Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Synthesis and Study of Properties of Geopolymer Materials Developed Using Local Natural Raw Materials and Industrial Waste

Elena Shapakidze1, Marina Avaliani2, Marina Nadirashvili1, Vera Maisuradze1, Ioseb Gejadze1, Tamar Petriashvili1
Affiliation: 
1IvaneJavakhishvili Tbilisi State University, Alexander Tvalchrelidze Caucasian Institute of Mineral Resources, 11, Mindeli St., Tbilisi 0186, Georgia 2IvaneJavakhishvili Tbilisi State University, Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, 11, Mindeli St., Tbilisi 0186, Georgia elena.shapakidze@tsu.ge
DOI: 
https://doi.org/10.23939/chcht17.04.711
AttachmentSize
PDF icon full_text.pdf1.41 MB

Keywords:

Abstract: 
This paper describes the synthesis of geopolymer materials using thermally modified clay rocks of Georgia and metallurgical granulated blast-furnace slag; as well as the study of their physical and mechanical properties, durability, and corrosion resistance in aggressive solutions.The methods of chemical, X-ray phase, differential thermal analysis and SEM were used.
References: 

[1] Levytska, O.;Dolzhenkova, O.; Sichevyi, O.;Dorhanova, L. Masonry Unit Manufacturing Technology Using Polymeric Binder.Chem. Chem. Technol.2020, 14, 88-92.https://doi.org/10.23939/chcht14.01.088
https://doi.org/10.23939/chcht14.01.088

[2] Savvova, O.; Voronov, H.; Fesenko, O.; Riabinin, S.; Tymofieiev, V. High-Strength Glass-Ceramic Material With Low Temperature Formation. Chem. Chem. Technol. 2022, 16, 337-344. https://doi.org/10.23939/chcht16.02.337
https://doi.org/10.23939/chcht16.02.337

[3] Shapoval, S.; Shapoval, P; Zhelykh, V.; Pona, O.; Spodyniuk, N.; Gulai, B.; Savchenko, O.; Myroniuk, K. Ecological and Energy Aspects of Using the Combined Solar Collectors for Low-Energy Houses. Chem. Chem. Technol. 2017, 11, 503-508.
https://doi.org/10.23939/chcht11.04.503

https://doi.org/10.23939/chcht11.04.503
https://doi.org/10.23939/chcht11.04.503

[4] Avaliani, M.; Chagelishvili, V.; Shapakidze, E.; Gvelesiani, M.; Barnovi, N.; Kveselava, V.; Esakia, N. Crystallization Fields of Condensed Scandium and Silver Phosphates and Regularities of Their Formation. European Chemical Bulletin2019, 8, 164-170.
https://doi.org/10.17628/ecb.2019.8.164-170

[5] Purbasari, A.; Ariyanti, D.; Sumardiono, S.; Khairunnisa, K.; Sidharta, T. Adsorption Kinetics and Isotherms of Cu(II) and Fe(II) Ions from Aqueous Solutions by Fly Ash-Based Geopolymer. Chem. Chem. Technol.2022, 16, 169-176. https://doi.org/10.23939/chcht16.02.169
https://doi.org/10.23939/chcht16.02.169

[6] Glukhovsky, V.D. Soil Silicates;Gosstroyizdat: Kiev,1959.

[7] Glukhovsky, V.D.;Krivenko, P.V.;Ryumina, P.V.;Gerasimchuk, V.L. Production of Concrete and Structures Based on Slag-Alkali Binders;Budivelnik: Kiev, 1988.

[8] Krivenko, P. Alkaline Cements. In Proceedings of the First International Conference on Alkaline Cements and Concrete; VIPOL Stock Company: Kiev, 1994;pp 11-129.

[9] Krivenko, P.V. Special Alkaline Cements;Budivelnyk: Kiev,1995.

[10] Krivenko, P. Review. Why Alkaline Activation - 60 Years of the Theory and Practice of Alkali-Activated Materials. J. Ceram. Sci.Technol. 2017,08, 323-334. https://doi.org/10.4416/JCST2017-00042

[11] Davidovits, J. Soft Mineralurgy and Geopolymers. InProc. of Geopolymer 88 - Conference Internationale, Université de Technologie;Compiègne, France,1988; pp 49-56.

[12] Davidovits, J. Carbon-Dioxide Greenhouse-Warming: What Future for Portland Cement. In Proceedings, Emerging Technologies Symposium on Cement and Concretes in the Global Environment; Portland Cement Association: Chicago, Illinois, 1993; pp1-21.

