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Development of Cold Fiber Head Space Solid-Phase Microextraction for Analysis of 2,5 Hexandion in Urine

Yasaman Pourbakhshi1, Abdul Rahman Bahramy1, Farshid Ghorbani Shanha1, Mohammad Javad Assari1, Leila Tajik1, Maryam Farhadian2
Affiliation: 
1 Center of Excellence for Occupational Health, Research Center of Health Sciences, School of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran 2 Department of Biostatistics, School of Public Health, Hamadan University of Medical Sciences, Hamedan, Iran bahrami.abdulrahman@gmail.com
DOI: 
https://doi.org/10.23939/chcht13.04.482
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Keywords:

Abstract: 
2,5-Hexanedione (2,5-HD), the main metabolite of n-hexane was extracted from urine samples using cold fiber head space solid-phase microextraction (CF-HS-SPME) based on thermoelectric cooling and analyzed with gas chromatography equipped with a flame ionization detector (GC-FID). Important parameters for improved efficiency of fiber sorption including sample volume, extraction time and temperature were optimized using a central composite design. The optimum conditions were determined, under which the detection limit and the relative standard deviations were found. The method was shown to be rapid, sensitive and easier than conventional methods for quantitative analysis of 2,5-HD in urine samples.
References: 

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