Adsorption Kinetics and Isotherms of Cu(II) and Fe(II) Ions from Aqueous Solutions by Fly Ash-Based Geopolymer
Affiliation:
1 Department of Chemical Engineering, Faculty of Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Tembalang, Semarang 50275, Indonesia
aprilina.purbasari@che.undip.ac.id
DOI:
https://doi.org/10.23939/chcht16.02.169
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Keywords:
Abstract:
This paper describes the adsorption of Cu2+ and Fe2+ ions, common heavy metals found in industrial wastewater, by a fly ash-based geopolymer in batch adsorption experiments. Kinetics studies showed that the adsorption of each ion followed a pseudo-second order reaction. Moreover, adsorption isotherm of Cu2+ and Fe2+ ions followed the Langmuir model. Monolayer adsorption capacities were approximately 53.76 mg/g for Cu2+ ion and 52.63 mg/g for Fe2+ ion, respectively.
References:
[1] Davidovits, J. Geopolymers: Ceramic-Like Inorganic Polymers. J. Ceram. Sci. Technol. 2017, 8, 335-350. https://doi.org/10.4416/JCST2017-00038
[2] Kramar, S.; Ducman, V. Mechanical and Microstructural Characterization of Geopolymer Synthesized from Low Calcium Fly Ash. Chem. Ind. Chem. Eng. Q. 2015, 21, 13-22. https://doi.org/10.2298/CICEQ130725042K
https://doi.org/10.2298/CICEQ130725042K
[3] Bhatnagar, A. ; Minocha, A.K. Conventional and Non-Conventional Adsorbents for Removal of Pollutants From Water - A Review. Indian J. Chem. Technol. 2006, 13, 203-217. http://nopr.niscair.res.in/handle/123456789/7020
[4] Alehyen, S.; Achouri, M.; Taibi, M. Characterization, Microstructure and Properties of Fly Ash-Based Geopolymer. J. Mater. Environ. Sci., 2017, 8, 1783-1796.
[5] Zhuang, X.Y.; Chen, L.; Komarneni, S.; Zhou, C.H.; Tong, D.S.; Yang, H.M.; Yu, W.H.; Wang, H. Fly Ash-Based Geopolymer: Clean Production, Properties and Applications. J. Clean. Prod. 2016, 125, 253-267. https://doi.org/10.1016/j.jclepro.2016.03.019
https://doi.org/10.1016/j.jclepro.2016.03.019
[6] Singh, N.B. Fly Ash-Based Geopolymer Binder: A Future Construction Material. Minerals 2018, 8, 299-320. https://doi.org/10.3390/min8070299
https://doi.org/10.3390/min8070299
[7] Siyal, A.A.; Shamsuddin, M.R.; Khan, M.I.; Rabat, N.E.; Zulfiqar, M.; Man, Z.; Siame, J.; Azizli, K.A. A Review on Geopolymers as Emerging Materials for the Adsorption of Heavy Metals and Dyes. J. Environ. Manage. 2018, 224, 327-339. https://doi.org/10.1016/j.jenvman.2018.07.046
https://doi.org/10.1016/j.jenvman.2018.07.046
[8] Rasaki, S.A.; Bingxue, Z.; Guarecuco, R.; Thomas, T.; Minghui, Y. Geopolymer for Use in Heavy Metals Adsorption, and Advanced Oxidative Processes: A Critical Review. J. Clean. Prod. 2019, 213, 42-58. https://doi.org/10.1016/j.jclepro.2018.12.145
https://doi.org/10.1016/j.jclepro.2018.12.145
[9] Iakovleva, E.; Sillanpää, M. The Use of Low-Cost Adsorbents for Wastewater Purification in Mining Industries. Environ. Sci. Pollut. Res. 2013, 20, 7878-7899. https://doi.org/10.1007/s11356-013-1546-8
https://doi.org/10.1007/s11356-013-1546-8
[10] Lim, A.P.; Aris A.Z. A Review on Economically Adsorbents on Heavy Metals Removal in Water and Wastewater. Rev. Environ. Sci. Biotechnol. 2014, 13, 163-181. https://doi.org/10.1007/s11157-013-9330-2
https://doi.org/10.1007/s11157-013-9330-2
[11] Sabadash, V.; Mylanyk, O.; Matsuska, O.; Gumnitsky, J. Kinetic Regularities of Copper Ions Adsorption by Natural Zeolite. Chem. Chem. Technol. 2017, 11, 459-462. https://doi.org/10.23939/chcht11.04.459
https://doi.org/10.23939/chcht11.04.459
[12] Al-Saydeh, S.A.; El-Naas, M.H.; Zaidi, S.J. Copper Removal from Industrial Wastewater: A Comprehensive Review. J. Ind. Eng. Chem. 2017, 56, 35-44. https://doi.org/10.1016/j.jiec.2017.07.026
https://doi.org/10.1016/j.jiec.2017.07.026
[13] Ahmaruzzaman, M. Industrial Wastes as Low-Cost Potential Adsorbents for the Treatment of Wastewater Laden with Heavy Metals. Adv. Colloid Interface Sci. 2011, 166, 36-59. https://doi.org/10.1016/j.cis.2011.04.005
https://doi.org/10.1016/j.cis.2011.04.005
[14] Ge, Y.; Cui, X.; Kong, Y.; Li, Z.; He, Y.; Zhou, Q. Porous Geopolymeric Spheres for Removal of Cu(II) from Aqueous Solution: Synthesis and Evaluation. J. Hazard. Mater. 2015, 283, 244-251. https://doi.org/10.1016/j.jhazmat.2014.09.038
https://doi.org/10.1016/j.jhazmat.2014.09.038
[15] Abas, S.N.A.; Ismail, M.H.S.; Kamal, M.L.; Izhar, S. Adsorption Process of Heavy Metals by Low-Cost Adsorbent: A Review. World Appl. Sci. J. 2013, 28, 1518-1530.