[13] Duxon,P.;Fernández-Jiménez, A.; Provis, J.L.; Lukey, G.C.; Palomo A.; van Deventer, J.S.J. GeopolymerTechnology: The Current State of the Art. J. Mater. Sci.2007, 42, 2917-2933.https://doi.org/10.1007/s10853-006-0637-z
https://doi.org/10.1007/s10853-006-0637-z

[14] Palomo, A.;Grutzeck, M.W.;Blanco, M.T. Alkali-Activated fly Ash Cement for Future. CemConcr Res1999,29,1323-1329.https://doi.org/10.1016/S0008-8846(98)00243-9
https://doi.org/10.1016/S0008-8846(98)00243-9

[15] Palomo, A.; Krivenko, P.; Garcia-Lodeiro, I.; Kavalerova, E.; Maltseva, O.; Fernández-Jiménez, A. A Review on Alkaline Activation: New Analytical Perspectives.Mater. deConstruccion2014, 64, 022.
https://doi.org/10.3989/mc.2014.00314

[16] Shapakidze, E.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Avaliani, M.; Todradze, G. Elaboration of Optimal Mode for Heat Treatment of Shales for Obtaining Metakaolin. European Chemical Bulletin2019,8, 31-33.
https://doi.org/10.17628/ecb.2019.8.31-33

[17] Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T. Obtaining of Geopolymer Binders Based on Thermally Modified Clay Rocks of Georgia. Nano Studies2020, 20, 43-52. http://dx.doi.org/10.13140/RG.2.2.18756.17281

[18] Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T.GeopolymersBased on Local Rocks as a Future Alternative to Portland Cement. In Advanced Materials, Polymers, and Composites: New Research on Properties, Techniques, and Applications; Apple Acad. Press: USA, 2020, 3;pp 351-358. http://dx.doi.org/10.13140/RG.2.2.28081.12644
https://doi.org/10.1201/9781003105015-28

[19] Fernando, P.T.; Said, J. Retraction Note: Resistance to Acid Attack, Abrasion and Leaching Behavior of Alkali-Activated Mine Waste Binders.Mater Struct2021, 54,154.https://doi.org/10.1617/s11527-021-01738-2
https://doi.org/10.1617/s11527-021-01738-2

[20] Bakharev, T. Resistance of Geopolymer Materials to Acid Attack. CemConcr Res2005, 35, 658-670.https://doi.org/10.1016/j.cemconres.2004.06.005
https://doi.org/10.1016/j.cemconres.2004.06.005

[21] Hewlett, P.C. Lea's Chemistry of Cement Concrete, third ed.; John Wily and Sons, Inc.: New York, 1998.

[22] Palomo, A.; Blanco-Varela, M.T.; Granizo, M.L.; Puertas, F.; Vazquez, T.;Grutzeck, M.W. Chemical Stability of Cementitious Materials Based on Metakaolin. CemConcr Res1999,29, 997-1004.https://doi.org/10.1016/S0008-8846(99)00074-5
https://doi.org/10.1016/S0008-8846(99)00074-5

[23] Shaikh, F.U.A. Effects of Alkali Solutions on Corrosion Durability of Geopolymer Concrete.Adv. Cem. Res. 2014, 2(2).109-123.https://doi.org/10.12989/acc.2014.2.2.109
https://doi.org/10.12989/acc.2014.2.2.109

[24] Bankharev, T. Durability of Geopolymer Materials in Sodium and Magnesium Sulfate Solutions. CemConcr Res2005,35, 1233-1246.https://doi.org/10.1016/j.cemconres.2004.09.002
https://doi.org/10.1016/j.cemconres.2004.09.002

[25] Kim, Y.Y.; Lee, B.J.; Saraswathy, V.; Kwon, S.J. Strength and Durability Performance of Alkali-Activated Rice Husk Ash Geopolymer Mortar. Sci. World. J. 2014,2014,209584.https://doi.org/10.1155/2014/209584
https://doi.org/10.1155/2014/209584

[26] Lingyu, T.; Dongpo, H.; Jianing, Zh.;Hongguang, W. Durability of Geopolymersand Geopolymer Concretes: A Review. Rev. Adv. Mater. Sci. 2021,60, 1-14. https://doi.org/10.1515/rams-2021-0002
https://doi.org/10.1515/rams-2021-0002