Micellization and Adsolubilization of Amphilic Invertible Polyesters
Affiliation:
1 Lviv Polytechnic National University
12, S. Bandery str., 79013 Lviv, Ukraine; ananiy.kohut@gmail.com
2 North Dakota State University
1735 NDSU Research Park Dr., Fargo, ND, 58102, USA
DOI:
https://doi.org/10.23939/chcht08.01.067
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Abstract:
Using surface tension measurements, solubilization, and fluorescence spectroscopy, polyesters based on aliphatic dicarboxylic acids and PEG-1000 have been shown to form monomolecular micelles in aqueous solutions at the concentrations of 10-7–10-4 %. With increasing concentration, the monomolecular micelles have been revealed to aggregate to afford polymolecular micelles. The amphiphilic polyesters have been demonstrated to possess invertibility and thus respond to the change in a medium polarity as well as adsorb at hydrophilic and hydrophobized dispersed silica surface. Using 2-naphthol, the adsorbed amphiphilic polyester layers have been shown to solubilize sparingly water-soluble organic compounds.
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