Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Effect of Extrusion Processing Variables in the Polyethylene/Clay Nanocomposites Rheological Properties

Cristiane da Silva1, 2, Leonardo Canto1 and Leila Visconti1
Affiliation: 
1Instituto de Macromoléculas Professora Eloisa Mano – UFRJ 2CENPES- Centro de Pesquisas Leopoldo Américo Miguez de Melo - Petrobras Cidade Universitária – Rio de Janeiro, Brazil
DOI: 
https://doi.org/10.23939/chcht04.01.061
AttachmentSize
PDF icon full_text.pdf155.34 KB
Abstract: 
In this work, high density polyethylene, HDPE, was compounded in a twin screw extruder with organophilic treated montmorillonite clay and a compatibilizer agent. The screws configuration was changed from distributive to highly dispersive [1], using four different profiles. The extrusion conditions were also changed. The exfoliation degree was evaluated by X-rays. The rheological measurements showed different behavior according to the processing adopted.
References: 

[1] Rauwvendaal C.: Mixing in Polymer Processing. Marcel Dekker Inc., 1991.

[2] Vaia R., Ishii H. and Giannelis E.: Chem. Mat., 1993, 5, 1694.
https://doi.org/10.1021/cm00036a004

[3] Vaia R., Jandt K., Kramer E. and Giannelis E.: Macromolecules, 1995, 28, 8080.
https://doi.org/10.1021/ma00128a016

[4] Fornes T., Yoon P., Hunter D. et al.: Polymer, 2002, 43, 5915.
https://doi.org/10.1016/S0032-3861(02)00400-7

[5] Fornes T., Hunter D., Keskkula H. and Paul D.: Macromolecules, 2004, 37, 1793.
https://doi.org/10.1021/ma0305481

[6] Zhao Z., Tang T., Qin Y. and Huang B.: Langmuir, 2003, 19, 7157.
https://doi.org/10.1021/la034575w

[7] Hotta S. and Paul D.: Polymer, 2004, 45, 7639.
https://doi.org/10.1016/j.polymer.2004.08.059

[8] Fornes T., Yoon P., Keskkula H. and Paul D.: Polymer, 2002, 42, 9929.
https://doi.org/10.1016/S0032-3861(01)00552-3

[9] Wang Y., Chem F., Li Y. and Wu K.: Composites B, 2004, 35, 111.
https://doi.org/10.1016/S1359-8368(03)00049-0

[10] Lertwimolnun W. and Vergnes B.: Polymer, 2005, 46, 3462.
https://doi.org/10.1016/j.polymer.2005.02.018

[11] Li X., Park H., Lee J. and Ha C.: Polym. Eng. Sci., 2002, 42, 2156.
https://doi.org/10.1002/pen.11105

[12] Kwak M., Lee M. and Lee B.: SPE-ANTEC Tech. Paper, CD-Rom, 2003.

[13] Zhu L. and Xanthos M.: J. Appl. Polym. Sci., 2004, 93, 1891.
https://doi.org/10.1002/app.20658

[14] Dennis H., Hunter D., Chang D. et al.: Polymer, 2001, 42, 9523.
https://doi.org/10.1016/S0032-3861(01)00473-6

[15] Dolgovskij M., Fasulo P., Lortie F. et al.: SPE-ANTEC Tech. Papers, CD-Rom, 2003.

[16] Kim K., Kim H. and Lee J.: Polym. Eng. Sci., 2001, 41, 1963.
https://doi.org/10.1002/pen.10892

[17] Hasegawa N., Okamoto H., Kato M. and Usuki A.: J. Appl. Polym. Sci., 2000, 78, 1918.
https://doi.org/10.1002/1097-4628(20001209)78:11<1918::AID-APP100>3.0.CO;2-H

[18] Ma J., Qi Z. and Hu Y.: J. Appl. Polym. Sci., 2001, 82, 3611.
https://doi.org/10.1002/app.2223

[19] Kawasumi M., Hasegawa N., Kato M. et al.: Macromolecules, 1997, 30, 6333.
https://doi.org/10.1021/ma961786h

[20] Maiti P., Nam P., Okamoto M. et al.: Macromolecules, 2002, 35, 2042.
https://doi.org/10.1021/ma010852z

[21] Fu X. and Qutubuddin S.: Polymer, 2001, 42, 1980.
https://doi.org/10.1016/S0032-3861(00)00385-2

[22] Ma J., Qi Z., Zhang S.F. and Zhang S. M.: Chem. J. China Univ., 2001, 22, 1767.

[23] Chen Z. and Gong K.: China Synth. Resin Plastics, 2000, 17, 44.
https://doi.org/10.1016/S0034-3617(00)80086-7