[16] Nguyen, K.M.; Nguyen, B.Q.; Nguyen H.T.; Nguyen H.T.H. Adsorption of Arsenic and Heavy Metals from Solutions by Unmodified Iron-Ore Sludge. Appl. Sci. 2019, 9, 619-633. https://doi.org/10.3390/app9040619
https://doi.org/10.3390/app9040619
[17] Al-Zboon, K.; Al-Harahsheh, M.S.; Hani, F.B. Fly Ash-Based Geopolymer for Pb Removal from Aqueous Solution. J. Hazard. Mater. 2011, 188, 414-421. https://doi.org/10.1016/j.jhazmat.2011.01.133
https://doi.org/10.1016/j.jhazmat.2011.01.133
[18]Al-Harahsheh, M.S.; Al-Zboon, K.; Al-Makhadmeh, L.; Hararah, M.; Mahasneh, M. Fly Ash Based Geopolymer for Heavy Metal Removal: A Case Study on Copper Removal. J. Environ. Chem. Eng. 2015, 3, 1669-1677. https://doi.org/10.1016/j.jece.2015.06.005
https://doi.org/10.1016/j.jece.2015.06.005
[19] Qiu, J.; Zhao, Y.; Xing, J.; Sun, X. Fly Ash-Based Geopolymer as a Potential Adsorbent for Cr(VI) Removal. Desalin. Water Treat. 2017, 70, 201-209. https://doi.org/10.5004/dwt.2017.20493
https://doi.org/10.5004/dwt.2017.20493
[20] Duan, P.; Yan, C.; Zhou, W.; Ren, D. Development of Fly Ash and Iron Ore Tailing Based Porous Geopolymer for Removal of Cu(II) from Wastewater. Ceram. Int. 2016, 42, 13507-13518. https://doi.org/10.1016/j.ceramint.2016.05.143
https://doi.org/10.1016/j.ceramint.2016.05.143
[21] Ayawei, N.; Ebelegi, A.N.; Wankasi, D. Modelling and Interpretation of Adsorption Isotherms. J. Chem. 2017, 2017, 3039817. https://doi.org/10.1155/2017/3039817
https://doi.org/10.1155/2017/3039817
[22] Karthikeyan, G.; Siva Ilango, S. Equilibrium Sorption Studies of Fe, Cu and Co Ions in Aqueous Medium Using Activated Carbon Prepared from Recinius Communis Linn. J. Appl. Sci. Environ. Manage. 2008, 12, 81-87. https://doi.org/10.4314/jasem.v12i2.55537
https://doi.org/10.4314/jasem.v12i2.55537
[23] Sarkar, C.; Basu, J.K.; Samanta, A.N. Synthesis of Mesoporous Geopolymeric Powder from LD Slag as Superior Adsorbent for Zinc (II) Removal. Adv. Powder Technol. 2018, 29, 1142-1152. https://doi.org/10.1016/j.apt.2018.02.005
https://doi.org/10.1016/j.apt.2018.02.005
[24] Davidovits, J. Geopolymer: Chemistry and Applications; Institut Géopolymère: Saint-Quentin, 2008.
[25] Lee, W.K.W.; van Deventer, J.S.J. Structural Reorganisation of Class F Fly Ash in Alkaline Silicate Solutions. Colloid Surface A 2002, 211, 49-66. https://doi.org/10.1016/S0927-7757(02)00237-6
https://doi.org/10.1016/S0927-7757(02)00237-6
[26] Lee, W.K.W.; van Deventer, J.S.J. The Effects of Inorganic Salt Contamination on the Strength and Durability of Geopolymers. Colloid Surface A 2002, 211, 115-126. https://doi.org/10.1016/S0927-7757(02)00239-X
https://doi.org/10.1016/S0927-7757(02)00239-X
[27] Nath, S.K.; Maitra, S.; Mukherjee, S.; Kumar S. Microstructural and Morphological Evolution of Fly Ash Based Geopolymers. Constr. Build. Mater. 2016, 111, 758-765. https://doi.org/10.1016/j.conbuildmat.2016.02.106
https://doi.org/10.1016/j.conbuildmat.2016.02.106
[28] Bouguermouh, K.; Bouzidi, N.; Mahtout, L.; Pérez-Villarejo, L.; Martínez-Cartas, M.L.Effect of Acid Attack on Microstructure and Composition of Metakaolin-Based Geopolymers: The Role of Alkaline Activator. J. Non-Cryst. Solids 2017, 463, 128-137. https://doi.org/10.1016/j.jnoncrysol.2017.03.011
https://doi.org/10.1016/j.jnoncrysol.2017.03.011
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