Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Physical and Mathematical Models of Target Component Extraction from Rectlinear Capillaries

Jaroslav Gumnitsky1, Lubov Venger1, Vira Sabadash1, Dmytro Symak1, Anna Hyvlud1, Zoriana Gnativ1
Affiliation: 
1 Lviv Polytechnic National University 12, S.Bandery St., 79013 Lviv, Ukraine virasabadash@gmail.com
DOI: 
https://doi.org/10.23939/chcht16.01.112
AttachmentSize
PDF icon full_text.pdf256.96 KB
Abstract: 
The extraction of the solid component from the rectilinear capillary has been investigated. The presence of two extraction zones (convective and molecular diffusion) was confirmed. The effect of the system vacuumizing on the extraction rate has been studied. The convection zone during vacuumizing was found to be increased due to the appearance of the vapor phase bubbles. The mass transfer coefficients for the convective zone have been determined. A mathematical model of the molecular diffusion stage is given, taking into account the nonlinear change in the component concentration in the liquid due to the displacement of the extraction boundary. The molecular diffusion coefficients in the capillary have been determined.
References: 

[1] Romankov, P.G.; Frolov, V.F.; Flisyuk, O.M. Massoobmennyie Processy Khimicheskoy Tekhnologii; Khimizdat: Sankt-Peterburg, 2020.

[2] Kurt, S.K.; Gürsel, I.V.; Hessel, V.; Nigam, K.D.P.; Kockmann, N. Liquid-Liquid Extraction System with Microstructured Coiled Flow Inverter and Other Capillary Setups for Single-Stage Extraction Applications. Chem. Eng. J. 2016, 284, 764-777. https://doi.org/10.1016/j.cej.2015.08.099
https://doi.org/10.1016/j.cej.2015.08.099

[3] Vakinti, M.; Mela, S.-M.; Fernández, E.; Psillakis, E.; Psillakis, E. Room Temperature and Sensitive Determination of Haloanisoles in Wine Using Vacuum-Assisted Headspace Solid-Phase Microextraction. J. Chromatogr. 2019, 1602, 142-149. https://doi.org/10.1016/j.chroma.2019.03.047
https://doi.org/10.1016/j.chroma.2019.03.047

[4] Mascrez, S.; Psillakis, E.; Purcaro, G. A Multifaceted Investigation on the Effect of Vacuum on the Headspace Solid-Phase Microextraction of Extra-Virgin Olive Oil. Anal. Chim. Acta 2020, 1103, 106-114. https://doi.org/10.1016/j.aca.2019.12.053
https://doi.org/10.1016/j.aca.2019.12.053

[5] Aksel'rud, G.A.; Gumnitskii, Y.M. Some Characteristics of the Kinetics of Ion Exchange in the Case of Pulsating Motion of a Liquid. J. Eng. Phys. 1970, 19, 1024-1026. https://doi.org/10.1007/BF00828782
https://doi.org/10.1007/BF00828782

[6] Gumnitskii Y.M.; Sen'kiv V.N. Extraction of a Solid Substance from Linear Capillaries During Periodic Boiling under Vacuum. Theor. Found. Chem. Eng. 2006, 40, 253-258. https://doi.org/10.1134/S0040579506030055
https://doi.org/10.1134/S0040579506030055

[7] Symak, D.; Atamanyuk, V.; Gumnitsky, J. Analysis of Dissolution Kinetics based on the Local Isotropic Turbulence Theory. Chem. Chem. Technol. 2015, 9, 493-496. https://doi.org/10.23939/chcht09.04.493
https://doi.org/10.23939/chcht09.04.493

[8] Symak, D.; Gumnitsky, J.; Atamaniuk, V.; Nagurskyy, O. Investigation of Physical Dissolution of Benzoic Acid Polydisperse Mixture. Chem. Chem. Technol. 2017, 11, 469. https://doi.org/10.23939/chcht11.04.469
https://doi.org/10.23939/chcht11.04.469

[9] Pavliuk, I.; Dyachok, V.; Novikov, V.; Ilkiv, N. Kinetics of Biologically Active Compound Extraction from Hops Strobiles Extraction Cake. Chem. Chem. Technol. 2017, 11, 487-491. https://doi.org/10.23939/chcht11.04.487
https://doi.org/10.23939/chcht11.04.487

[10] Dyachok, V.; Ilkiv, I. On the Mechanism of Extraction from Solid Bodies of Cellular Structure. Chem. Chem. Technol. 2013, 7, 27-30. https://doi.org/10.23939/chcht07.01.027
https://doi.org/10.23939/chcht07.01.027

[11] Sattari-Najafabadi, M.; Esfahany, M.N.; Wu, Z., Sunden, B. Mass Transfer between Phases in Microchannels: A Review. Chem. Eng. Process 2018, 127, 213-237. https://doi.org/10.1016/j.cep.2018.03.012
https://doi.org/10.1016/j.cep.2018.03.012

[12] Vorobyova, V.I.; Skiba, M.I.; Trus, I.M. Apricot Pomaces Extract (Prunus Armeniaca L.) as a Highly Efficient Sustainable Corrosion Inhibitor for Mild Steel in Sodium Chloride Solution. Int. J. Corros. Scale Inhib. 2019, 8, 1060-1083. https://doi.org/10.17675/2305-6894-2019-8-4-15
https://doi.org/10.17675/2305-6894-2019-8-4-15

[13] Allaf, T.; Tomao, V.; Besombes, C.; Chemat, F. Thermal and Mechanical Intensification of Essential Oil Extraction from Orange Peel via Instant Autovaporization. Chem. Eng. Process. 2013, 72, 24-30. https://doi.org/10.1016/j.cep.2013.06.005
https://doi.org/10.1016/j.cep.2013.06.005

[14]. Beiranvand, M.; Ghiasvand, A. Simple, Low-Cost and Reliable Device for Vacuum-Assisted Headspace Solid-Phase Microextraction of Volatile and Semivolatile Compounds from Complex Solid Samples. Chromatographia 2017, 80, 1771-1780. https://doi.org/10.1007/s10337-017-3422-z
https://doi.org/10.1007/s10337-017-3422-z

[15] Sabadash, V.; Mylanyk, O.; Matsuska, O.; Gumnitsky, J. Kinetic Regularities of Copper Ions Adsorption by Natural Zeolite. Chem. Chem. Technol. 2017, 11, 459-462. https://doi.org/10.23939/chcht11.04.459
https://doi.org/10.23939/chcht11.04.459