Catalytic intensification of the cyclohexane oxidation

Oleksandr Ivashchuk1
Affiliation: 
1 Lviv Polytechnic National University, 12, Bandery St., 79013 Lviv, Ukraine oleksandr.s.ivashchuk@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht11.04.430
AttachmentSize
PDF icon full_text.pdf330.99 KB
Abstract: 
Methods of intensification of the process of liquid-phase cyclohexane oxidation in the presence of complex catalytic systems, catalytic solutions and individual catalysts have been considered in the article. Quantitative and qualitative influences of binary catalytic systems which contain cobalt naphthenate and organic modifiers of different nature have been determined. The research confirmed the assumption of complexation involving components of the catalytic solutions in the reaction mixture. The structural formula of possible intermediate catalytic complex has been built.
References: 

[1] Furman M., Goldman A. et al.: Proyzvodstvo Cyklogeksanona i Adypynovoi Kisloty Okisleniem Cyklogeksana. Khimiya, Moskva 1967.

[2] Furman M., Arest-Yakubovych I.,Geberger F. et al.: Trudy Nauchno-issled. i Proekt. Inst. Azot. Prom i Prod. Org. Sinteza, 1973, 21, 41.

[3] Sooknoi T., Limtrakul J.: Appl. Catal. A, 2002, 233, 227. https://doi.org/10.1016/S0926-860X(02)00196-5
https://doi.org/10.1016/S0926-860X(02)00196-5

[4] Berezyn I., Denysov E., Emanuel N.: Okislenie Cyklogeksana. MGU, Moskva 1962.

[5] Ivashchuk O., Reutskyy V.: Book of abstract of 11th Meeting of the European Society of Sonochemistry. France, La Grande-Motte 2008, 191.

[6] Reutskyy V., Ivashchuk O., Zastavnyy S.: VisnykNU "Lvivska Polytechnica", 2003, 488, 170.

[7] Reutskyy V., Melnyk Yu., Ivashchuk O.: Voprosy Khim. Khim. Tekhnol., 2004, 6, 71.

[8] Ivaschuk O., Skachko S., Melnyk Yu., Reutskyy V.: XVII Int. Conf. on Chemical Reactors CHEMREACTOR-17. Greece, Athens-Crete 2006, 646.

[9] Ivashchuk O., Reutskyy V., Mudryy S.: Book of abstracts 5th Int. Conf. on Chemistry and Chemical Education "SviridovReadings 2010". Belarus, Minsk 2010, 61.

[10] Ivashchuk O., Reutskyy V.: Chem. Chem. Technol., 2008, 2, 85.

[11] Suprun O., Reutskyy V., Ivashchuk O., Mudryi S.: Skhidno-Ievropeiskyi Zhur. Peredovykh Tekhn., 2014, 6, 8.

[12] Ivashchuk O., Suprun O., Reutskyy V. Proceedings of 5th International Youth Science Forum "Litteris Et Artibus".Ukraine, Lviv 2015, 390-391.

[13] Kazitsyna L., Kupletskaya N.: Primenenie UF-, IR, NMR-spectroskopii v Organicheskoi Khimii. Vysshaya shkola, Moskva 1971.

[14] Mironov V., Yankovskyy S.: Spectroskopia v Organicheskoi Khimii. Khimiya, Moskva 1985.