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Subsolidus Structure of the MgO – Al2O3 – FeO – TiO2 system

Oksana Borysenko1, Sergey Logvinkov2, Galina Shabanova1, Yaroslav Pitak1, Andrii Ivashura2, Igor Ostapenko3
Affiliation: 
1National Technical University "Kharkiv Polytechnic Institute", 2, Kyrpychova str., 61002 Kharkiv, Ukraine 2Simon Kuznets Kharkov National University of Economics, 9-а, pr-t Nauki, 61166 Kharkiv, Ukraine 3TOV "Druzhkivskiy Vognetrivkiy zavod", 121-a, O. Tykhoho str., 84293 Druzhkovka, Ukraine onborisenko@ukr.net
DOI: 
https://doi.org/10.23939/chcht16.03.367
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Abstract: 
The subsolidus structure of the four-component system MgO – Al2O3 – FeO – TiO2 was studied in six temperature ranges. Geometric-topological characteristics of the phases of the system under study have been determined, topological graphs of the relationship of elementary tetrahedrons have been constructed, their volumes, degrees of asymmetry for all temperature ranges have been found. The optimal regions of compositions for the production of spinel-containing materials have been predicted, which are within the limits of elementary tetrahedra: MgO – FeO – Mg2TiO4 – MgAl2O4, FeAl2O4 – Mg2TiO4 – FeO – Fe2TiO4, FeAl2O4 – Mg2TiO4 – MgAl2O4 – FeO and FeAl2O4 – MgTiO3 – MgAl2O4 – Al2O3.
References: 

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