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MgO Supported Al2O3 Oxide: A New, Efficient, and Reusable Catalyst for Synthesis of Chalcones

Santosh Shriram Katkar1, Amol Haridas Kategaonkar2, Kaluram N. Vidhate3
Affiliation: 
1 Department of Chemistry, MSS’s Arts, Science and Commerce College, Ambad, Dist Jalna-431 204 Maharashtra, India 2 Department of Chemistry, K.S.K.W. Arts, Science and Commerce College, CIDCO, Uttamnagar, Nashik-422 008, Maharashtra, India 3Department of Chemistry, Milind college of science, Nagsenwan Aurangabad, Maharashtra, India katkars25@gmail.com
DOI: 
https://doi.org/10.23939/chcht14.02.169
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Abstract: 
We have studied a series of mixed metal oxides of Mg-Al by a simple co-precipitation technique. Various characterization techniques, including XRD, SEM, EDS, TEM, BET and CO2-TPD were carried out to investigate their physicochemical properties. An efficient and facile protocol has been documented for the synthesis of chalcones using different aldehydes and acetophenone using Mg-Al oxide under reflux conditions in ethanol affording good to excellent yields. Recyclability of a catalyst is a significant feature of this protocol. Moreover, it was proposed that MgO can disperse and increase the basicity, pore size and catalytic activity.
References: 

[1] Kantam M., Pal U., Sreedhar B., Choudary B.: Adv. Synth. Catal., 2007, 349, 1671. https://doi.org/10.1002/adsc.200600525
[2] Aramendía M., Borau V., Jiménez C. et al.: J. Catal., 1996, 161, 829. https://doi.org/10.1006/jcat.1996.0246
[3] Díez V., Apesteguía C., Di Cosimo J.: J. Catal., 2006, 240, 235. https://doi.org/10.1016/j.jcat.2006.04.003
[4] Zhang G., Hattori H., Tanabe K.: Appl. Catal., 1988, 36, 189. https://doi.org/10.1016/S0166-9834(00)80114-1
[5] Di Cosimo J., Díez V., Apesteguía C.: Appl. Catal. A, 1996, 137, 149. https://doi.org/10.1016/0926-860X(95)00289-8
[6] Di Cosimo J., Apesteguía C.: J. Mol. Catal. A, 1998, 130, 177. https://doi.org/10.1016/S1381-1169(97)00204-5
[7] Hattori H.: Chem. Rev., 1995, 95, 537. https://doi.org/10.1021/cr00035a005
[8] Wang Y., Zhu J., Cao J. et al.: Micropor. Mesopor. Mater., 1998, 26, 175. https://doi.org/10.1016/S1387-1811(98)00231-5
[9] Tu M., Davis R.: J. Catal., 2001, 199, 85. https://doi.org/10.1006/jcat.2000.3145
[10] Aramendía M., Borau V., Jiménez C. et al.: Appl. Catal. A, 2003, 244, 207. https://doi.org/10.1016/S0926-860X(02)00213-2
[11] Ranjit K., Klabunde K.: Chem. Mater., 2005, 17, 65. https://doi.org/10.1021/cm040360b
[12] Utamapanya S., Klabunde K., Schlup J.: Chem. Mater., 1991, 3, 175. https://doi.org/10.1021/cm00013a036
[13] Richards R., Volodin A., Bedilo A., Klabunde K.: Phys. Chem. Chem. Phys., 2003, 5, 4299. https://doi.org/10.1039/b309059k
[14] Martin M., Narske R., Klabunde K.: Micropor. Mesopor. Mater., 2005, 83, 47. https://doi.org/10.1016/j.micromeso.2005.04.003
[15] Richards R., Li W., Decker S. et al.: J. Am. Chem. Soc., 2000, 122, 4921. https://doi.org/10.1021/ja994383g
[16] Stankic S., Müeller M., Diwald O. et al.: Angew. Chem. Int. Ed., 2005, 44, 4917. https://doi.org/10.1002/anie.200500663
[17] Di Cosimo J., Diez V., Xu M., Iglesia E.: J. Catal., 1998, 178, 499. https://doi.org/10.1006/jcat.1998.2161
[18] Corma A., Iborra S., Miquel S., Primo J.: J. Catal., 1998, 173, 315. https://doi.org/10.1006/jcat.1997.1930
[19] Liu Y., Lotero E., Goodwin J., Mo X.: Appl. Catal. A, 2007, 331, 138. https://doi.org/10.1016/j.apcata.2007.07.038
[20] Prescott H., Li Z., Kemnitz E. et al.: J. Catal., 2005, 234, 119. https://doi.org/10.1016/j.jcat.2005.06.004
[21] Velu S., Swamy C.: Appl. Catal. A, 1994, 119, 241. https://doi.org/10.1016/0926-860X(94)85194-8
[22] Rao K., Gravelle M., Valente J., Figueras F.: J. Catal., 1998, 173, 115. https://doi.org/10.1006/jcat.1997.1878
[23] Climent M., Corma A., Iborra S., Primo J.: J. Catal., 1995, 151, 60. https://doi.org/10.1006/jcat.1995.1008
[24] Corma A., Fornes V., Martinaranda R., Rey F.: J. Catal., 1992, 134, 58. https://doi.org/10.1016/0021-9517(92)90209-Z
[25] Dimmock J., Elias D., Beazely M., Kandepu N.: Curr. Med. Chem., 1999, 6, 1125.
