Some Supramolecular Nanostructures Based on Catalytic Active Nickel and Iron Heteroligand Complexes. Functional Models of Ni(Fe) Dioxygenases

Ludmila Matienko, Vladimir Binyukov, Larisa Mosolova, Elena Mil and Gennady Zaikov
PDF icon full_text.pdf1.76 MB
The possibility of the supramolecular nano structures formation on the basis of iron and nickel heteroligand complexes: Fex(acac)y18C6m(H2O)n, and Fex(acac)y(CTAB)p(H2O)q, or Ni2(OAc)3(acac)L2•2H2O (L2 = MP)  with the assistance of H-bonding, is researched using the AFM method. Formation of different supramolecular nanostructures on the basis of nickel and iron heteroligand complexes as models for Ni(Fe)ARD Dioxygenases may be used for understanding of different actions of these enzymes.

[1] Li Y. and Zamble D.: Chem. Rev., 2009, 109, 4617.

[2] Dai Y., Pochapsky Th. and Abeles R.: Biochemistry, 2001, 40, 6379.

[3] Al-Mjeni F., Ju T., Pochapsky Th. and Maroney M.: Biochemistry, 2002, 41, 6761.

[4] Sauter M., Lorbiecke R., OuYang B. et al.: The Plant J., 2005, 44, 718.

[5] Chai S., Ju T., Dang M. et al.: Biochemistry, 2008, 47, 2428.

[6] Matienko L., Mosolova L. and Zaikov G.: Selective Catalytic Hydrocarbons Oxidation. New Perspectives. Nova Science Publ., Inc., New York 2010.

[7] Matienko L.: Ch. 2 [in:] D'Amore A. and Zaikov G. (Eds.), Reactions and Properties of Monomers and Polymers. Nova Sience Publ., Inc., New York 2007, 21.

[8] Weissermel K. and Arpe H.-J.: Industrial Organic Chemistry, 3nd edn. VCH: New York 1997.

[9] Matienko L. and Mosolova L.: Oxid. Commun., 2010, 33, 830.

[10] Leninger St., Olenyuk B. and Stang P.: Chem. Rev., 2000, 100, 853.

[11] Stang P. and Olenyuk B.: Acc. Chem. Res., 1997, 30, 502.

[12] Beletskaya I., Tyurin V., Tsivadze A. et al.: Chem. Rev., 2009, 109, 1659.

[13] Drain C., Varotto A. and Radivojevic I.: ibid, 1630.

[14] Chu C-C., Raffy G., Ray D. et al.: J. Am. Chem. Soc., 2010, 132, 12717.

[15] Uehara K., Ohashi Y. and Tanaka M.: Bull. Chem. Soc. Jpn., 1976, 49, 1447.

[16] Nelson J., Howels P., Landen G. et al.: [in:] Fundamental Research in Homogeneous Catalysis. Plenum, New York- London 1979, 921.

[17] Daolio S., Traldi P., Pelli B. et al.: Inorg. Chem., 1984, 23, 4750.

[18] Gopal B., Madan L., Betz S. and Kossiakoff A.: Biochemistry, 2005, 44, 193.

[19] Balogh-Hergovich E., Kaizer J. and Speier G.: J. Mol. Catal. A, 2000, 159, 215.

[20] Straganz G. and Nidetzky B.: J. Am. Chem. Soc., 2005, 127, 12306.

[21] Basiuk E., Basiuk V., Gomez-Lara J. and Toscano R.: J. Incl. Phenom. Macrocycl. Chem., 2000, 38, 45.

[22] Mukherjee P., Drew M., Gomez-Garcia C. and Ghosh A.: Inorg. Chem., 2009, 48, 4817.

[23] Belsky V. and Bulychev B.: Usp. Khim., 1999, 68, 136.

[24] Nekipelov V. and Zamaraev K.: Coord. Chem. Rev., 1985, 61, 185.