Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Influence of Polymer-Silicate Nucleator on the Structure and Properties of Polyamide 6

Volodymyr Levytskyi1,2, Andrii Masyuk1, Diana Katruk1, Rafał Kuzioła2, Mykhailo Bratychak Jr.1, Nataliia Chopyk1, Ulyana Khromyak3
Affiliation: 
1 Lviv Polytechnic National University, 12, Bandera St., 79013 Lviv, Ukraine 2 The John Paul II Catholic University of Lublin, 14, Al. Racławickie, 20-950 Lublin, Poland 3 Lviv State University of Life Safety, 35, Kleparivska St., 79000 Lviv, Ukraine masyukas@gmail.com
DOI: 
https://doi.org/10.23939/chcht14.04.496
AttachmentSize
PDF icon full_text.pdf1.68 MB
Abstract: 
Physico-chemical properties of developed nickel-containing modified silicate materials as the nucleators for composites based on polyamide 6 are presented. As it was established, additive of the nucleator modified by polyvinylpyrrolidone promotes the increase of crystallinity degree of polyamide 6 and the decrease of crystallite size. It was found that changes in the structure of the material cause the increase of its tensile strength, surface hardness and Vicat softening point.
References: 

[1] Mai Y., Yu Z.: Polymer Nanocomposites. Woodhead Publishing. Boca Raton 2006.
[2] Katruk D., Levytskyi V., Khromyak U. et al.: Int. J. Polym. Sci., 2019, 2019, 1. https://doi.org/10.1155/2019/2547384
[3] Levyts’kyi V., Katruk D., Shybanova A. et al.: Mater. Sci., 2017, 52, 559. https://doi.org/10.1007/s11003-017-9990-0
[4] Levytskyi V., Katruk D., Masyuk A. et al.: Chem. Chem. Technol., 2018, 12, 53. https://doi.org/10.23939/chcht12.01.053
[5] Kerber M., Vynohradov V., Holovkin H.: Polimerni Kompozytsiyni Materialy. Profesiya. SPb 2008.
[6] Levytskyi V., Katruk D., Kochubei V. et al.: Mater. Sci., 2017, 53, 385. https://doi.org/10.1007/s11003-017-0086-7
[7] Guo M., Liu Y., Li J. et al.: China Synth. Resin Plastics, 2014, 31, 4. https://doi.org/10.1039/c3ra46244g
[8] Yebra-Rodrígueza A., Alvarez-Lloret P., Cardell C., Rodríguez-Navarro A.: Appl. Clay Sci., 2009, 43, 91. https://doi.org/10.1016/j.clay.2008.07.010
[9] Levytskyj V., Laruk Yu., Huminetsky T., Sikora J.: Chem. Chem. Technol., 2015, 9, 199. https://doi.org/10.23939/chcht09.02.199
[10] Krasinskyi V., Suberlyak O., Zemke V. et al.: Chem. Chem. Technol., 2019, 14, 59. https://doi.org/10.23939/chcht13.01.059
[11] Levytskyj V., Kochubei V., Gancho A.: Chem. Chem. Technol., 2013, 7, 169. https://doi.org/10.23939/chcht07.02.169
[12] Mittal V.: J. Therm. Comp. Mater., 2007, 20, 575. https://doi.org/10.1177/0892705707083636
[13] Sangwal K.: Additives and Crystallization Processes From Fundamentals to Applications. Wiley & Sons Ltd. Chichester 2007. https://doi.org/10.1002/9780470517833
[14] Murphy J.: Additives for Plastics Handbook, 2nd edn. Elsevier Science, Oxford 2001.
[15] Mudra I., Balazs G.: J. Therm. Anal. Calorim., 1998, 52, 355. https://doi.org/10.1023/A:1010105825111
[16] Levytskyi V., Masyuk A., Suberlyak O.: Voprosy Khimii i Khimicheskoi Tekhnologii, 2017, 6, 68.
[17] Levytskyi, V., Masyuk, A., Katruk, D., Bratychak, M.: Mater. Sci., Chem. Chem. Technol., 2016, 10, 35. https://doi.org/10.23939/chcht10.01.035
[18] Rabiej M., Rabiej S.: Analiza Rentgenowskich Krywych Dyfrakcyjnych Polymerów za Pomoca Programu Komputerowego WAXSFIT. Bielsko-Biała. Warszawa 2006.
[19] Liyv E.: Metodika Opredeleniya Phyziko-Mekhanicheskikh Svoistv Polymernykh Kompozitov Putem Vnedreniya Konusoobraznogo Indentora. EstNIINTI, Talin 1983.
[20] Gurato G., Gaidano D., Zannetti R.: Die Makromol. Chem.: 1978, 179, 231. https://doi.org/10.1002/macp.1978.021790123
[21] Levyts’kyi V., Masyuk А., Bialopiotrowicz Т. et al.: Mater. Sci., 2018, 54, 48. https://doi.org/10.1007/s11003-018-0157-4
[22] Wypych G.: Handbook of Nucleating Agents. ChemTec Publishing. Ontario 2016. https://doi.org/10.1016/B978-1-927885-19-2.50019-X
[23] Wypych G., Wypych A.: Databook of Nucleating Agents. ChemTec Publishing. Ontario 2016. https://doi.org/10.1016/B978-1-927885-19-2.50019-X
[24] Levytskyi V., Masyuk A., Samoiliuk D. et al.: Mater. Sci., 2016, 52, 17. https://doi.org/10.1007/s11003-016-9921-5
[25] Koenig J.: Spectroscopy of Polymers, 2nd edn. Elsevier Science. New York 1999. https://doi.org/10.1016/B978-044410031-3/50005-0
[26] Mandelkern L.: Crystallization of Polymers, 2nd edn., v. 2. Kinetics and Mechanisms. Cambridge University Press, Cambridge 2004.