[26] Go M., Wu X., Lui L.: Curr. Med. Chem., 2005, 12, 483. https://doi.org/10.2174/0929867053363153
[27] Nowakowka Z.: Eur. J. Med. Chem., 2007, 42, 125. https://doi.org/10.1016/j.ejmech.2006.09.019
[28] Khobragade C., Bodade R., Shine M. et al.: J. Enzym. Inhib. Med. Chern., 2008, 23, 341. https://doi.org/10.1080/14756360701608585
[29] Sogawa S., Nihro Y., Ueda H. et al.: Biol. Pharm. Bull., 1994, 17, 251. https://doi.org/10.1248/bpb.17.251
[30] Nerya O., Musa R., Khatib S. et al.: Phytochem., 2004, 65, 1389. https://doi.org/10.1016/j.phytochem.2004.04.016
[31] Prakash O., Kumar A., Sadana A. et al.: Tetrahedron, 2005, 61, 6642. https://doi.org/10.1016/j.tet.2005.03.035
[32] Prasad R., Rao L., Prasoona L. et al.: Bioorg. Med. Chem. Lett., 2005, 15, 5030. https://doi.org/10.1016/j.bmcl.2005.08.040
[33] Raghavan S., Anuradha K.: Tetrahedron Lett., 2002, 43, 5181. https://doi.org/10.1016/S0040-4039(02)00972-3
[34] Bohn B.: Introduction to Flavonoids, Harwood Academic, Amsterdam 1998.
[35] Azad M., Munawar M., Siddiqui H.: J. Appl. Sci., 2007, 7, 2485. https://doi.org/10.3923/jas.2007.2485.2489
[36] Prasad R., Kumar P.P., Kumar P.R., Rao A.: E-J. Chem., 2008, 5, 144. https://doi.org/10.1155/2008/602458
[37] Iglesias M., Marinas J., Sinisterra J.: Tetrahedron, 1987, 43, 2335. https://doi.org/10.1016/S0040-4020(01)86819-8
[38] Savanth M., Chakraborti K.: J. Mol. Catal., 2006, 244, 20. https://doi.org/10.1016/j.molcata.2005.08.039
[39] Calloway N., Green L.: J. Am. Chem. Soc., 1937, 59, 809. https://doi.org/10.1021/ja01284a011
[40] Chitra M., Rajendran T., Duraipandiyan V. et al.: Indian J. Sci. Technol., 2010, 3, 890.
[41] Narender T., K.P. Reddy. Tetrahedron Lett ., 2007,48, 3177. https://doi.org/10.1016/j.tetlet.2007.03.054
[42] Mazza L., Guaram A.: Synthesis, 1980, 1980, 41. https://doi.org/10.1055/s-1980-28916
[43] Iranpoor I., Kazemi F.: Tetrahedron, 1998, 54, 9475. https://doi.org/10.1016/S0040-4020(98)00575-4
[44] Rendy R., Zhang Y., McElrea A.: J. Org. Chem., 2004, 69, 2340. https://doi.org/10.1021/jo030327t
[45] Hua Q., Dabin L., Chunxu L.: Ind. Eng. Chem. Res., 2011, 50, 1146. https://doi.org/10.1021/ie101790k
[46] Katkar S., Mohite P., Gadekar L. et al.: Cent. Eur. J. Chem., 2010, 8, 320. https://doi.org/10.2478/s11532-009-0151-7
[47] Katkar S., Arbad B., Lande M.: Arab. J. Sci. Eng., 2010, 36, 39. https://doi.org/10.1007/s13369-010-0010-z
[48] Katkar S., Mohite P., Gadekar L. et al.: Chinese Chem. Lett., 2010, 21, 421. https://doi.org/10.1016/j.cclet.2009.10.020
[49] Katkar S., Mohite P., Gadekar L. et al.: Green Chem. Lett. Rev., 2010, 3, 287. https://doi.org/10.1080/17518253.2010.482065
[50] Katkar S., Lande M., Arbad B., Rathod S.: Bull. Korean Chem. Soc., 2010, 31, 1301. https://doi.org/10.5012/bkcs.2010.31.5.1301
[51] Katkar S., Lande M., Arbad B., Gaikwad S.: Chinese J. Chem., 2011, 29, 199. https://doi.org/10.1002/cjoc.201190052
[52] Gadekar L., Katkar S., Mane S. et al.: Bull. Korean Chem. Soc., 2009, 30, 2532. https://doi.org/10.5012/bkcs.2009.30.11.2532
[53] Gadekar L., Mane S., Katkar S. et al.: Cent. Eur. J. Chem., 2009, 7, 550. https://doi.org/10.2478/s11532-009-0050-y
[54] Gadekar L., Katkar S., Vidhate K. et al.: Bull. Catal. Soc. India, 2008, 7, 79.
[55] Rathod S., Gadekar L., Katkar S. et al.: Bull. Catal. Soc. India, 2009, 8, 16.
[56] Shaikh U., Katkar S., Vidhate K. et al.: J. Ind. Chem. Soc., 2012, 88, 1465.
[57] Lande M., Navgire M., Rathod S. et al.: J. Ind. Eng. Chem., 2012, 18, 277. https://doi.org/10.1016/j.jiec.2011.11.048
[58] Vidhate K., Katkar S., Arbad B., Lande M.: Adv. App. Sci. Res., 2012, 3, 713.
[59] Katkar S., Kategaonkar A.: J. Chem. Chem. Sci., 2015, 5, 591.
[60] Katkar S., Kategaonkar A.: OCAIJ, 2015, 11, 415.
[61] Raghav N., Malik P.: Adv.Appl. Sci. Res., 2011, 2, 410.