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Oxidation of 1-Octene by the Molecular Oxygen in the Presence of Immobilized Catalytic Compositions

Oksana Makota and Lidiya Bulgakova
Affiliation: 
Lviv Polytechnic National University 12, S. Bandera str., 79013 Lviv, Ukraine; makotaoksana@yahoo.com
DOI: 
https://doi.org/10.23939/chcht06.03.237
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Abstract: 
The influence of immobilized catalytic compositions, obtained by immobilization of cyanide complexes of transition metals: Ni, Pd, Pt, Со, Fe, Ru, and oxysalts of vanadium on the aluminum oxide as a carrier, on the initial stages of the liquid-phase oxidation reaction of 1-octene by the molecular oxygen was studied. It was established that the highest activity in the oxidation reaction of 1-octene by the molecular oxygen showed the catalytic composition containing immobilized ruthenium cyanide complex K2[Ru(CN)6] – MnCl2•4H2O (XI) whereas the activity of catalytic composition containing immobilized nicole cyanide complex K2[Ni(CN)4] – VO(SO4)•3H2O (I) was the lowest one.
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