothiamide (HL4). Using X-ray analysis the molecular and crystal structures of [Cu(HL4)Cl2]2] • 2CH3OH complex were determined.
References: 

[1] Wang F., Langley R., Gulten G. et al.: J. Exp. Med., 2007, 204, 73.
https://doi.org/10.1084/jem.20062100

[2] Winogradova V. and Maizus Z.: Kinetika i Kataliz, 1971, 12, 1322.

[3] Ranskiy A., Boichenko S., Gordienko O. et al.: Composytsyini Mastylni Materialy na Osnovi Tioamidiv ta ich Complexnykh spoluk. Vinnytsa VNTU, Vinnytsa 2012.

[4] Ranskiy A. and Evseeva M.: Sintez, Budova i Reakcii Komplexoutvorennya Aromatychnykh i Heterocyclichnykh Tioamidiv. Vinnytsa VNTU, Vinnytsa 2009.

[5] Valdez-Rojas J. E., Roios-Guerra H., Ramirez-Sanchez A. et al.: Can. J. Chem., 2012, 90, 567.
https://doi.org/10.1139/v2012-030

[6] Koketsu M. and Ishihara H.: Curr. Org. Synth., 2007, 4, 15.
https://doi.org/10.2174/157017907779981615

[7] Ranskiy A. and Didenko N. : Chem. Chem. Technol., 2014, 8, 317.

[8] Uraev A., Nivorozhkin A., Korshunov O. et al.: Coordinats. Khimia, 1999, 25, 79.

[9] Didenko N. and Ranskiy A.: Visnyk Vinnyts. Politechn. Inst., 2012, 3, 182.

[10] Egorov A., Matynhova S. and Anisimov A.: Appl. Organometall. Chem., 2005, 19, 605.
https://doi.org/10.1002/aoc.844

[11] Klimova V.: Osnovnye Micrometody Analiza Organicheskykh Soedineniy. Khimiya, Moskva 1975.

[12] Sheldrick G.: SHELXTL PLUS. PC Version. A system of computer programs for the determination of structure from X-ray diffraction data. Rev. 5.1, 1998.

[13] Burgi H. and Dunitz J.: Structure Correlation. VCH., Weinheim 1994.
https://doi.org/10.1002/9783527616091

[14] Orpen G., Brammer L., Allen F. H. et al.: J. Chem. Dalton Trans., 1989, 12, S1.
https://doi.org/10.1039/dt98900000s1